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4-Methylanisole

4-Methylanisole Suppliers list
Company Name: Henan DaKen Chemical CO.,LTD.
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Products Intro: Product Name:4-Methylanisole
CAS:104-93-8
Purity:99% Package:100g ,1KG ,5KG 25KG
Company Name: Henan Tianfu Chemical Co.,Ltd.
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Products Intro: Product Name:4-Methylanisole
CAS:104-93-8
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Products Intro: Product Name:4-Methylanisole
CAS: 104-93-8
Purity:99% Package:1kg;1USD
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Products Intro: Product Name:4-Methylanisole
CAS:104-93-8
Package:50kg

4-Methylanisole manufacturers

  • 4-Methylanisole
  • $0.00 / Kg/Drum
  • 2022-01-21
  • CAS:104-93-8
  • Min. Order: 1KG
  • Purity: 99.9%
  • Supply Ability: 100000kg per month
  • 4-Methylanisole
  • $10.00 / KG
  • 2021-12-01
  • CAS:104-93-8
  • Min. Order: 1KG
  • Purity: 99%
  • Supply Ability: 10 ton
  • 4-Methylanisole
  • $15.00-10.00 / KG
  • 2021-08-12
  • CAS:104-93-8
  • Min. Order: 1KG
  • Purity: 99%+ HPLC
  • Supply Ability: Monthly supply of 1 ton
4-Methylanisole Basic information
Product Name:4-Methylanisole
Synonyms:FEMA 2681;1-METHOXY-4-METHYLBENZENE;METHYL-P-CRESOL;METHYL P-TOLYL ETHER;4-METHYLANISOLE;4-METHOXYTOLUENE;MSO;P-CRESYL METHYL ETHER
CAS:104-93-8
MF:C8H10O
MW:122.16
EINECS:203-253-7
Product Categories:Indolines ,Indoles;Building Blocks;C8;Chemical Synthesis;Organic Building Blocks;Oxygen Compounds;AnisoleSeries;Ethers;Organic Building Blocks;Oxygen Compounds;Alphabetical Listings;Flavors and Fragrances;M-N;VX:15689727968
Mol File:104-93-8.mol
4-Methylanisole Structure
4-Methylanisole Chemical Properties
Melting point -32°C
Boiling point 174 °C(lit.)
density 0.969 g/mL at 25 °C(lit.)
vapor pressure 5.25 mm Hg ( 50 °C)
refractive index n20/D 1.511(lit.)
FEMA 2681 | P-METHYLANISOLE
Fp 128 °F
storage temp. Sealed in dry,Room Temperature
form Liquid
color Clear colorless to slightly yellow
Odor Threshold0.0012ppm
explosive limit1.1-8.3%(V)
Water Solubility slightly soluble
λmax279nm(MeOH)(lit.)
JECFA Number1243
BRN 1237336
Stability:Stable. Incompatible with strong oxidizing agents. Combustible.
CAS DataBase Reference104-93-8(CAS DataBase Reference)
NIST Chemistry ReferenceBenzene, 1-methoxy-4-methyl-(104-93-8)
EPA Substance Registry Systemp-Methylanisole (104-93-8)
Safety Information
Hazard Codes Xn
Risk Statements 22-38-10-52/53-63
Safety Statements 36/37-16-61
RIDADR UN 1993 3/PG 3
WGK Germany 1
RTECS BZ8780000
TSCA Yes
HazardClass 3
PackingGroup III
HS Code 29093090
Hazardous Substances Data104-93-8(Hazardous Substances Data)
toxicityThe acute oral LD50 in rats was reported as 1.92 (1.51-2.45) g/kg (Hart, 1971). The acute dermal LD50 in rabbits was reported as > 5 g/kg (Hart, 1971).
MSDS Information
ProviderLanguage
4-Methylanisole English
SigmaAldrich English
ACROS English
ALFA English
4-Methylanisole Usage And Synthesis
Descriptionp-Methylanisole has a pungent odor suggestive of ylang-ylang. May be prepared by methylation of p-cresol.
Chemical Propertiesp-Methylanisole has a pungent odor suggestive of ylang-ylang.
Chemical Propertiescolourless liquid
OccurrenceReported found in the oils of ylang-ylang, cananga and flowers of Mimusops elengi L. Also reported found in tomato, blue and Camembert cheese, starfruit, buckwheat, rooibus tea (Aspalathus linearis) and tapereba (Spondias lutea).
UsesPerfumery, flavoring.
PreparationBy methylation of p-cresol.
Aroma threshold valuesDetection: 200 ppb
Taste threshold valuesTaste characteristics at 20 ppm: naphthyl, phenolic, camphoraceous, cooling and woody.
Synthesis Reference(s)Journal of the American Chemical Society, 113, p. 8516, 1991 DOI: 10.1021/ja00022a046
Tetrahedron Letters, 32, p. 2759, 1991 DOI: 10.1016/0040-4039(91)85078-J
The Journal of Organic Chemistry, 59, p. 4687, 1994 DOI: 10.1021/jo00095a054
Safety ProfileModerately toxic by ingestion. A skin irritant. Flammable liquid when exposed to heat, sparks, or flame. When heated to decomposition it emits acrid smoke and irritating fumes.
Purification MethodsDissolve 4-methyl anisole in diethyl ether, wash it with M NaOH, water, dry (Na2CO3), evaporate and distil it under vacuum. The picrate has m 103o (from aqueous EtOH). [Beilstein 6 IV 2098.]
Tag:4-Methylanisole(104-93-8) Related Product Information
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