2,5-DI-TERT-BUTYLANILINE manufacturers
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| | 2,5-DI-TERT-BUTYLANILINE Basic information |
| | 2,5-DI-TERT-BUTYLANILINE Chemical Properties |
| Melting point | 103-106 °C (lit.) | | form | powder | | BRN | 2691916 | | InChI | 1S/C14H23N/c1-13(2,3)10-7-8-11(12(15)9-10)14(4,5)6/h7-9H,15H2,1-6H3 | | InChIKey | NUZVLYNISQOZOW-UHFFFAOYSA-N | | SMILES | CC(C)(C)c1ccc(c(N)c1)C(C)(C)C | | CAS DataBase Reference | 21860-03-7 |
| Hazard Codes | Xi | | Risk Statements | 36/37/38 | | Safety Statements | 26-36 | | WGK Germany | 3 | | Storage Class | 11 - Combustible Solids | | Hazard Classifications | Eye Irrit. 2 Skin Irrit. 2 STOT SE 3 |
| | 2,5-DI-TERT-BUTYLANILINE Usage And Synthesis |
| Uses | 2,5-Di-tert-butylaniline has been used in the preparation of:
- new rigid bidentate nitrogen ligands 1,2-bis[(2,5-di-tert-butylphenyl)imino]acenaphthene (dtb-BIAN)
- N-(2,5-di-tert-butylphenyl)perylene-3,4-dicarboximide
| | Purification Methods | The aniline recrystallises from EtOH in fine needles after steam distillation. It has a pKa2 5 of 3.58 (50% aqueous EtOH). The tosylate has m 164o (from AcOH). [Bell & Wilson J Chem Soc 2340 1956, Carpenter et al. J Org Chem 16 586 1951, Bartlett et al. J Am Chem Soc 76 2349 1954, Beilstein 12 IV 2891.] |
| | 2,5-DI-TERT-BUTYLANILINE Preparation Products And Raw materials |
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