MIL-101(CR)
| 中文名称 | MIL-101(CR) |
|---|---|
| 中文同义词 | MIL-101(CR)金属有机骨架;金属有机框架MIL-101(CR);MIL-101(Cr);XFF37;MIL-101(Cr)/MIL-101(Cr)金属有机骨架 |
| 英文名称 | MIL-101(Cr) |
| 英文同义词 | MIL-101(CR);Diaquatris[μ-[1,4-benzenedicarboxylato(2-)-κO1:κO'1]]fluoro-μ3-oxotriChromium hydrate(1:x);Metal Organic Frameworks (MOFs) MIL-101(Cr);XFF37;tris(chromium(3+)) |
| CAS号 | 869288-09-5 |
| 分子式 | C24H16Cr3FO16 |
| 分子量 | 735.36 |
| EINECS号 | |
| 相关类别 | 材料化学;科研材料中间体 |
| Mol文件 | 869288-09-5.mol |
| 结构式 |  |
MIL-101(CR) 性质
| 密度 | 0.58 g/cm3 |
|---|---|
| 储存条件 | 2-8°C, stored under nitrogen |
| 外观 | 浅绿色至绿色固体 |
| InChI | InChI=1S/3C8H6O4.3Cr.FH.3H2O.O/c3*9-7(10)5-1-2-6(4-3-5)8(11)12;;;;;;;;/h3*1-4H,(H,9,10)(H,11,12);;;;1H;3*1H2;/q;;;+3;2*+4;;;;;-2/p-9 |
| InChIKey | QQOADXNDUNUNLG-UHFFFAOYSA-E |
| SMILES | [F-][Cr+3]12O=C(C3C=CC(C(=O)[O-])=CC=3)[O-][Cr+3]3(O=C(C4C=CC(C(=O)[O-])=CC=4)[O-][Cr+3](O=C(C4C=CC(C(=O)[O-])=CC=4)[O-]1)(O)[O-2]23)O.O |
| 配位金属 | Cr |
| 配体 | 对苯二甲酸（CAS：100-21-0） |
| 孔径 | 窗口:1.2-1.6nm;孔径:2.9-3.4nm |
| 孔容 | 2.0-2.4cm3/g |
| 粒径 | 500-800nm |
| 比表面 | BET比表面2800-3200m2/g |
参考文献
[1] A Chromium Terephthalate-Based Solid with Unusually Large Pore Volumes and Surface Area. https://doi.org/10.1126/science.1116275
[2] Comparative Study of Hydrogen Sulfide Adsorption in the MIL-53(Al, Cr, Fe), MIL-47(V), MIL-100(Cr), and MIL-101(Cr) Metal-Organic Frameworks at Room Temperature. https://doi.org/10.1021/ja901587t
[3] Amine Grafting on Coordinatively Unsaturated Metal Centers of MOFs: Consequences for Catalysis and Metal Encapsulation. https://doi.org/10.1002/anie.200705998
[4] High Uptakes of CO₂ and CH₄ in Mesoporous Metal-Organic Frameworks MIL-100 and MIL-101. https://doi.org/10.1021/la800227x
[5] High Flux Thin Film Nanocomposite Membranes Based on Metal−Organic Frameworks for Organic Solvent Nanofiltration. https://doi.org/10.1021/ja407665w