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ChemicalBook >> CAS DataBase List >> (R)-(6,6'-Dimethoxybiphenyl-2,2'-diyl)bis[bis(3,5-di-tert-butyl-4-methoxypheny

(R)-(6,6'-Dimethoxybiphenyl-2,2'-diyl)bis[bis(3,5-di-tert-butyl-4-methoxypheny

(R)-(6,6'-Dimethoxybiphenyl-2,2'-diyl)bis[bis(3,5-di-tert-butyl-4-methoxypheny price.
  • $74 - $3784
  • Product name: (R)-(6,6'-Dimethoxybiphenyl-2,2'-diyl)bis[bis(3,5-di-tert-butyl-4-methoxypheny
  • CAS: 352655-61-9
  • MF: C74H104O6P2
  • MW: 1151.56
  • EINECS:
  • MDL Number:MFCD09265029
  • Synonyms:(R)-(6,6'-Dimethoxybiphenyl-2,2'-diyl)bis[bis(3,5-di-tert-butyl-4-methoxypheny;(R)-(-)-2,2'-Bis[di(3,5-di-t-butyl-4-methoxyphenyl)phosphino]-6,6'-dimethoxy-1,1'-biphenyl,min.97%;(R)-(-)-2,2''-BIS[DI(3,5-DI-T-BUTYL-4-METHOXYPHENYL)PHOSPHINO]-6,6''-DIMETHOXY-1,1''-BIPHENYL, MIN. 97%;(S)-(6,6μ-Dimethoxybiphenyl-2,2μ-diyl)bis[bis(3,5-di-tert-butyl-4-methoxyphenyl)phosphine];(S)-3,5-t-Bu-4-MeO-MeOBIPHEP, SL-A109-2, (S)-[6,6μ-Dimethoxy(1,1μ-biphenyl)-2,2μ-diyl]bis{bis[3,5-bis(1,1-dimethylethyl)-4-methoxyphenyl]phosphine};(R)-(6,6μ-Dimethoxybiphenyl-2,2μ-diyl)bis[bis(3,5-di-tert-butyl-4-methoxyphenyl)phosphine];(R)-3,5-t-Bu-4-MeO-MeOBIPHEP, SL-A109-1, (R)-[6,6μ-Dimethoxy(1,1μ-biphenyl)-2,2μ-diyl]bis{bis[3,5-bis(1,1-dimethylethyl)-4-methoxyphenyl]phosphine};(R)-(-)-2,2'-Bis[di-(3,5-di-tert-butyl-4-methoxy-phenyl)phosphino]-(diphenylphosphino)-6,6'-dimethoxy-1,1'-biphenyl
Price18 Properties Safety Information Description
18 prices
Selected condition：
Brand
  • Ambeed
  • American Custom Chemicals Corporation
  • BLDpharm
  • Strem Chemicals
Package
  • 50mg
  • 100mg
  • 250mg
  • 500MG
  • 1g
  • 2G
  • 5g
  • 10g
  • ManufacturerAmbeed
  • Product numberA127511
  • Product description(R)-(-)-2,2'-Bis[di(3,5-di-t-butyl-4-methoxyphenyl)phosphino]-6,6'-dimethoxy-1,1'-biphenyl 98%
  • Packaging50mg
  • Price$80
  • Updated2021-12-16
  • Buy
  • ManufacturerAmbeed
  • Product numberA127511
  • Product description(R)-(-)-2,2'-Bis[di(3,5-di-t-butyl-4-methoxyphenyl)phosphino]-6,6'-dimethoxy-1,1'-biphenyl 98%
  • Packaging100mg
  • Price$132
  • Updated2021-12-16
  • Buy
  • ManufacturerAmbeed
  • Product numberA127511
  • Product description(R)-(-)-2,2'-Bis[di(3,5-di-t-butyl-4-methoxyphenyl)phosphino]-6,6'-dimethoxy-1,1'-biphenyl 98%
  • Packaging250mg
  • Price$285
  • Updated2021-12-16
  • Buy
  • ManufacturerAmbeed
  • Product numberA127511
  • Product description(R)-(-)-2,2'-Bis[di(3,5-di-t-butyl-4-methoxyphenyl)phosphino]-6,6'-dimethoxy-1,1'-biphenyl 98%
  • Packaging1g
  • Price$775
  • Updated2021-12-16
  • Buy
  • ManufacturerAmbeed
  • Product numberA127511
  • Product description(R)-(-)-2,2'-Bis[di(3,5-di-t-butyl-4-methoxyphenyl)phosphino]-6,6'-dimethoxy-1,1'-biphenyl 98%
  • Packaging5g
  • Price$2553
  • Updated2021-12-16
  • Buy
  • ManufacturerAmerican Custom Chemicals Corporation
  • Product numberING0001277
  • Product description(R)-(-)-2,2'-BIS[DI(3,5-DI-TERT-BUTYL-4-METHOXYPHENYL)PHOSPHINO]-6,6'-DIMETHOXY-1,1'-BIPHENYL 95.00%
  • Packaging100MG
  • Price$646.88
  • Updated2021-12-16
  • Buy
  • ManufacturerAmerican Custom Chemicals Corporation
  • Product numberING0001277
  • Product description(R)-(-)-2,2'-BIS[DI(3,5-DI-TERT-BUTYL-4-METHOXYPHENYL)PHOSPHINO]-6,6'-DIMETHOXY-1,1'-BIPHENYL 95.00%
  • Packaging500MG
  • Price$914.17
  • Updated2021-12-16
  • Buy
  • ManufacturerAmerican Custom Chemicals Corporation
  • Product numberING0001277
  • Product description(R)-(-)-2,2'-BIS[DI(3,5-DI-TERT-BUTYL-4-METHOXYPHENYL)PHOSPHINO]-6,6'-DIMETHOXY-1,1'-BIPHENYL 95.00%
  • Packaging1G
  • Price$1269.75
  • Updated2021-12-16
  • Buy
  • ManufacturerAmerican Custom Chemicals Corporation
  • Product numberING0001277
  • Product description(R)-(-)-2,2'-BIS[DI(3,5-DI-TERT-BUTYL-4-METHOXYPHENYL)PHOSPHINO]-6,6'-DIMETHOXY-1,1'-BIPHENYL 95.00%
  • Packaging2G
  • Price$1765
  • Updated2021-12-16
  • Buy
  • ManufacturerBLDpharm
  • Product numberBD633937
