Tetraarsenic tetrasulfide

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CAS:12279-90-2
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CAS:12279-90-2
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CAS:12279-90-2
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Tetraarsenic tetrasulfide Basic information
Product Name:Tetraarsenic tetrasulfide
Synonyms:Tetraarsenic tetrasulfide.;2,4,6,8-Tetrathia-1,3,5,7-tetraarsatricyclo[3.3.0.03,7]octane
CAS:12279-90-2
MF:As4S4
MW:427.95
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Mol File:12279-90-2.mol
Tetraarsenic tetrasulfide Structure
Tetraarsenic tetrasulfide Chemical Properties
Melting point 320°
Boiling point bp 565°
density 3.5
solubility insoluble in H2O; slightly soluble in benzene; soluble in alkaline solutions
form red monoclinic crystals
color red monoclinic crystals, crystalline
Water Solubility insoluble H2O, hot HCl; soluble warm alkali [KIR78]
CAS DataBase Reference12279-90-2
Safety Information
MSDS Information
Tetraarsenic tetrasulfide Usage And Synthesis
Chemical Propertiesred or orange solid; naturally occurring mineral; can be manufactured by heating iron pyrites and arsenopyrite; used in pyrotechnics [KIR78]
OccurrenceArsenic sulfide occurs in nature as the mineral realgar. It is used as a pigment; in pyrotechnics to produce blue fire; in dyeing and calico printing; and as a depilatory for hides.
UsesAs pigment in painting; in fireworks as blue fire and to give an intense white flame; manufacture of shot; calico printing and dyeing; tanning and depilating hides.
PreparationArsenic sulfide is prepared commercially by heating a mixture of iron pyrites and arsenopyrite; or by heating arsenic trioxide with sulfur. The compound is then sublimed and collected. It may be also made from arsenic sesquisulfide - by either heating with sodium bicarbonate in a sealed tube or on prolong treatment with boiling solution of sodium carbonate.
Tetraarsenic tetrasulfide Preparation Products And Raw materials
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ARSENIC (II) SULFIDE