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FERBAM

FERBAM Suppliers list
Company Name: Chemson Industrial (Shanghai) Co., Ltd.
Tel: 86-21-65208861-ext8007
Email: sales1@chemson.com.cn
Products Intro: Product Name:Fermate; Iron tris(dimethyldithiocarbamate)
CAS:14484-64-1
Purity:99.50% Package:25kg
Company Name: Hangzhou FandaChem Co.,Ltd.
Tel: 008615858145714
Email: fandachem@gmail.com
Products Intro: Product Name:Iron(III) dimethyldithiocarbamate fandachem
CAS:14484-64-1
Purity:As coa Package:As request Remarks:14484-64-1
Company Name: Hubei Jusheng Technology Co.,Ltd.
Tel: 86-18871470254
Email: linda@hubeijusheng.com
Products Intro: Product Name:ferbam
CAS:14484-64-1
Purity:99% Package:5KG;1KG Remarks:C9H18FeN3S6
Company Name: Hubei xin bonus chemical co. LTD
Tel: 86-13657291602
Email: linda@hubeijusheng.com
Products Intro: Product Name:FERBAM
CAS:14484-64-1
Purity:0.99 Package:5KG;1KG
Company Name: HENAN BON INDUSTRIAL CO.,LTD
Tel: 0371-55170695
Email: info@hnbon.com
Products Intro: CAS:14484-64-1
Purity:0.99 Package:25KG;5KG;1KG;500G