  • Product description(R)-(-)-2,2'-Bis[di(3,5-di-t-butyl-4-methoxyphenyl)phosphino]-6,6'-dimethoxy-1,1'-biphenyl 98%
  • Packaging50mg
  • Price$75
  • Updated2021-12-16
  • Buy
  • ManufacturerBLDpharm
  • Product numberBD633937
  • Product description(R)-(-)-2,2'-Bis[di(3,5-di-t-butyl-4-methoxyphenyl)phosphino]-6,6'-dimethoxy-1,1'-biphenyl 98%
  • Packaging100mg
  • Price$120
  • Updated2021-12-16
  • Buy
  • ManufacturerBLDpharm
  • Product numberBD633937
  • Product description(R)-(-)-2,2'-Bis[di(3,5-di-t-butyl-4-methoxyphenyl)phosphino]-6,6'-dimethoxy-1,1'-biphenyl 98%
  • Packaging250mg
  • Price$250
  • Updated2021-12-16
  • Buy
  • ManufacturerBLDpharm
  • Product numberBD633937
  • Product description(R)-(-)-2,2'-Bis[di(3,5-di-t-butyl-4-methoxyphenyl)phosphino]-6,6'-dimethoxy-1,1'-biphenyl 98%
  • Packaging1g
  • Price$695
  • Updated2021-12-16
  • Buy
  • ManufacturerBLDpharm
  • Product numberBD633937
  • Product description(R)-(-)-2,2'-Bis[di(3,5-di-t-butyl-4-methoxyphenyl)phosphino]-6,6'-dimethoxy-1,1'-biphenyl 98%
  • Packaging5g
  • Price$3128
  • Updated2021-12-16
  • Buy
  • ManufacturerStrem Chemicals
  • Product number15-0042
  • Product description(R)-(-)-2,2'-Bis[di(3,5-di-t-butyl-4-methoxyphenyl)phosphino]-6,6'-dimethoxy-1,1'-biphenyl, min. 97%
  • Packaging100mg
  • Price$74
  • Updated2021-12-16
  • Buy
  • ManufacturerStrem Chemicals
  • Product number15-0042
  • Product description(R)-(-)-2,2'-Bis[di(3,5-di-t-butyl-4-methoxyphenyl)phosphino]-6,6'-dimethoxy-1,1'-biphenyl, min. 97%
  • Packaging500mg
  • Price$278
  • Updated2021-12-16
  • Buy
Manufacturer Product number Product description Packaging Price Updated Buy
Ambeed A127511 (R)-(-)-2,2'-Bis[di(3,5-di-t-butyl-4-methoxyphenyl)phosphino]-6,6'-dimethoxy-1,1'-biphenyl 98% 50mg $80 2021-12-16 Buy
Ambeed A127511 (R)-(-)-2,2'-Bis[di(3,5-di-t-butyl-4-methoxyphenyl)phosphino]-6,6'-dimethoxy-1,1'-biphenyl 98% 100mg $132 2021-12-16 Buy
Ambeed A127511 (R)-(-)-2,2'-Bis[di(3,5-di-t-butyl-4-methoxyphenyl)phosphino]-6,6'-dimethoxy-1,1'-biphenyl 98% 250mg $285 2021-12-16 Buy
Ambeed A127511 (R)-(-)-2,2'-Bis[di(3,5-di-t-butyl-4-methoxyphenyl)phosphino]-6,6'-dimethoxy-1,1'-biphenyl 98% 1g $775 2021-12-16 Buy
Ambeed A127511 (R)-(-)-2,2'-Bis[di(3,5-di-t-butyl-4-methoxyphenyl)phosphino]-6,6'-dimethoxy-1,1'-biphenyl 98% 5g $2553 2021-12-16 Buy
American Custom Chemicals Corporation ING0001277 (R)-(-)-2,2'-BIS[DI(3,5-DI-TERT-BUTYL-4-METHOXYPHENYL)PHOSPHINO]-6,6'-DIMETHOXY-1,1'-BIPHENYL 95.00% 100MG $646.88 2021-12-16 Buy
American Custom Chemicals Corporation ING0001277 (R)-(-)-2,2'-BIS[DI(3,5-DI-TERT-BUTYL-4-METHOXYPHENYL)PHOSPHINO]-6,6'-DIMETHOXY-1,1'-BIPHENYL 95.00% 500MG $914.17 2021-12-16 Buy
American Custom Chemicals Corporation ING0001277 (R)-(-)-2,2'-BIS[DI(3,5-DI-TERT-BUTYL-4-METHOXYPHENYL)PHOSPHINO]-6,6'-DIMETHOXY-1,1'-BIPHENYL 95.00% 1G $1269.75 2021-12-16 Buy
American Custom Chemicals Corporation ING0001277 (R)-(-)-2,2'-BIS[DI(3,5-DI-TERT-BUTYL-4-METHOXYPHENYL)PHOSPHINO]-6,6'-DIMETHOXY-1,1'-BIPHENYL 95.00% 2G $1765 2021-12-16 Buy
BLDpharm BD633937 (R)-(-)-2,2'-Bis[di(3,5-di-t-butyl-4-methoxyphenyl)phosphino]-6,6'-dimethoxy-1,1'-biphenyl 98% 50mg $75 2021-12-16 Buy
BLDpharm BD633937 (R)-(-)-2,2'-Bis[di(3,5-di-t-butyl-4-methoxyphenyl)phosphino]-6,6'-dimethoxy-1,1'-biphenyl 98% 100mg $120 2021-12-16 Buy
BLDpharm BD633937 (R)-(-)-2,2'-Bis[di(3,5-di-t-butyl-4-methoxyphenyl)phosphino]-6,6'-dimethoxy-1,1'-biphenyl 98% 250mg $250 2021-12-16 Buy
BLDpharm BD633937 (R)-(-)-2,2'-Bis[di(3,5-di-t-butyl-4-methoxyphenyl)phosphino]-6,6'-dimethoxy-1,1'-biphenyl 98% 1g $695 2021-12-16 Buy
BLDpharm BD633937 (R)-(-)-2,2'-Bis[di(3,5-di-t-butyl-4-methoxyphenyl)phosphino]-6,6'-dimethoxy-1,1'-biphenyl 98% 5g $3128 2021-12-16 Buy
Strem Chemicals 15-0042 (R)-(-)-2,2'-Bis[di(3,5-di-t-butyl-4-methoxyphenyl)phosphino]-6,6'-dimethoxy-1,1'-biphenyl, min. 97% 100mg $74 2021-12-16 Buy
Strem Chemicals 15-0042 (R)-(-)-2,2'-Bis[di(3,5-di-t-butyl-4-methoxyphenyl)phosphino]-6,6'-dimethoxy-1,1'-biphenyl, min. 97% 500mg $278 2021-12-16 Buy
Next Last

