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ChemicalBook >> CAS DataBase List >> (11BR)-2,6-BIS(DIPHENYLPHOSPHINO)-N,N-DIMETHYLDINAPHTHO(2,1-D:1',2'-F)-1,3,2-DIOXAPHOSPHEPIN-4-AMINE, KANATA PURITY

(11BR)-2,6-BIS(DIPHENYLPHOSPHINO)-N,N-DIMETHYLDINAPHTHO(2,1-D:1',2'-F)-1,3,2-DIOXAPHOSPHEPIN-4-AMINE, KANATA PURITY

(11BR)-2,6-BIS(DIPHENYLPHOSPHINO)-N,N-DIMETHYLDINAPHTHO(2,1-D:1',2'-F)-1,3,2-DIOXAPHOSPHEPIN-4-AMINE, KANATA PURITY price.
  • $47 - $1181.22
  • Product name: (11BR)-2,6-BIS(DIPHENYLPHOSPHINO)-N,N-DIMETHYLDINAPHTHO(2,1-D:1',2'-F)-1,3,2-DIOXAPHOSPHEPIN-4-AMINE, KANATA PURITY
  • CAS: 913617-04-6
  • MF: C46H36NO2P3
  • MW: 727.72
  • EINECS:
  • MDL Number:MFCD09750461
  • Synonyms:(11BR)-2,6-BIS(DIPHENYLPHOSPHINO)-N,N-DIMETHYLDINAPHTHO(2,1-D:1',2'-F)-1,3,2-DIOXAPHOSPHEPIN-4-AMINE, KANATA PURITY;(11bR)-2,6-Bis(diphenylphosphino)-N,N-dimethyldinaphtho[2,1-d:1μ,2μ-f]-1,3,2-dioxaphosphepin-4-amine;Dinaphtho[2,1-d:1',2'-f][1,3,2]dioxaphosphepin-4-amine, 2,6-bis(diphenylphosphino)-N,N-dimethyl-, (11bR)-;(11bR)-2,6-Bis(diphenylphosphino)-N,N-dimethyldinaphtho[2,1-d:1',2'-f][1,3,2]dioxaphosphepin-4-amine;(11bR)-2,6-Bis(diphenylphosphino)-N,N-dimethyldinaphtho[2,1-d:1′,2′-f]-1,3,2-dioxaphosphepin-4-amine;(11bR)-2,6-Bis(diphenylphosphino)-N,N-dimethyldinaphtho[2,1-d:1′,2′-f]-1,3,2-dioxaphosphepin-4-amine, CAS 913617-04-6
Price8 Properties Safety Information Description
8 prices
Selected condition：
Brand
  • Ambeed
  • American Custom Chemicals Corporation
  • Sigma-Aldrich
Package
  • 50mg
  • 100mg
  • 250mg
  • 500MG
  • 1g
  • ManufacturerAmbeed
  • Product numberA1006200
  • Product description(11bR)-2,6-Bis(diphenylphosphino)-N,N-dimethyldinaphtho[2,1-d:1',2'-f][1,3,2]dioxaphosphepin-4-amine 97%
  • Packaging50mg
  • Price$47
  • Updated2021-12-16
  • Buy
  • ManufacturerAmbeed
  • Product numberA1006200
  • Product description(11bR)-2,6-Bis(diphenylphosphino)-N,N-dimethyldinaphtho[2,1-d:1',2'-f][1,3,2]dioxaphosphepin-4-amine 97%
  • Packaging100mg
  • Price$90
  • Updated2021-12-16
  • Buy
  • ManufacturerAmbeed
  • Product numberA1006200
  • Product description(11bR)-2,6-Bis(diphenylphosphino)-N,N-dimethyldinaphtho[2,1-d:1',2'-f][1,3,2]dioxaphosphepin-4-amine 97%
  • Packaging250mg
  • Price$185
  • Updated2021-12-16
  • Buy
  • ManufacturerAmbeed
  • Product numberA1006200
  • Product description(11bR)-2,6-Bis(diphenylphosphino)-N,N-dimethyldinaphtho[2,1-d:1',2'-f][1,3,2]dioxaphosphepin-4-amine 97%
  • Packaging1g
  • Price$590
  • Updated2021-12-16
  • Buy
  • ManufacturerAmerican Custom Chemicals Corporation
  • Product numberCCH0005077
  • Product description(11BR)-2,6-BIS(DIPHENYLPHOSPHINO)-N,N-DIMETHYLDINAPHTHO(2,1-D,1',2'-F)-1,3,2-DIOXAPHOSPHEPIN-4-AMINE 95.00%
  • Packaging100MG
  • Price$750.09
  • Updated2021-12-16
  • Buy
  • ManufacturerAmerican Custom Chemicals Corporation
  • Product numberCCH0005077
  • Product description(11BR)-2,6-BIS(DIPHENYLPHOSPHINO)-N,N-DIMETHYLDINAPHTHO(2,1-D,1',2'-F)-1,3,2-DIOXAPHOSPHEPIN-4-AMINE 95.00%
  • Packaging500MG
  • Price$1181.22
  • Updated2021-12-16
  • Buy
  • ManufacturerSigma-Aldrich
  • Product number683248
  • Product description(11bR)-2,6-Bis(diphenylphosphino)-N,N-dimethyldinaphtho[2,1-d:1′,2′-f]-1,3,2-dioxaphosphepin-4-amine
  • Packaging100mg
  • Price$105
  • Updated2023-06-20
  • Buy
  • ManufacturerSigma-Aldrich
  • Product number683248
  • Product description(11bR)-2,6-Bis(diphenylphosphino)-N,N-dimethyldinaphtho[2,1-d:1′,2′-f]-1,3,2-dioxaphosphepin-4-amine
  • Packaging500mg
  • Price$284
  • Updated2026-03-19
  • Buy
Manufacturer Product number Product description Packaging Price Updated Buy
Ambeed A1006200 (11bR)-2,6-Bis(diphenylphosphino)-N,N-dimethyldinaphtho[2,1-d:1',2'-f][1,3,2]dioxaphosphepin-4-amine 97% 50mg $47 2021-12-16 Buy
Ambeed A1006200 (11bR)-2,6-Bis(diphenylphosphino)-N,N-dimethyldinaphtho[2,1-d:1',2'-f][1,3,2]dioxaphosphepin-4-amine 97% 100mg $90 2021-12-16 Buy
Ambeed A1006200 (11bR)-2,6-Bis(diphenylphosphino)-N,N-dimethyldinaphtho[2,1-d:1',2'-f][1,3,2]dioxaphosphepin-4-amine 97% 250mg $185 2021-12-16 Buy
Ambeed A1006200 (11bR)-2,6-Bis(diphenylphosphino)-N,N-dimethyldinaphtho[2,1-d:1',2'-f][1,3,2]dioxaphosphepin-4-amine 97% 1g $590 2021-12-16 Buy
American Custom Chemicals Corporation CCH0005077 (11BR)-2,6-BIS(DIPHENYLPHOSPHINO)-N,N-DIMETHYLDINAPHTHO(2,1-D,1',2'-F)-1,3,2-DIOXAPHOSPHEPIN-4-AMINE 95.00% 100MG $750.09 2021-12-16 Buy
American Custom Chemicals Corporation CCH0005077 (11BR)-2,6-BIS(DIPHENYLPHOSPHINO)-N,N-DIMETHYLDINAPHTHO(2,1-D,1',2'-F)-1,3,2-DIOXAPHOSPHEPIN-4-AMINE 95.00% 500MG $1181.22 2021-12-16 Buy
Sigma-Aldrich 683248 (11bR)-2,6-Bis(diphenylphosphino)-N,N-dimethyldinaphtho[2,1-d:1′,2′-f]-1,3,2-dioxaphosphepin-4-amine 100mg $105 2023-06-20 Buy
Sigma-Aldrich 683248 (11bR)-2,6-Bis(diphenylphosphino)-N,N-dimethyldinaphtho[2,1-d:1′,2′-f]-1,3,2-dioxaphosphepin-4-amine 500mg $284 2026-03-19 Buy

