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Aluminum acetylacetonate

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Aluminum acetylacetonate Basic information
Product Name:Aluminum acetylacetonate
Synonyms:aluminumtris(acetylacetonate);tris(2,4-pentanedionato)-aluminu;Tris(2,4-pentanedionato)aluminum;tris(2,4-pentanedionato-O,O’)-,(OC-6-11)-Aluminum;tris(2,4-pentanedione)aluminum;tris(acetylacetonate)aluminum(iii;Tris(acetylacetonato) aluminium(III);Tris(acetylacetonato)aluminum
Product Categories:-;metal beta-diketonate complexes;Pharmaceutical Intermediates;Organometallics;Al (Alminum) Compounds;Catalysts for Organic Synthesis;Homogeneous Catalysts;Metal Complexes;Synthetic Organic Chemistry;Classes of Metal Compounds;Typical Metal Compounds
Mol File:13963-57-0.mol
Aluminum acetylacetonate Structure
Aluminum acetylacetonate Chemical Properties
Melting point 190-193 °C(lit.)
Boiling point 315 °C(lit.)
density 1,27 g/cm3
Fp 314-316°C
storage temp. Store below +30°C.
solubility 3g/l
form Crystalline Powder
color White to cream
PH8 (3g/l, H2O, 20℃)
Water Solubility 2.5 g/L (20 ºC)
BRN 4157942
Stability:Stable. Incompatible with strong oxidizing agents.
CAS DataBase Reference13963-57-0
NIST Chemistry ReferenceAluminum tris(acetylacetonate)(13963-57-0)
EPA Substance Registry SystemAluminum, tris(2,4-pentanedionato-.kappa. O,.kappa.O')-, (OC-6-11)-(13963-57-0)
Safety Information
Hazard Codes T
Risk Statements 25-36/37/38-36-43
Safety Statements 26-36/37/39-45-28A-36/37
RIDADR UN 3467 6.1/PG 2
WGK Germany 3
RTECS BD2230000
Autoignition Temperature500 °C
HazardClass 6.1
PackingGroup III
HS Code 29420000
ToxicityLD50 orally in Rabbit: 48.7 mg/kg
MSDS Information
Aluminum 2,4-pentanedionate English
SigmaAldrich English
ACROS English
ALFA English
Aluminum acetylacetonate Usage And Synthesis
Chemical PropertiesAluminium (III) acetylacetonate is a white to yellow powder or crystals in appearance. It is stable and incompatible with strong oxidizing agents.
UsesDeposition of aluminum, catalyst.
Health HazardExposures to aluminium (III) acetylacetonate cause adverse health effects. Exposures by inhalation, ingestion, and through skin contact are harmful. It causes irritation effects to the eyes, skin, and respiratory tract. Aluminium (III) acetylacetonate may release 2,4-pentanedione, which is a suspected teratogen and causes neurological health effects and harm to the unborn child. However, toxicology is not fully investigated.
Purification MethodsRecrystallise it several times from *benzene or aqueous MeOH, 216 and 286mn. max [Charles & Pawlikowski J Phys Chem 62 440 1958.] It can be purified by sublimation and has the following solubilities in g percent: *C6H6 35.9 (20o), 47.6 (40o), toluene 15.9 (20o), 22.0 (40o) and acetylacetone 6.6 (20o), 10.4 (40o). [Fernelius & Bryant Inorg Synth V 105 1957, Beilstein 1 IV 3668.]
Aluminum acetylacetonate Preparation Products And Raw materials
Raw materials2,4-Pentanedione-->Aluminium
Tag:Aluminum acetylacetonate(13963-57-0) Related Product Information
Rosin Boric acid Zinc stearate Naphthalene Bis(2,4-pentanediono)nickel Acetone ETHYLENE ALUMINUM ACETYLACETONATE, DODECAHYDRATE titanium (Ⅳ) acetylacetonate Cobaltic acetylacetonate Platinum bis(acetylacetonate) Aluminum acetylacetonate Aluminum phosphide Acetylacetone Aluminum Cupric acetylacetonate Ferric acetylacetonate Aluminium sulfate