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ChemicalBook >> CAS DataBase List >> 3-OXO-3-M-TOLYL-PROPIONIC ACID ETHYL ESTER

3-OXO-3-M-TOLYL-PROPIONIC ACID ETHYL ESTER

3-OXO-3-M-TOLYL-PROPIONIC ACID ETHYL ESTER price.
  • $55.6 - $832
  • Product name: 3-OXO-3-M-TOLYL-PROPIONIC ACID ETHYL ESTER
  • CAS: 33166-79-9
  • MF: C12H14O3
  • MW: 206.24
  • EINECS:
  • MDL Number:MFCD03424816
  • Synonyms:ETHYL 3-OXO-3-M-TOLYLPROPANOATE;ETHYL (3-METHYLBENZOYL)ACETATE;3-OXO-3-M-TOLYL-PROPIONIC ACID ETHYL ESTER;3-OXO-3-(3-TOLYL)PROPIONIC ACID ETHYL ESTER;ETHYL 3-(3-METHYLPHENYL)-3-OXOPROPANOATE;Ethyl 2-(3-methylbenzoyl)acetate;Ethyl 3-oxo-3-(m-tolyl)propionate;Ethyl m-methylbenzoylacetate
15 prices
Selected condition:
Brand
  • Acrotein
  • AHH
  • AK Scientific
  • American Custom Chemicals Corporation
  • Chemenu
  • Crysdot
  • Matrix Scientific
  • Sigma-Aldrich
  • TRC
Package
  • 500mg
  • 0.5g
  • 1g
  • 5g
  • 10g
  • 25g
  • ManufacturerAcrotein
  • Product numberOP-0145
  • Product descriptionEthyl (3-methylbenzoyl)acetate 97%
  • Packaging1g
  • Price$82.5
  • Updated2021-12-16
  • Buy
  • ManufacturerAcrotein
  • Product numberOP-0145
  • Product descriptionEthyl (3-methylbenzoyl)acetate 97%
  • Packaging5g
  • Price$247.5
  • Updated2021-12-16
  • Buy
  • ManufacturerAHH
  • Product numberMT-20589
  • Product description3-Oxo-3-(3-tolyl)propionicacidethylester 98%
  • Packaging0.5g
  • Price$538
  • Updated2021-12-16
  • Buy
  • ManufacturerAK Scientific
  • Product numberB825
  • Product descriptionEthyl (3-methylbenzoyl)acetate
  • Packaging5g
  • Price$253
  • Updated2021-12-16
  • Buy
  • ManufacturerAmerican Custom Chemicals Corporation
  • Product numberCHM0023997
  • Product description3-OXO-3-(3-TOLYL)PROPIONIC ACID ETHYL ESTER 95.00%
  • Packaging1G
  • Price$683.75
  • Updated2021-12-16
  • Buy
  • ManufacturerChemenu
  • Product numberCM192716
  • Product descriptionEthyl3-(3-methylphenyl)-3-oxopropanoate 95%
  • Packaging5g
  • Price$224
  • Updated2021-12-16
  • Buy
  • ManufacturerChemenu
  • Product numberCM192716
  • Product descriptionEthyl3-(3-methylphenyl)-3-oxopropanoate 95%
  • Packaging10g
  • Price$393
  • Updated2021-12-16
  • Buy
  • ManufacturerChemenu
  • Product numberCM192716
  • Product descriptionEthyl3-(3-methylphenyl)-3-oxopropanoate 95%
  • Packaging25g
  • Price$785
  • Updated2021-12-16
  • Buy
  • ManufacturerCrysdot
  • Product numberCD12082779
  • Product descriptionEthyl3-oxo-3-(m-tolyl)propanoate 95%
  • Packaging5g
  • Price$238
  • Updated2021-12-16
  • Buy
  • ManufacturerCrysdot
  • Product numberCD12082779
  • Product descriptionEthyl3-oxo-3-(m-tolyl)propanoate 95%
  • Packaging10g
  • Price$416
  • Updated2021-12-16
  • Buy
  • ManufacturerCrysdot
  • Product numberCD12082779
  • Product descriptionEthyl3-oxo-3-(m-tolyl)propanoate 95%
  • Packaging25g
  • Price$832
  • Updated2021-12-16
  • Buy
  • ManufacturerMatrix Scientific
  • Product number079830
  • Product descriptionEthyl 3-(3-methylphenyl)-3-oxopropanoate
  • Packaging1g
  • Price$109
  • Updated2021-12-16
  • Buy
  • ManufacturerMatrix Scientific
  • Product number079830
  • Product descriptionEthyl 3-(3-methylphenyl)-3-oxopropanoate
  • Packaging5g
  • Price$452
  • Updated2021-12-16
  • Buy
  • ManufacturerSigma-Aldrich
  • Product number559180
  • Product descriptionEthyl (3-methylbenzoyl)acetate
  • Packaging1g
  • Price$55.6
  • Updated2024-03-01
  • Buy
  • ManufacturerTRC
  • Product numberE926713
  • Product descriptionEthyl3-Oxo-3-(m-tolyl)propanoate
  • Packaging500mg
  • Price$130
  • Updated2021-12-16
  • Buy
Manufacturer Product number Product description Packaging Price Updated Buy
Acrotein OP-0145 Ethyl (3-methylbenzoyl)acetate 97% 1g $82.5 2021-12-16 Buy
Acrotein OP-0145 Ethyl (3-methylbenzoyl)acetate 97% 5g $247.5 2021-12-16 Buy
AHH MT-20589 3-Oxo-3-(3-tolyl)propionicacidethylester 98% 0.5g $538 2021-12-16 Buy
AK Scientific B825 Ethyl (3-methylbenzoyl)acetate 5g $253 2021-12-16 Buy
American Custom Chemicals Corporation CHM0023997 3-OXO-3-(3-TOLYL)PROPIONIC ACID ETHYL ESTER 95.00% 1G $683.75 2021-12-16 Buy
Chemenu CM192716 Ethyl3-(3-methylphenyl)-3-oxopropanoate 95% 5g $224 2021-12-16 Buy
Chemenu CM192716 Ethyl3-(3-methylphenyl)-3-oxopropanoate 95% 10g $393 2021-12-16 Buy
Chemenu CM192716 Ethyl3-(3-methylphenyl)-3-oxopropanoate 95% 25g $785 2021-12-16 Buy
Crysdot CD12082779 Ethyl3-oxo-3-(m-tolyl)propanoate 95% 5g $238 2021-12-16 Buy
Crysdot CD12082779 Ethyl3-oxo-3-(m-tolyl)propanoate 95% 10g $416 2021-12-16 Buy
Crysdot CD12082779 Ethyl3-oxo-3-(m-tolyl)propanoate 95% 25g $832 2021-12-16 Buy
Matrix Scientific 079830 Ethyl 3-(3-methylphenyl)-3-oxopropanoate 1g $109 2021-12-16 Buy
Matrix Scientific 079830 Ethyl 3-(3-methylphenyl)-3-oxopropanoate 5g $452 2021-12-16 Buy
Sigma-Aldrich 559180 Ethyl (3-methylbenzoyl)acetate 1g $55.6 2024-03-01 Buy
TRC E926713 Ethyl3-Oxo-3-(m-tolyl)propanoate 500mg $130 2021-12-16 Buy