Properties

Melting point :245-249 °C
storage temp. :2-8°C
form :solid
pka :0.85±0.20(Predicted)
Appearance :White to off-white Solid
InChIKey :JVTXDRKUFXCFCF-UHFFFAOYSA-N
SMILES :CN(C)P1Oc2c(cc3ccccc3c2-c4c(O1)c(cc5ccccc45)P(c6ccccc6)c7ccccc7)P(c8ccccc8)c9ccccc9

Safety Information

Symbol(GHS): GHS hazard pictograms
Signal word: Warning
Hazard statements:
Code Hazard statements Hazard class Category Signal word Pictogram P-Codes
H302 Harmful if swallowed Acute toxicity,oral Category 4 Warning GHS hazard pictograms P264, P270, P301+P312, P330, P501
H315 Causes skin irritation Skin corrosion/irritation Category 2 Warning GHS hazard pictograms P264, P280, P302+P352, P321,P332+P313, P362
H319 Causes serious eye irritation Serious eye damage/eye irritation Category 2A Warning GHS hazard pictograms P264, P280, P305+P351+P338,P337+P313P
H335 May cause respiratory irritation Specific target organ toxicity, single exposure;Respiratory tract irritation Category 3 Warning GHS hazard pictograms
Precautionary statements:
P261 Avoid breathing dust/fume/gas/mist/vapours/spray.
P280 Wear protective gloves/protective clothing/eye protection/face protection.
P301+P312 IF SWALLOWED: call a POISON CENTER or doctor/physician IF you feel unwell.
P302+P352 IF ON SKIN: wash with plenty of soap and water.
P305+P351+P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

Description

(11bR)-2,6-Bis(diphenylphosphino)-N,N-dimethyldinaphtho[2,1-d:1′,2′-f]-1,3,2-dioxaphosphepin-4-amine is a phosphine-phosphoramidite ligand, which can be used in:
  • The stereoselective preparation of aminoesters via rhodium-catalyzed enantioselective hydrogenation of dehydroaminoesters.
  • The Rh-catalyzed asymmetric hydrogenation of N-(α-arylvinyl) acetamides.

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Suppliers and manufacturers

Wuhan Topule Biopharmaceutical Co., Ltd
Aladdin Scientific Tianjin Derchemist Science & Technology Co., Ltd. Sigma-Aldrich Shanghai Haohong Pharmaceutical Co., Ltd. Shanghai Anyinuo Biomedical Technology Co., Ltd. Henan Weituxi Chemical Technology Co., Ltd. Beijing Jin Ming Biotechnology Co., Ltd. Wuhan Augda Biotechnology Co., Ltd Bide Pharmatech Ltd.