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1-Ethyl-3-methylimidazolium Diethyl Phosphate

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CAS:848641-69-0
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1-Ethyl-3-methylimidazolium Diethyl Phosphate Basic information
Product Name:1-Ethyl-3-methylimidazolium Diethyl Phosphate
Synonyms:1-Ethyl-3-methylimidazolium diethylphosphate;Basionics(R) LQ 11;EMIM DEP;Basionics? LQ 11;1-Ethyl-3-methylimidazolium diethyl phosphate >=98.0% (HPLC);EMIM(EtO)2PO2;Enim DEP;1-ethyl-3-methylimidazolium diethylphosphat
CAS:848641-69-0
MF:C10H21N2O4P
MW:0
EINECS:684-879-1
Product Categories:Chemical Synthesis;Ionic Liquids;Specialty Synthesis;Chemical Synthesis;Imidazolium;Ionic Liquids
Mol File:848641-69-0.mol
1-Ethyl-3-methylimidazolium Diethyl Phosphate Structure
1-Ethyl-3-methylimidazolium Diethyl Phosphate Chemical Properties
Melting point 19-21°C
Boiling point 196℃ at 101.325kPa
density 1.157
vapor pressure 1.2-10.9hPa at 25-60℃
refractive index n20/D 1.475
storage temp. Inert atmosphere,Room Temperature
form Liquid
color Colorless to Yellow to Orange
PH5-7 (200g/l, H2O, 20℃)
Water Solubility Fully miscible in water.
Sensitive Moisture Sensitive
BRN 10726450
LogP-0.22 at 25℃ and pH7.5
CAS DataBase Reference848641-69-0
ECW5.8 V
Safety Information
Hazard Codes C
Risk Statements 22-34
Safety Statements 26-36/37/39-45
RIDADR UN3265 8/PG 2
WGK Germany 3
HazardClass 8
PackingGroup II
HS Code 29332900
MSDS Information
1-Ethyl-3-methylimidazolium Diethyl Phosphate Usage And Synthesis
Conductivity0.84 mS/cm
Chemical PropertiesYellow to orange liquid
UsesIt finds its application in improving enzymatic hydrolysis of wheat straw and in the enzymatic in situ saccharification of cellulose in aqueous-ionic liquid media.
Application1-Ethyl-3-methylimidazolium diethylphosphate ([C2mim][(C2)2OPO3]) has high biomass solubilization ability due to hydrogen bond basicity and the potential role of cation to rupture the bacterial cell wall. Specifically, one [(C2)2OPO3] anion can interact with two hydroxyl groups of cellulose, which further supports its ability to dissolve biopolymers having OH functionality. Moreover, the cationic imidazolium part of ([C2mim][(C2)2OPO3]) has been shown to interact with negatively charged phospholipid membrane via strong electrostatic interaction to rupture the bacterial membrane[1].
General Description1-Ethyl-3-methylimidazolium diethyl phosphate is a low melting, imidazolium-based ionic liquid, which can dissolve cellulose. The solution of cellulose in EMIM DEP-pyridine mixture is stable in time.
References[1] Dubey S, et al. 1-Ethyl-3-methylimidazolium Diethylphosphate Based Extraction of Bioplastic “Polyhydroxyalkanoates” from Bacteria: Green and Sustainable Approach. ACS Sustainable Chemistry & Engineering, 2017; 6: 766–773.
1-Ethyl-3-methylimidazolium Diethyl Phosphate Preparation Products And Raw materials
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