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Dimethylammoniumdichlorotri(mu-chloro)bis[(R)-(+)-2,2'-bis(diphenylphosphino)-1,1'-binaphthyl]diruthenate(II)

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Dimethylammoniumdichlorotri(mu-chloro)bis[(R)-(+)-2,2'-bis(diphenylphosphino)-1,1'-binaphthyl]diruthenate(II) Suppliers list
Company Name: Shaoxin Catsyn Co., Ltd.
Tel: +undefined-0575-82040869 +86-0575-82040869;
Email: sales@catsyn.com
Products Intro: Product Name:Dimethylammonium dichlorotri(μ-chloro)bis[(R)-(+)-2,2'-bis(diphenylphosphino)-1,1'-binaphthyl]diruthenate(II), [NH2Me2][{RuCl((R)-binap)}2(μ-Cl)3]
CAS:199684-47-4
Purity:98% Min. Package:1G;1KG;100KG Remarks:SC10176
Company Name: Zibo Hangyu Biotechnology Development Co., Ltd
Tel: +86-0533-2185556 +8617865335152
Email: Mandy@hangyubiotech.com
Products Intro: CAS:199684-47-4
Purity:0.99 Package:5KG;1KG
Company Name: J & K SCIENTIFIC LTD.  
Tel: 010-82848833 400-666-7788
Email: jkinfo@jkchemical.com
Products Intro: Product Name:Dimethylammonium dichlorotri(mu-chloro)bis[(R)-(+)-2,2'-bis(diphenylphosphino)-1,1'-binaphthyl]diruthenate(II) [NH2Me2][{RuCl((R)-binap)}2(mu-Cl)3]
CAS:199684-47-4
Package:1g;250mg;5g
Company Name: Energy Chemical  
Tel: 021-021-58432009 400-005-6266
Email: sales8178@energy-chemical.com
Products Intro: Product Name:(R)-[(RuCl(BINAP))2(μ-Cl)3[NH2Me2]
CAS:199684-47-4
Package:100MG,500MG
Company Name: Shanghai Incat Chemtech Co.,Ltd.  
Tel: 021-57603038 13601791340
Email: 307593986@qq.com
Products Intro: Product Name:DiMethylaMMoniuM dichlorotri(μ-chloro)bis[(R)-(+)-2,2'-bis(diphenylphosphino)-1,1'-binaphthyl]diruthenate(II), ?[NH2Me2][{RuCl((R)-binap)}2(μ-Cl)3]
CAS:199684-47-4
Remarks:公斤级;100G;50G;10G
Dimethylammoniumdichlorotri(mu-chloro)bis[(R)-(+)-2,2'-bis(diphenylphosphino)-1,1'-binaphthyl]diruthenate(II) Basic information
Reaction
Product Name:Dimethylammoniumdichlorotri(mu-chloro)bis[(R)-(+)-2,2'-bis(diphenylphosphino)-1,1'-binaphthyl]diruthenate(II)
Synonyms:Dimethylammonium dichlorotri(chloro)bis[(R)-(+)-2,2'-bis(diphenylphosphino)-1,1'-binaphthyl]diruthenate(II) [NH2Me2][{RuCl((R)-binap)}2(Cl)3];DiMethylaMMoniuM dichlorotri(Mu-chloro)bis[(R)-(+)-2,2'-bis(diphenylphosphino)-1,1'-binaphthyl]diruthenate(II) [NH2Me2][{RuCl((R)-binap)}2(μ-Cl)3];Dimethylammoniumdichlorotri(mu-chloro)bis[(R)-(+)-2,2'-bis(diphenylphosphino)-1,1'-binaphthyl]diruthenate(II);(R)-[(RuCl(BINAP))2(μ-Cl)3[NH2Me2];Dimethylammonium dichlorotri(μ-chloro)bis[(R)-(+)-2,2μ-bis(diphenylphosphino)-1,1μ-binaphthyl]diruthenate(II);[NH2Me2][{RuCl((R)-binap)}2(mu-Cl)3];[NH2ME2][(RUCL((R)-BINAP))2(Μ-CL)3];-binaphthyl]diruthenate(II),[NH2Me2][{RuCl((R)
CAS:199684-47-4
MF:C90H76Cl5NP4Ru2
MW:1674.89
EINECS:
Product Categories:Ru
Mol File:199684-47-4.mol
Dimethylammoniumdichlorotri(mu-chloro)bis[(R)-(+)-2,2'-bis(diphenylphosphino)-1,1'-binaphthyl]diruthenate(II) Structure
Dimethylammoniumdichlorotri(mu-chloro)bis[(R)-(+)-2,2'-bis(diphenylphosphino)-1,1'-binaphthyl]diruthenate(II) Chemical Properties
Melting point >100°C
storage temp. 2-8°C
form Powder
color orange
Sensitive air sensitive
CAS DataBase Reference199684-47-4
Safety Information
WGK Germany 3
HS Code 2843.90.0000
MSDS Information
Dimethylammoniumdichlorotri(mu-chloro)bis[(R)-(+)-2,2'-bis(diphenylphosphino)-1,1'-binaphthyl]diruthenate(II) Usage And Synthesis
Reaction
  1. (R)-BINAP or (R)-Tol-BINAP can be combined with dichloro(1,5-cyclooctadiene)ruthenium to form precursors to NOYORI CATALYST SYSTEMS. These systems exhibit very high catalytic activity and enantioselectivity in the hydrogenation of a wide range of substrates. NOYORI CATALYST SYSTEMS have been shown to effect highly enantioselective hydrogenation of functionalized ketones where the substituents are dialkylamino, hydroxy, siloxy, carbonyl, ester, amide or thioester.
  2. Useful ligand in asymmetric Heck processes.
  3. Ligand employed in palladium-catalyzed asymmetric arylation of ketones.
  4. Ligand employed in rhodium-catalyzed 1,4-additions to enones.
  5. Ligand employed in palladium-catalyzed hydroamination of styrene derivatives.
  6. Ligand employed in silver-catalyzed asymmetric Sakuri-Hosomi allylation and Mukaiyama aldol reaction.
  7. Ligand employed in rhodium-catalyzed kinetic resolution of enynes.
  8. Ligand employed in asymmetric rhodium-catalyzed hydroboration of cyclopropenes.
  9. Ligand employed in silver-catalyzed a-hydroxylation of stannyl enol ethers.
  10. Ligand employed in palladium-catalyzed synthesis of chiral allenes.
  11. Ligand for palladium-catalyzed enantioselective hetero Michael addition to form b-amino acid derivatives.
  12. Ligand employed in rhodium-catalyzed asymmetric rearrangement of alkynyl alkenyl carbinols.
  13. Ligand employed in rhodium-catalyzed 1,2-addition of aluminium organyl compounds to cyclic enones.
  14. Ligand employed in iridium-catalyzed transfer hydrogenative allylation of benzylic alcohols.
  15. Ligand employed in rhodium-catalyzed asymmetric C-Si bond formation by conjugate silyl transfer using a Si-B linkage.
Reactions of 199684-47-4_1
Reactions of 199684-47-4_2
Reactions of 199684-47-4_3
UsesTakasago Ligands and Complexes for Asymmetric Reactions
Dimethylammoniumdichlorotri(mu-chloro)bis[(R)-(+)-2,2'-bis(diphenylphosphino)-1,1'-binaphthyl]diruthenate(II) Preparation Products And Raw materials
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