Properties

Boiling point :951.5±65.0 °C(Predicted)
form :crystal
color :white

Safety Information

Symbol(GHS): GHS hazard pictograms
Signal word: Warning
Hazard statements:
Code Hazard statements Hazard class Category Signal word Pictogram P-Codes
H302 Harmful if swallowed Acute toxicity,oral Category 4 Warning GHS hazard pictograms P264, P270, P301+P312, P330, P501
H315 Causes skin irritation Skin corrosion/irritation Category 2 Warning GHS hazard pictograms P264, P280, P302+P352, P321,P332+P313, P362
H319 Causes serious eye irritation Serious eye damage/eye irritation Category 2A Warning GHS hazard pictograms P264, P280, P305+P351+P338,P337+P313P
H335 May cause respiratory irritation Specific target organ toxicity, single exposure;Respiratory tract irritation Category 3 Warning GHS hazard pictograms
Precautionary statements:
P261 Avoid breathing dust/fume/gas/mist/vapours/spray.
P280 Wear protective gloves/protective clothing/eye protection/face protection.
P301+P312 IF SWALLOWED: call a POISON CENTER or doctor/physician IF you feel unwell.
P302+P352 IF ON SKIN: wash with plenty of soap and water.
P305+P351+P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

Description

Atropisomeric MeOBIPHEP ligands

  • Asymmetrical conjugate addition of arylboronic acids to maleimides and enones catalyzed by rhodium complexes
  • Intramolecular ketone hydroacylation
  • Desymmetrization through enantioselective C-C bond activation and ring expansion of allenyl cyclobutanols
  • Hydroamination of bicyclic alkenes and dienes with anilines
  • 1,4-addition/asymmetric protonation of amino acrylates

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Suppliers and manufacturers

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Aladdin Scientific J & K SCIENTIFIC LTD. Energy Chemical Bide Pharmatech Ltd. Sigma-Aldrich Zhengzhou Kingorgchem Chemical Technology Co., Ltd.gy Co., Ltd. LaaJoo Aikon International Limited