Properties

Boiling point :273-274 °C(lit.)
Density :1.083 g/mL at 25 °C(lit.)
refractive index :n20/D 1.5290(lit.)
Flash point :>230 °F
storage temp. :Sealed in dry,Room Temperature
CAS DataBase Reference :33166-79-9(CAS DataBase Reference)

Safety Information

Symbol(GHS): GHS hazard pictograms
Signal word: Warning
Hazard statements:
Code Hazard statements Hazard class Category Signal word Pictogram P-Codes
H315 Causes skin irritation Skin corrosion/irritation Category 2 Warning GHS hazard pictograms P264, P280, P302+P352, P321,P332+P313, P362
H319 Causes serious eye irritation Serious eye damage/eye irritation Category 2A Warning GHS hazard pictograms P264, P280, P305+P351+P338,P337+P313P
H335 May cause respiratory irritation Specific target organ toxicity, single exposure;Respiratory tract irritation Category 3 Warning GHS hazard pictograms
Precautionary statements:
P264 Wash hands thoroughly after handling.
P264 Wash skin thouroughly after handling.
P280 Wear protective gloves/protective clothing/eye protection/face protection.
P302+P352 IF ON SKIN: wash with plenty of soap and water.
P305+P351+P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.
P321 Specific treatment (see … on this label).
P332+P313 IF SKIN irritation occurs: Get medical advice/attention.
P362 Take off contaminated clothing and wash before reuse.

Description

Ethyl (3-methylbenzoyl)acetate is a reactant that has been used for stereoselective ketonization-olefination of indoles by Co/Mn-mediated oxidative cross-coupling of indoles via dioxygen activation. It has also been used in Enantioselective Michael reaction. Another use of it has been in SEGPhos-ruthenium-catalyzed asymmetric hydrogenation.