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ChemicalBook >> CAS DataBase List >> (R,R)-(-)-2,3-Bis(t-butylmethylphosphino)quinoxaline

(R,R)-(-)-2,3-Bis(t-butylmethylphosphino)quinoxaline

(R,R)-(-)-2,3-Bis(t-butylmethylphosphino)quinoxaline price.
  • $55 - $1643
  • Product name: (R,R)-(-)-2,3-Bis(t-butylmethylphosphino)quinoxaline
  • CAS: 866081-62-1
  • MF: C18H28N2P2
  • MW: 334.38
  • EINECS:
  • MDL Number:MFCD10565649
  • Synonyms:(R) QuinoxP;2,3-Bis((R)-tert-butyl(methyl)phosphino)quinoxaline;(R,R)-(-)-2,3-Bis(tert-butylmethylphosphino)quinoxaline 97%;(R,R)-(-)-2,3-Bis(t-butylmethylphosphino)quinoxaline;(R,R)-QuinoxP*;(R) QuinoxP(R);(R,R)-(-)-2,3-Bis(tert-butylmethylphosphino)quinoxaline;(R,R)-(-)-2,3-Bis(t-butylmethylphosphino)quinoxaline, min. 98% (R,R)-QuinoxP*
19 prices
Selected condition:
Brand
  • Alichem
  • Ambeed
  • Chemenu
  • Chem-Impex
  • Crysdot
  • Sigma-Aldrich
  • Strem Chemicals
  • TCI Chemical
  • TRC
Package
  • 10mg
  • 50mg
  • 100mg
  • 250mg
  • 500mg
  • 1g
  • ManufacturerAlichem
  • Product number866081621
  • Product description2,3-Bis((R)-tert-butyl(methyl)phosphino)quinoxaline
  • Packaging100mg
  • Price$388
  • Updated2021-12-16
  • Buy
  • ManufacturerAlichem
  • Product number866081621
  • Product description2,3-Bis((R)-tert-butyl(methyl)phosphino)quinoxaline
  • Packaging250mg
  • Price$626.2
  • Updated2021-12-16
  • Buy
  • ManufacturerAlichem
  • Product number866081621
  • Product description2,3-Bis((R)-tert-butyl(methyl)phosphino)quinoxaline
  • Packaging1g
  • Price$1643
  • Updated2021-12-16
  • Buy
  • ManufacturerAmbeed
  • Product numberA578539
  • Product description2,3-Bis((R)-tert-butyl(methyl)phosphino)quinoxaline 98%
  • Packaging50mg
  • Price$76
  • Updated2021-12-16
  • Buy
  • ManufacturerAmbeed
  • Product numberA578539
  • Product description2,3-Bis((R)-tert-butyl(methyl)phosphino)quinoxaline 98%
  • Packaging100mg
  • Price$98
  • Updated2021-12-16
  • Buy
  • ManufacturerAmbeed
  • Product numberA578539
  • Product description2,3-Bis((R)-tert-butyl(methyl)phosphino)quinoxaline 98%
  • Packaging250mg
  • Price$196
  • Updated2021-12-16
  • Buy
  • ManufacturerAmbeed
  • Product numberA578539
  • Product description2,3-Bis((R)-tert-butyl(methyl)phosphino)quinoxaline 98%
  • Packaging500mg
  • Price$388
  • Updated2021-12-16
  • Buy
  • ManufacturerAmbeed
  • Product numberA578539
  • Product description2,3-Bis((R)-tert-butyl(methyl)phosphino)quinoxaline 98%
  • Packaging1g
  • Price$719
  • Updated2021-12-16
  • Buy
  • ManufacturerChemenu
  • Product numberCM221138
  • Product description2,3-Bis((R)-tert-butyl(methyl)phosphino)quinoxaline 95%
  • Packaging1g
  • Price$1449
  • Updated2021-12-16
  • Buy
  • ManufacturerChem-Impex
  • Product number41172
  • Product description(R,R)-(-)-2,3-Bis(tert-butylmethylphosphino)quinoxaline,≥98%(HPLC) ≥98%(HPLC)
  • Packaging100MG
  • Price$223.64
  • Updated2021-12-16
  • Buy
  • ManufacturerCrysdot
  • Product numberCD51000260
  • Product description2,3-Bis((R)-tert-butyl(methyl)phosphino)quinoxaline 95+%
  • Packaging100mg
  • Price$388
  • Updated2021-12-16
  • Buy
  • ManufacturerCrysdot
  • Product numberCD51000260
  • Product description2,3-Bis((R)-tert-butyl(methyl)phosphino)quinoxaline 95+%
  • Packaging250mg
  • Price$620
  • Updated2021-12-16
  • Buy
  • ManufacturerCrysdot
  • Product numberCD51000260
  • Product description2,3-Bis((R)-tert-butyl(methyl)phosphino)quinoxaline 95+%
  • Packaging1g
  • Price$1550
  • Updated2021-12-16
  • Buy
  • ManufacturerSigma-Aldrich
  • Product number676403
  • Product description(R,R)-(–)-2,3-Bis(tert-butylmethylphosphino)quinoxaline 97%
  • Packaging100mg
  • Price$102.6
  • Updated2024-03-01
  • Buy
  • ManufacturerSigma-Aldrich
  • Product number676403
  • Product description(R,R)-(–)-2,3-Bis(tert-butylmethylphosphino)quinoxaline 97%
  • Packaging500mg
  • Price$278.4
  • Updated2024-03-01
  • Buy
  • ManufacturerStrem Chemicals
  • Product number15-0126
  • Product description(R,R)-(-)-2,3-Bis(t-butylmethylphosphino)quinoxaline, min. 98% (R,R)-QuinoxP*
  • Packaging100mg
  • Price$116
  • Updated2024-03-01
  • Buy
Manufacturer Product number Product description Packaging Price Updated Buy
Alichem 866081621 2,3-Bis((R)-tert-butyl(methyl)phosphino)quinoxaline 100mg $388 2021-12-16 Buy
Alichem 866081621 2,3-Bis((R)-tert-butyl(methyl)phosphino)quinoxaline 250mg $626.2 2021-12-16 Buy
Alichem 866081621 2,3-Bis((R)-tert-butyl(methyl)phosphino)quinoxaline 1g $1643 2021-12-16 Buy
Ambeed A578539 2,3-Bis((R)-tert-butyl(methyl)phosphino)quinoxaline 98% 50mg $76 2021-12-16 Buy
Ambeed A578539 2,3-Bis((R)-tert-butyl(methyl)phosphino)quinoxaline 98% 100mg $98 2021-12-16 Buy
Ambeed A578539 2,3-Bis((R)-tert-butyl(methyl)phosphino)quinoxaline 98% 250mg $196 2021-12-16 Buy
Ambeed A578539 2,3-Bis((R)-tert-butyl(methyl)phosphino)quinoxaline 98% 500mg $388 2021-12-16 Buy
Ambeed A578539 2,3-Bis((R)-tert-butyl(methyl)phosphino)quinoxaline 98% 1g $719 2021-12-16 Buy
Chemenu CM221138 2,3-Bis((R)-tert-butyl(methyl)phosphino)quinoxaline 95% 1g $1449 2021-12-16 Buy
Chem-Impex 41172 (R,R)-(-)-2,3-Bis(tert-butylmethylphosphino)quinoxaline,≥98%(HPLC) ≥98%(HPLC) 100MG $223.64 2021-12-16 Buy
Crysdot CD51000260 2,3-Bis((R)-tert-butyl(methyl)phosphino)quinoxaline 95+% 100mg $388 2021-12-16 Buy
Crysdot CD51000260 2,3-Bis((R)-tert-butyl(methyl)phosphino)quinoxaline 95+% 250mg $620 2021-12-16 Buy
Crysdot CD51000260 2,3-Bis((R)-tert-butyl(methyl)phosphino)quinoxaline 95+% 1g $1550 2021-12-16 Buy
Sigma-Aldrich 676403 (R,R)-(–)-2,3-Bis(tert-butylmethylphosphino)quinoxaline 97% 100mg $102.6 2024-03-01 Buy
Sigma-Aldrich 676403 (R,R)-(–)-2,3-Bis(tert-butylmethylphosphino)quinoxaline 97% 500mg $278.4 2024-03-01 Buy
Strem Chemicals 15-0126 (R,R)-(-)-2,3-Bis(t-butylmethylphosphino)quinoxaline, min. 98% (R,R)-QuinoxP* 100mg $116 2024-03-01 Buy

