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ChemicalBook >> CAS DataBase List >> o-Phenylenediamine

o-Phenylenediamine

o-Phenylenediamine price.
  • $9 - $675
  • Product name: o-Phenylenediamine
  • CAS: 95-54-5
  • MF: C6H8N2
  • MW: 108.14
  • EINECS:202-430-6
  • MDL Number:MFCD00007721
  • Synonyms:1,2-Diaminobenzene, o-Phenylenediamine, OPD;1,2-Fenylendiamin;benzene,1,2-diamino- ;diamino-1,2benzene ;EK 1700;ek1700 ;sq15500 ;PHENYLENEDIAMINE(O-)
44 prices
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Brand
  • AHH
  • AK Scientific
  • Alfa Aesar
  • Chem-Impex
  • Matrix Scientific
  • Medical Isotopes, Inc.
  • Oakwood
  • Sigma-Aldrich
  • TCI Chemical
  • TRC
Package
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  • 50tablets
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  • ManufacturerAHH
  • Product numberMB-03481
  • Product descriptionbenzene-1,2-diamine 97%
  • Packaging1Kg
  • Price$125
  • Updated2021-12-16
  • Buy
  • ManufacturerAK Scientific
  • Product numberJ54149
  • Product descriptiono-Phenylenediamine
  • Packaging25g
  • Price$15
  • Updated2021-12-16
  • Buy
  • ManufacturerAK Scientific
  • Product numberH444
  • Product descriptiono-Phenylenediamine
  • Packaging500g
  • Price$75
  • Updated2021-12-16
  • Buy
  • ManufacturerAlfa Aesar
  • Product numberA11946
  • Product descriptiono-Phenylenediamine, 98%
  • Packaging25g
  • Price$32.8
  • Updated2024-03-01
  • Buy
  • ManufacturerAlfa Aesar
  • Product numberA11946
  • Product descriptiono-Phenylenediamine, 98%
  • Packaging250g
  • Price$55
  • Updated2024-03-01
  • Buy
  • ManufacturerAlfa Aesar
  • Product numberA11946
  • Product descriptiono-Phenylenediamine, 98%
  • Packaging1000g
  • Price$138
  • Updated2024-03-01
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  • ManufacturerAlfa Aesar
  • Product numberA11946
  • Product descriptiono-Phenylenediamine, 98%
  • Packaging5000g
  • Price$555
  • Updated2024-03-01
  • Buy
  • ManufacturerChem-Impex
  • Product number31478
  • Product descriptiono-Phenylenediamine,≥99%(GC)Hazmat ≥99%(GC)
  • Packaging100G
  • Price$16.6
  • Updated2021-12-16
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  • ManufacturerChem-Impex
  • Product number40899
  • Product description1,2-Phenylenediamine,≥98%(GC)Hazmat ≥98%(GC)
  • Packaging25G
  • Price$17.47
  • Updated2021-12-16
  • Buy
  • ManufacturerChem-Impex
  • Product number31478
  • Product descriptiono-Phenylenediamine,99%(GC) 99%(GC)
  • Packaging250G
  • Price$26.6
  • Updated2021-12-16
  • Buy
  • ManufacturerChem-Impex
  • Product number40899
  • Product description1,2-Phenylenediamine,98%(GC) 98%(GC)
  • Packaging100G
  • Price$32.48
  • Updated2021-12-16
  • Buy
  • ManufacturerChem-Impex
  • Product number31478
  • Product descriptiono-Phenylenediamine,≥99%(GC)Hazmat ≥99%(GC)
  • Packaging1KG
  • Price$82.99
  • Updated2021-12-16
  • Buy
  • ManufacturerChem-Impex
  • Product number40899
  • Product description1,2-Phenylenediamine,98%(GC) 98%(GC)
  • Packaging500G
  • Price$96.32
  • Updated2021-12-16
  • Buy
  • ManufacturerChem-Impex
  • Product number31478
  • Product descriptiono-Phenylenediamine,99%(GC) 99%(GC)
  • Packaging2.5KG
  • Price$175.56
  • Updated2021-12-16
  • Buy
  • ManufacturerChem-Impex
  • Product number31478
  • Product descriptiono-Phenylenediamine,99%(GC) 99%(GC)
  • Packaging5KG
  • Price$313.88
  • Updated2021-12-16
  • Buy
  • ManufacturerChem-Impex
  • Product number31478
  • Product descriptiono-Phenylenediamine,99%(GC) 99%(GC)
  • Packaging10KG
  • Price$595.84
  • Updated2021-12-16
  • Buy
Manufacturer Product number Product description Packaging Price Updated Buy
AHH MB-03481 benzene-1,2-diamine 97% 1Kg $125 2021-12-16 Buy
AK Scientific J54149 o-Phenylenediamine 25g $15 2021-12-16 Buy
AK Scientific H444 o-Phenylenediamine 500g $75 2021-12-16 Buy
Alfa Aesar A11946 o-Phenylenediamine, 98% 25g $32.8 2024-03-01 Buy
Alfa Aesar A11946 o-Phenylenediamine, 98% 250g $55 2024-03-01 Buy
Alfa Aesar A11946 o-Phenylenediamine, 98% 1000g $138 2024-03-01 Buy
Alfa Aesar A11946 o-Phenylenediamine, 98% 5000g $555 2024-03-01 Buy
Chem-Impex 31478 o-Phenylenediamine,≥99%(GC)Hazmat ≥99%(GC) 100G $16.6 2021-12-16 Buy
Chem-Impex 40899 1,2-Phenylenediamine,≥98%(GC)Hazmat ≥98%(GC) 25G $17.47 2021-12-16 Buy
Chem-Impex 31478 o-Phenylenediamine,99%(GC) 99%(GC) 250G $26.6 2021-12-16 Buy
Chem-Impex 40899 1,2-Phenylenediamine,98%(GC) 98%(GC) 100G $32.48 2021-12-16 Buy
Chem-Impex 31478 o-Phenylenediamine,≥99%(GC)Hazmat ≥99%(GC) 1KG $82.99 2021-12-16 Buy
Chem-Impex 40899 1,2-Phenylenediamine,98%(GC) 98%(GC) 500G $96.32 2021-12-16 Buy
Chem-Impex 31478 o-Phenylenediamine,99%(GC) 99%(GC) 2.5KG $175.56 2021-12-16 Buy
Chem-Impex 31478 o-Phenylenediamine,99%(GC) 99%(GC) 5KG $313.88 2021-12-16 Buy
Chem-Impex 31478 o-Phenylenediamine,99%(GC) 99%(GC) 10KG $595.84 2021-12-16 Buy