Lastest Price from FERBAM manufacturers

  • FERBAM
  • US $15.00-10.00 / KG
  • 2021-08-12
  • CAS:14484-64-1
  • Min. Order: 1KG
  • Purity: 99%+ HPLC
  • Supply Ability: Monthly supply of 1 ton
  • FERBAM
  • US $1.00 / KG
  • 2020-01-13
  • CAS:14484-64-1V
  • Min. Order: 1KG
  • Purity: 98%-99.9%
  • Supply Ability: 200kg
FERBAM Basic information
Product Name:FERBAM
Synonyms:CARBAMATE(R);FERBAM;FERBAM GRANUFLO;FERBERK;FERBERK(R);FERMATE;FERMATE(R);FERRADOW(R)
CAS:14484-64-1
MF:C9H18FeN3S6
MW:416.49
EINECS:238-484-2
Product Categories:Organometallics;Classes of Metal Compounds;Fe (Iron) Compounds;Transition Metal Compounds
Mol File:14484-64-1.mol
FERBAM Structure
FERBAM Chemical Properties
Melting point 180°C (dec.)
vapor pressure 2 x 10-11 Pa (est.)
storage temp. 0-6°C
form solid
Water Solubility 130 mg l-1 (room temperature)
Hydrolytic Sensitivity4: no reaction with water under neutral conditions
Merck 14,4013
Exposure limitsNIOSH 10 mg/m3, IDLH 800 mg/m3; OSHA PEL: TWA 15 mg/m3; ACGIH TLV: TWA 10 mg/m3.
Stability:Stable. Incompatible with strong oxidants.
InChIKeyWHDGWKAJBYRJJL-UHFFFAOYSA-K
CAS DataBase Reference14484-64-1
IARC3 (Vol. 12, Sup 7) 1987
EPA Substance Registry SystemFerbam (14484-64-1)
Safety Information
Hazard Codes Xi,N
Risk Statements 36/37/38-50/53
Safety Statements 26-36/37/39-61-60
RIDADR UN3077 9/PG 3
RTECS NO8750000
TSCA Yes
HazardClass 6.1
PackingGroup II
HS Code 29302000
Hazardous Substances Data14484-64-1(Hazardous Substances Data)
ToxicityLD50 in male mice, rats (mg/kg): 3000, 2700 i.p. (Hodge)
MSDS Information
FERBAM Usage And Synthesis
Chemical Propertiesodourless black solid
Chemical PropertiesFerbam is a combustible, odorless dark brown to black powder or granular solid
UsesNonphytotoxic fungicide used to control scab on fruits and other crops.
UsesFerbam is a protective fungicide applied to foliage to control scab on pome fruit, peach leaf curl, blue mould on tobacco and other diseases on many other crops. It is often used in combinations with other dithiocarbamates to extend the spectrum of activity.
UsesFruit fungicide.
DefinitionA wettable powder containing 76% ferbam.
General DescriptionFerbam is a carbamate fungicide. It is a stable, black powder and combustible and gives off irritating or toxic fumes (or gases) in a fire. Ferbam is incompatible with strong oxidants. It is used for foliar protectant against scab, rust, mould, and many fungal diseases on fruits, vegetables, melons, and ornamentals. Also, it works as a repellent towards Japanese beetles. The major uses of ferbam are in the control of apple scab and cedar apple rust, peach leaf curl, tobacco blue mould, and cranberry diseases. Ferbam is a broad-spectrum registered fungicide for the control of certain diseases in fruit trees, small fruit and berry crops, potatoes, ornamentals, conifers, and tobacco and for use on citrus, pome, stone fruits, and cranberries. Major areas of use include Florida, Massachusetts, New Jersey, and other countries. Ferbam is used as water-dispersible granule, 76WG.
Air & Water ReactionsThio and dithiocarbamates slowly decompose in aqueous solution to form carbon disulfide and methylamine or other amines. Such decompositions are accelerated by acids.
Reactivity ProfileFERBAM is a dithiocarbamate. Flammable gases are generated by the combination of thiocarbamates and dithiocarbamates with aldehydes, nitrides, and hydrides. Thiocarbamates and dithiocarbamates are incompatible with acids, peroxides, and acid halides.
HazardIrritant to eyes and mucous membranes. Questionable carcinogen.
Health HazardFerbam is an irritant of the eyes and respiratory tract; in animals it causes central nervous system depression, and it is expected that severe exposure will cause the same effect in humans.
Agricultural UsesFungicide: Registered for use in the U.S. and Canada. Not approved for use in EU countries. A dimethyl-dithiocarbamate fungicide. It is widely used, together with other fungicides, to control Postbloom Fruit Drop (PFD) on citrus crops, and as a foliar protectant against scab, rust, mold and many fungus disease on fruits, vegetables, melons and ornamentals. It is registered in several states for use on currents and gooseberries to control leaf spot disease, and on apple, crabapple, hawthorn and quince to control cedar-apple rust disease. It is used to control rust disease on shrubs and ornamentals.
Trade nameAI3-14689®; AAFERTIS®; APPLE DUST No. 1®[C]; BERCEMA FERTAM 50®; CASWELL No. 458®; FERBAM 50®; FERBECK®; FERMATE FERBAM FUNGICIDE®[C]; FERMOCIDE®; FERRADOUR®; FERRADOW®; FUKLASIN ULTRA®; HEXAFERB®; HOKMATE®; KARBAM BLACK®; KARBAM CARBAMATE®; KNOCKMATE®; NIACIDE®; STAUFFER FERBAM®; SUP’R-FLO FERBAM FLOWABLE®; TRICARBAMIX®[C]; TRIFUNGOL®; VANCIDE FE95®[C]
Safety ProfilePoison by intraperitoneal route. Moderately toxic by ingestion. Experimental teratogenic and reproductive effects. Questionable carcinogen with experimental carcinogenic and tumorigenic data. Mutation data reported. A fungicide. When heated to decomposition it emits very toxic fumes of NOx and SOx. See also CARBAiMATES.
Potential ExposureA dithiocarbamate. A potential danger to those involved in the production, formulation and application of this dithiocarbamate; used as a fungicide, rubber accelerator, and plastics prodegradant. Some dithiocarbamates have been used as rubber components
Environmental FatePlant. Decomposes in plants to ethylene thiourea, ethylene thiuram monosul?de, ethylene thiuram disul?de and sulfur (Hartley and Kidd, 1987).
Chemical/Physical. Hydrolyzes in acidic media releasing carbon disul?de. Decomposes in water forming ethylene thiourea (Hartley and Kidd, 1987).
Decomposes >180°C (Windholz et al., 1983) emitting toxic fumes of nitrogen and sulfur oxides (Lewis, 1990; Sax and Lewis, 1987).
Metabolic pathwayFerbam generates dimethyldithiocarbamic acid by being cleaved in acidic conditions and in biological media. The acid is conjugated with glucose and alanine in plants and with glucuronic acid in mammals. Dimethyldithiocarbamic acid is further degraded to dimethylamine and CS2. An extensive review of the properties of the dithiocarbamate pesticides was published by the World Health Organisation (WHO, 1988) from which much of the following information is taken.
ShippingUN2771 Dithiocarbamate and Thiocarbamate pesticides, solid, toxic, Hazard Class: 6.1; Labels: 6.1-Poisonous materials. UN3077 Environmentally hazardous substances, solid, n.o.s., Hazard class: 9; Labels: 9-Miscellaneous hazardous material, Technical Name Required
DegradationFerbam is hydrolysed in acidic media forming dimethyldithiocarbamic acid (2) that in turn decomposes to liberate carbon disulfide (PM) (see Scheme 1).
IncompatibilitiesIncompatible with oxidizers (chlorates, nitrates, peroxides, permanganates, perchlorates, chlorine,bromine, fluorine, etc.); contact may cause fires or explosions. Keep away from alkaline materials, strong bases, strong acids, oxoacids, epoxides. Heat alkalies (lime); moisture can cause decomposition. Decomposes on prolonged storage. Dithiocarbamate esters are combustible. They react violently with powerful oxidizers such as calcium hypochlorite. Poisonous gases are generated by the thermal decomposition of Dithiocarbamate compounds, including carbon disulfide, oxides of sulfur, oxides of nitrogen, hydrogen sulfide, ammonia, and methylamine. Thio and dithiocarbamates slowly decompose in aqueous solution to form carbon disulfide and methylamine or other amines. Such decompositions are accelerated by acids. Flammable gases are generated by the combination of dithiocarbamate with aldehydes, nitrides, and hydrides. Dithiocarbamate are incompatible with acids, peroxides, and acid halides.
Waste DisposalFerbam is hydrolyzed by alkali and is unstable to moisture, lime and heat. Ferbam can be incinerated. In accordance with 40CFR165, follow recommendations for the disposal of pesticides and pesticide containers. Must be disposed properly by following package label directions or by contacting your local or federal environmental control agency, or by contacting your regional EPA office. Consult with environmental regulatory agencies for guidance on acceptable disposal practices. Generators of waste containing this contaminant (≥100 kg/mo) must conform with EPA regulations governing storage, transportation, treatment, and waste disposal
FERBAM Preparation Products And Raw materials
Tag:FERBAM(14484-64-1) Related Product Information
BIS(DITHIOBENZIL) NICKEL Cupric acetate monohydrate Iron(III) citrate Propineb Sodium hydrosulfide Dimethyl disulfide FERBAM FERBAM SOLUTION 100UG/ML IN METHANOL 1ML FERBAM SOLUTION 100UG/ML IN TOLUENE 1ML tris(dibutyldithiocarbamato-S,S')iron DIETHYLDITHIOCARBAMIC ACID FERRIC SALT