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ChemicalBook >> CAS DataBase List >> (s,s)-2-ALLYL-2-CHLORO-3,4-DIMETHYL-5-PHENYL-[1,3,2]-OXAZASILOLIDINE

(s,s)-2-ALLYL-2-CHLORO-3,4-DIMETHYL-5-PHENYL-[1,3,2]-OXAZASILOLIDINE

(s,s)-2-ALLYL-2-CHLORO-3,4-DIMETHYL-5-PHENYL-[1,3,2]-OXAZASILOLIDINE price.
  • $99 - $395
  • Product name: (s,s)-2-ALLYL-2-CHLORO-3,4-DIMETHYL-5-PHENYL-[1,3,2]-OXAZASILOLIDINE
  • CAS: 447440-43-9
  • MF: C13H18ClNOSi
  • MW: 267.83
  • EINECS:
  • MDL Number:MFCD09953823
  • Synonyms:(s,s)-2-ALLYL-2-CHLORO-3,4-DIMETHYL-5-PHENYL-[1,3,2]-OXAZASILOLIDINE;(4S,5S)-2-Allyl-2-chloro-3,4-dimethyl-5-phenyl-1-oxa-3-aza-2-silacyclopentane ;1-Oxa-3-aza-2-silacyclopentane,2-chloro-3,4-dimethyl-5-pheny...;(4S,5S)-2-chloro-3,4-dimethyl-5-phenyl-2-prop-2-enyl-1,3,2-oxazasilolidine;(4S,5S)-2-Allyl-2-chloro-3,4-dimethyl-5-phenyl-1,3,2-oxazasilolidine;1-Oxa-3-aza-2-silacyclopentane, 2-chloro-3,4-dimethyl-5-phenyl-2-(2-propen-1-yl)-, (4S,5S)-;(4S,5S)-2-Allyl-2-chloro-3,4-dimethyl-5-phenyl-1-oxa-3-aza-2-silacyclopentane;(4S,5S)-2-Allyl-2-chloro-3,4-dimethyl-5-phenyl-1-oxa-3-aza-2-silacyclopentane, CAS 447440-43-9
Price2 Properties Safety Information Description
2 prices
Selected condition：
Brand
  • Strem Chemicals
Package
  • 1g
  • 5g
  • ManufacturerStrem Chemicals
  • Product number14-1815
  • Product description(4S,5S)-2-Allyl-2-chloro-3,4-dimethyl-5-phenyl-1-oxa-3-aza-2-silacyclopentane, min. 98% (~2:1 mixture of diastereomers)
  • Packaging1g
  • Price$99
  • Updated2024-03-01
  • Buy
  • ManufacturerStrem Chemicals
  • Product number14-1815
  • Product description(4S,5S)-2-Allyl-2-chloro-3,4-dimethyl-5-phenyl-1-oxa-3-aza-2-silacyclopentane, min. 98% (~2:1 mixture of diastereomers)
  • Packaging5g
  • Price$395
  • Updated2024-03-01
  • Buy
Manufacturer Product number Product description Packaging Price Updated Buy
Strem Chemicals 14-1815 (4S,5S)-2-Allyl-2-chloro-3,4-dimethyl-5-phenyl-1-oxa-3-aza-2-silacyclopentane, min. 98% (~2:1 mixture of diastereomers) 1g $99 2024-03-01 Buy
Strem Chemicals 14-1815 (4S,5S)-2-Allyl-2-chloro-3,4-dimethyl-5-phenyl-1-oxa-3-aza-2-silacyclopentane, min. 98% (~2:1 mixture of diastereomers) 5g $395 2024-03-01 Buy

Properties

Density :1.095 g/mL at 25 °C
refractive index :n20/D1.517
Flash point :38℃
pka :4.43±0.60(Predicted)
form :liquid
Specific Gravity :1.01
optical activity :[α]20/D 72.5°, c = 0.6 in ethanol (200 proof)
Sensitive :moisture sensitive, store cold
Hydrolytic Sensitivity :8: reacts rapidly with moisture, water, protic solvents
Boiling point :120°C/5 mmHg
InChI :1S/C13H18ClNOSi/c1-4-10-17(14)15(3)11(2)13(16-17)12-8-6-5-7-9-12/h4-9,11,13H,1,10H2,2-3H3/t11-,13+,17/m0/s1
InChIKey :XHCRAANIMMYPDV-APBZJUGRSA-N
SMILES :C[C@H]1[C@@H](O[Si](Cl)(CC=C)N1C)c2ccccc2

Safety Information

Symbol(GHS): GHS hazard pictogramsGHS hazard pictograms
Signal word: Danger
Hazard statements:
Code Hazard statements Hazard class Category Signal word Pictogram P-Codes
H226 Flammable liquid and vapour Flammable liquids Category 3 Warning
H261 In contact with water releases flammable gas Substances And Mixtures Which, In Contact With Water,Emit Flammable Gases Category 2
Category 3		 Danger
Warning		 GHS hazard pictograms P231+P232, P280, P370+P378,P402+P404, P501
H315 Causes skin irritation Skin corrosion/irritation Category 2 Warning GHS hazard pictograms P264, P280, P302+P352, P321,P332+P313, P362
H319 Causes serious eye irritation Serious eye damage/eye irritation Category 2A Warning GHS hazard pictograms P264, P280, P305+P351+P338,P337+P313P
H335 May cause respiratory irritation Specific target organ toxicity, single exposure;Respiratory tract irritation Category 3 Warning GHS hazard pictograms
Precautionary statements:
P231+P232 Handle under inert gas. Protect from moisture.
P261 Avoid breathing dust/fume/gas/mist/vapours/spray.
P305+P351+P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.
P422 Store contents under …

Description

Reagent used in the enantioselective allylation of aldehydes

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