Properties

Melting point :100-102 °C
Boiling point :256-258 °C
Density :1,27 g/cm3
vapor density :3.7 (vs air)
vapor pressure :0.01 mm Hg ( 25 °C)
refractive index :1.6339 (estimate)
Flash point :110°C
storage temp. :2-8°C
solubility :H2O: 1 tablet/10 mL, clear, colorless
form :tablet
Colour Index :76010
pka :4.46(at 25℃)
color :white to off-white
PH Range :Green Q uorescence (3.1) to nonQ uorescence (4.4)
PH :7-8 (50g/l, H2O, 20℃)
explosive limit :1.5%(V)
Water Solubility :<0.1 g/100 mL at 20 ºC
Sensitive :Air & Light Sensitive
Merck :14,7284
BRN :606074
Exposure limits :TLV-TWA 0.1 mg/m3; carcinogenicity: A2- Suspected Human Carcinogen (ACGIH 1989).
Stability :Stable. Incompatible with strong oxidizing agents.
Major Application :bottom antireflective coatings, semiconductor devices, hair dyes, detecting antibody, substrate for horseantibody, glucose, streptomycin, penicillin, sulfonamide, neuroglobin, substrate for horseradish peroxidase
LogP :0.12-0.17 at 20-25℃ and pH7-8
CAS DataBase Reference :95-54-5(CAS DataBase Reference)
IARC :2B (Vol. 123) 2020
NIST Chemistry Reference :1,2-Benzenediamine(95-54-5)
EPA Substance Registry System :1,2-Phenylenediamine (95-54-5)

Safety Information

Symbol(GHS): GHS hazard pictogramsGHS hazard pictogramsGHS hazard pictograms
Signal word: Danger
Hazard statements:
Code Hazard statements Hazard class Category Signal word Pictogram P-Codes
H301 Toxic if swalloed Acute toxicity,oral Category 3 Danger GHS hazard pictograms P264, P270, P301+P310, P321, P330,P405, P501
H317 May cause an allergic skin reaction Sensitisation, Skin Category 1 Warning GHS hazard pictograms P261, P272, P280, P302+P352,P333+P313, P321, P363, P501
H319 Causes serious eye irritation Serious eye damage/eye irritation Category 2A Warning GHS hazard pictograms P264, P280, P305+P351+P338,P337+P313P
H341 Suspected of causing genetic defects Germ cell mutagenicity Category 2 Warning P201,P202, P281, P308+P313, P405,P501
H351 Suspected of causing cancer Carcinogenicity Category 2 Warning P201, P202, P281, P308+P313, P405,P501
H410 Very toxic to aquatic life with long lasting effects Hazardous to the aquatic environment, long-term hazard Category 1 Warning GHS hazard pictograms P273, P391, P501
Precautionary statements:
P202 Do not handle until all safety precautions have been read and understood.
P273 Avoid release to the environment.
P280 Wear protective gloves/protective clothing/eye protection/face protection.
P301+P310 IF SWALLOWED: Immediately call a POISON CENTER or doctor/physician.
P302+P352 IF ON SKIN: wash with plenty of soap and water.
P305+P351+P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

Description

o-phenylenediamine is used to prepare tiabendazole, pyrazinamide, morinamide, clemizole and chlormidazole. It is involved in the synthesis of benzimidazole by reacting with carboxylic acids and their derivatives. It is also used to prepare quinoxalinedione and mercaptoimidazoles by condensation with dimethyl oxalate and xanthate esters respectively. It reacts with nitrous acid to get benzotriazole, which finds application as a corrosion inhibitor. It is actively involved in the preparation of pharmaceuticals by reacting substituted o-phenylenediamine with various diketones.

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