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TRIS(2-AMINOETHYL)AMINE

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CAS:4097-89-6
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CAS:4097-89-6
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CAS:4097-89-6
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  • 2021-08-12
  • CAS:4097-89-6
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TRIS(2-AMINOETHYL)AMINE Basic information
Product Name:TRIS(2-AMINOETHYL)AMINE
Synonyms:tris(beta-aminoethyl)amine;2,2',2''-Triaminotriethylamine,97%TREN;2,2'',2 -TRIAMINOTRIETHYLAMINE TREN;2,2μ,2μμ-Nitrilotriethylamine, 2,2μ,2μμ-Triaminotriethylamine, TAEA;2,2',2''-Nitrilotris(ethane-1-amine);2,2',2''-Nitrilotrisethanamine;Tris(2-aminoethyl)amine ,95%;Tris(2-aMinoethyl)aMine, 96% 100ML
CAS:4097-89-6
MF:C6H18N4
MW:146.23
EINECS:223-857-4
Product Categories:
Mol File:4097-89-6.mol
TRIS(2-AMINOETHYL)AMINE Structure
TRIS(2-AMINOETHYL)AMINE Chemical Properties
Melting point -16 °C
Boiling point 114 °C/15 mmHg (lit.)
density 0.976 g/mL at 20 °C (lit.)
vapor density 5 (vs air)
vapor pressure 0.02 mm Hg ( 20 °C)
refractive index n20/D 1.497(lit.)
Fp >230 °F
storage temp. 2-8°C
solubility Chloroform (Sparingly), DMSO (Slightly)
form saline suspension
pka10.00±0.10(Predicted)
color Clear yellow
Specific Gravity0.977
Water Solubility Miscible with water.
Sensitive Hygroscopic
BRN 1739626
Stability:Stable. Hygroscopic. Absorbs carbon dioxide from the air. Incompatible with strong acids, strong oxidizing agents.
CAS DataBase Reference4097-89-6(CAS DataBase Reference)
EPA Substance Registry System1,2-Ethanediamine, N,N-bis(2-aminoethyl)- (4097-89-6)
Safety Information
Hazard Codes T,Xi
Risk Statements 22-24-34-36/37/38-10
Safety Statements 26-36/37/39-45-16
RIDADR UN 2922 8/PG 2
WGK Germany 3
RTECS KH8587082
3-10-23
TSCA Yes
HazardClass 6.1
PackingGroup II
HS Code 29211990
Toxicitymouse,LD50,oral,1800mg/kg (1800mg/kg),LUNGS, THORAX, OR RESPIRATION: RESPIRATORY DEPRESSIONBEHAVIORAL: ATAXIAGASTROINTESTINAL: "HYPERMOTILITY, DIARRHEA","Spravochnik po Toksikologii i Gigienicheskim Normativam Vol. -, Pg. 223, 1999.
MSDS Information
ProviderLanguage
ACROS English
SigmaAldrich English
ALFA English
TRIS(2-AMINOETHYL)AMINE Usage And Synthesis
Chemical PropertiesColorless liquid
UsesTris(2-aminoethyl)amine is a tetradentate chelating ligand and forms stable complexes with transition metals. It is also used as a carbon dioxide absorbent. Further, it acts as a reagent for cleavage of the fluorenylmethyloxycarbonyl (Fmoc) group in peptide synthesis. It reacts with aryl isocyanates and isothiocyanates to give tris-urea and -thiourea derivatives.
DefinitionChEBI: Tris(2-aminoethyl)amine is a tetramine.
General DescriptionTris(2-aminoethyl)amine (TREN) is a water soluble tripodal ligand that is majorly used in co-ordination chemistry. It has three aminoethylgroups that attach with the surface atoms to provide a scaffold assembly.
HazardA poison by ingestion and skin contact.
Safety ProfileA poison by ingestion and skin contact. When heated to decomposition it emits toxic vapors of NOx.
Purification MethodsFor a separation from a mixture containing 62% TRIEN, see entry under triethylenetetramine. Also purify it by conversion to the hydrochloride (see below), recrystallise it and regenerate the free base [Xie & Hendrickson J Am Chem Soc 109 6981 1987]. [Beilstein 4 H 256, 4 II 695, 4 III 545, 4 IV 1250.]
Tag:TRIS(2-AMINOETHYL)AMINE(4097-89-6) Related Product Information
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