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CERIUM(III) CHLORIDE

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CAS:7790-86-5
Purity:99% Package:100g,500g,1kg,5kg,10kg
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CAS:7790-86-5
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Products Intro: Product Name:Cerium(III) chloride
CAS:7790-86-5
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Products Intro: Product Name:CERIUM(III) CHLORIDE
CAS:7790-86-5
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Lastest Price from CERIUM(III) CHLORIDE manufacturers

  • CERIUM(III) CHLORIDE
  • US $1.00 / KG
  • 2019-07-06
  • CAS:7790-86-5
  • Min. Order: 1KG
  • Purity: 98%
  • Supply Ability: 1kg,5kg,100kg
  • CERIUM(III) CHLORIDE
  • US $10.00 / KG
  • 2019-05-07
  • CAS:7790-86-5
  • Min. Order: 1KG
  • Purity: 99%
  • Supply Ability: 500tons/month
CERIUM(III) CHLORIDE Basic information
Product Name:CERIUM(III) CHLORIDE
Synonyms:CeCl3;Cerium chloride (CeCl3);ceriumchloride(cecl3);ceriumtrichloride;Cerium Chloride (Mohrs Salt);CERIUM II CHLORIDE;Cerium(Ⅲ) chloride heptahydrate;CERIUM(III) CHLORIDE, 99.9%
CAS:7790-86-5
MF:CeCl3
MW:246.48
EINECS:232-227-8
Product Categories:Other Metal;Inorganics;Ce (Cerium) Compounds;Classes of Metal Compounds;Transition Metal Compounds;metal halide
Mol File:7790-86-5.mol
CERIUM(III) CHLORIDE Structure
CERIUM(III) CHLORIDE Chemical Properties
Melting point 848 °C(lit.)
Boiling point 1727 °C
density 3.97 g/mL at 25 °C(lit.)
Fp 1727°C
form beads
color White to Pale Gray
Specific Gravity3.92
Water Solubility Soluble in water, ethanol, acids and acetone.
Sensitive Hygroscopic
Merck 14,1997
Stability:Stable. Hygroscopic. Incompatible with strong acids, strong oxidizing agents.
InChIKeyVYLVYHXQOHJDJL-UHFFFAOYSA-K
CAS DataBase Reference7790-86-5(CAS DataBase Reference)
EPA Substance Registry SystemCerium chloride (CeCl3) (7790-86-5)
Safety Information
Hazard Codes Xi
Risk Statements 36/37/38
Safety Statements 26-36
RIDADR UN 3260 8 / PGIII
WGK Germany 2
RTECS FK5075000
3-10
TSCA Yes
HS Code 28461090
ToxicityLD50 in mice, guinea pigs (mg/kg): 352, 110 i.p. (Graca)
MSDS Information
ProviderLanguage
SigmaAldrich English
ACROS English
ALFA English
CERIUM(III) CHLORIDE Usage And Synthesis
Chemical PropertiesCerium(III) chloride is a white powder and is used for incandescent gas mantles, spectrography and polymerization of olefins.
Cerium(III) chloride
Cerium(III) chloride acts as a Lewis acid and used in Friedel-Crafts alkylation and acylation reactions in organic synthesis. It is used as a precursor for the preparation of other cerium salts, such as cerium(III) trifluoromethanesulfonate.
When added to nitrile aldol reactions, diastereoselectivity is enhanced, providing high yields of β-hydroxynitriles.
Cerium Chloride is mainly used as catalyst for petroleum,automobile exhaust catalyst , also used as intermediate compound , also used to make metal Cerium.
Physical propertiesWhite, very fine powder; hexagonal crystal system; heptahydrate is yellow orthogonal crystal and hygroscopic; density of anhydrous salt 3.97 g/cm3; melts at 817°C; vaporizes at 1,727°C; heptahydrate begins to lose water above 90°C and becomes anhydrous at about 230°C; soluble in water and alcohol; hexahydrate has greater solubility in these solvents.
UsesIncandescent gas mantles, spectrography, preparation of cerium metal, polymerization cat- alyst.
Production MethodsCerium(III) chloride is prepared by the reaction of hydrochloric acid with a cerium salt, such as cerium hydroxide or carbonate, followed by crystallization;
Ce(OH)3 + 3HCl → CeCl3 + 3H2O
Ce2(CO3)3 + 6HCl → 2CeCl3 + 3CO2 + 3H2O.
Safety ProfilePoison by intravenous, intraperitoneal, and subcutaneous routes. Moderately toxic by ingestion. See also CERIUM COMPOUNDS. When heated to decomposition it emits toxic fumes of Cl-
CERIUM(III) CHLORIDE Preparation Products And Raw materials
Raw materialsRare earth chlorides
Tag:CERIUM(III) CHLORIDE(7790-86-5) Related Product Information
Cerium fluoride CEROUS CHLORIDE, HYDRATED AMMONIUM CERIUM(IV) SULFATE CEROUS CARBONATE CERIUM OXIDE CERIUM(III) NITRATE HEXAHYDRATE Cerium dioxide CERIC SULFATE CERIUM(III) PHOSPHATE Ceric ammonium nitrate CERIUM(III) NITRATE HEXAHYDRATE Cerium tetrahydroxide CERIUM (III) NITRATE CERIC SULFATE CERIUM(III) SULFATE N-HYDRATE CERIUM CERIUM(III) CHLORIDE HEPTAHYDRATE CERIUM