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ChemicalBook >> (S)-(-)-3-METHOXY-2-METHYL-3-OXOPROPYLZINC BROMIDE

(S)-(-)-3-METHOXY-2-METHYL-3-OXOPROPYLZINC BROMIDE

(S)-(-)-3-METHOXY-2-METHYL-3-OXOPROPYLZINC BROMIDE price.
  • $691 - $2501.15
  • Product name: (S)-(-)-3-METHOXY-2-METHYL-3-OXOPROPYLZINC BROMIDE
  • CAS: 312693-18-8
  • MF: C5H9BrO2Zn
  • MW: 246.42
  • EINECS:
  • MDL Number:MFCD00671994
  • Synonyms:3-METHOXY(2S)-(-)-METHYL-3-OXOPROPYLZINC BROMIDE;(S)-(-)-3-METHOXY-2-METHYL-3-OXOPROPYLZINC BROMIDE;(S)-(-)-3-METHOXY-2-METHYL-3-OXOPROPYLZI NC BROMIDE, 0.5M SOLUTION IN THF;(s)-(-)-3-methoxy-2-methyl-3-oxopropylzinc bromide solution;(S)-()-3-Methoxy-2-methyl-3-oxopropylzinc bromide solution 0.5M in THF
2 prices
Selected condition:
Brand
  • American Custom Chemicals Corporation
  • Sigma-Aldrich
Package
  • 50ML
  • ManufacturerAmerican Custom Chemicals Corporation
  • Product numberING0005965
  • Product description3-METHOXY(2S)-(-)-METHYL-3-OXOPROPYLZINC BROMIDE 95.00%
  • Packaging50ML
  • Price$2501.15
  • Updated2021-12-16
  • Buy
  • ManufacturerSigma-Aldrich
  • Product number498815
  • Product description(S)-(?)-3-Methoxy-2-methyl-3-oxopropylzinc bromide solution 0.5 M in THF
  • Packaging50ml
  • Price$691
  • Updated2023-06-20
  • Buy
Manufacturer Product number Product description Packaging Price Updated Buy
American Custom Chemicals Corporation ING0005965 3-METHOXY(2S)-(-)-METHYL-3-OXOPROPYLZINC BROMIDE 95.00% 50ML $2501.15 2021-12-16 Buy
Sigma-Aldrich 498815 (S)-(?)-3-Methoxy-2-methyl-3-oxopropylzinc bromide solution 0.5 M in THF 50ml $691 2023-06-20 Buy

Properties

Density :0.965 g/mL at 25 °C
Flash point :1 °F
storage temp. :2-8°C

Safety Information

Symbol(GHS): GHS hazard pictogramsGHS hazard pictogramsGHS hazard pictograms
Signal word: Danger
Hazard statements:
Code Hazard statements Hazard class Category Signal word Pictogram P-Codes
H225 Highly Flammable liquid and vapour Flammable liquids Category 2 Danger GHS hazard pictograms P210,P233, P240, P241, P242, P243,P280, P303+ P361+P353, P370+P378,P403+P235, P501
H302 Harmful if swallowed Acute toxicity,oral Category 4 Warning GHS hazard pictograms P264, P270, P301+P312, P330, P501
H319 Causes serious eye irritation Serious eye damage/eye irritation Category 2A Warning GHS hazard pictograms P264, P280, P305+P351+P338,P337+P313P
H335 May cause respiratory irritation Specific target organ toxicity, single exposure;Respiratory tract irritation Category 3 Warning GHS hazard pictograms
H351 Suspected of causing cancer Carcinogenicity Category 2 Warning P201, P202, P281, P308+P313, P405,P501
Precautionary statements:
P210 Keep away from heat/sparks/open flames/hot surfaces. — No smoking.
P280 Wear protective gloves/protective clothing/eye protection/face protection.
P305+P351+P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.
P370+P378 In case of fire: Use … for extinction.
P403+P235 Store in a well-ventilated place. Keep cool.

Description

(S)-(?)-3-Methoxy-2-methyl-3-oxopropylzinc bromide can be used:
  • As an intermediate in the total synthesis of macrolide derivative laingolide B stereoisomers.
  • As a substrate in the synthesis of (3R)-1-benzyl-3-methylpyrrolidine-2,5-dione (aliphatic carboxamide) using NiII-pincer complexes.


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