Properties

Melting point :100-104 °C
Boiling point :447.6±45.0 °C(Predicted)
alpha :-54.3° (c 1.0, CHCl3)
storage temp. :Inert atmosphere,Room Temperature
pka :-0.54±0.59(Predicted)
form :Powder
color :orange
InChIKey :DRZBLHZZDMCPGX-UHFFFAOYSA-N

Safety Information

Symbol(GHS): GHS hazard pictograms
Signal word: Danger
Hazard statements:
Code Hazard statements Hazard class Category Signal word Pictogram P-Codes
H301 Toxic if swalloed Acute toxicity,oral Category 3 Danger GHS hazard pictograms P264, P270, P301+P310, P321, P330,P405, P501
H315 Causes skin irritation Skin corrosion/irritation Category 2 Warning GHS hazard pictograms P264, P280, P302+P352, P321,P332+P313, P362
H319 Causes serious eye irritation Serious eye damage/eye irritation Category 2A Warning GHS hazard pictograms P264, P280, P305+P351+P338,P337+P313P
H335 May cause respiratory irritation Specific target organ toxicity, single exposure;Respiratory tract irritation Category 3 Warning GHS hazard pictograms
H413 May cause long lasting harmful effects to aquatic life Hazardous to the aquatic environment, long-term hazard Category 4
Precautionary statements:
P273 Avoid release to the environment.
P302+P352 IF ON SKIN: wash with plenty of soap and water.
P305+P351+P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

Description

(R,R)-(-)-2,3-Bis(tert-butylmethylphosphino)quinoxaline is an efficient ligand exhibiting high levels of enantiocontrol in synthetic transformations ranging from metal-catalyzed 1,4-addition of arylboronic acids to asymmetric hydrogenation to alkylative ring opening.

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