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Bis[1,2-bis(diphenylphosphino)ethane]palladium(0)

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Company Name: Capot Chemical Co.,Ltd.
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Products Intro: Product Name:Bis[1,2-bis(diphenylphosphino)ethane]palladium(0)
CAS:31277-98-2
Purity:98%(Min,HPLC) Package:100g;1kg;5kg,10kg,25kg,50kg
Company Name: career henan chemical co
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Products Intro: Product Name:Bis[1,2-bis(diphenylphosphino)ethane]palladium(0)
CAS:31277-98-2
Purity:95%-99% Package:1kg;1USD
Company Name: Nanjing Dolon Biotechnology Co.,Ltd.
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Products Intro: Product Name:Bis[1,2-bis(diphenylphosphino)ethane]palladium(0)
CAS:31277-98-2
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Products Intro: Product Name:Bis[1,2-bis(diphenylphosphino)ethane]palladium(0)
CAS:31277-98-2
Purity:99%min Package:100g/bottle;500g/bottle;1kg/bottle;10kg/drum;50kg/drum;100kg/drum;5272T/drum;
Company Name: Antai Fine Chemical Technology Co.,Limited
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Products Intro: Product Name:Bis[1,2-bis(diphenylphosphino)ethane]palladium(0)
CAS:31277-98-2
Package:1KG;5KG;25KG Remarks:Orange crystal powder

Bis[1,2-bis(diphenylphosphino)ethane]palladium(0) manufacturers

Bis[1,2-bis(diphenylphosphino)ethane]palladium(0) Basic information
Product Name:Bis[1,2-bis(diphenylphosphino)ethane]palladium(0)
Synonyms:BIS[1,2-BIS(DIPHENYLPHOSPHINO)ETHANE]-PALLADIUM;BIS[1,2-BIS(DIPHENYLPHOSPHINO)ETHANE]PALLADIUM(0);BIS(DIPHOS)PALLADIUM(0);PD(DIPHOS)2;bis(ethylenebis(diphenylphosphine))palladium;Bisbisdiphenylphosphinoethanepalladium;Bis[1,2-bis(diphenylphosphino)ethane]palladium(0),98%;Pd(dppe)2
CAS:31277-98-2
MF:C52H48P4Pd
MW:903.25
EINECS:625-554-6
Product Categories:Pd;Pyrimidines;metal-phosphine complexes;Catalysts for Organic Synthesis;Classes of Metal Compounds;Homogeneous Catalysts;Metal Complexes;Pd (Palladium) Compounds;Synthetic Organic Chemistry;Transition Metal Compounds
Mol File:31277-98-2.mol
Bis[1,2-bis(diphenylphosphino)ethane]palladium(0) Structure
Bis[1,2-bis(diphenylphosphino)ethane]palladium(0) Chemical Properties
Melting point 219-225 °C
storage temp. -20°C
solubility sol nonprotic solvents
form Powder
color orange
Water Solubility insoluble
Sensitive Air Sensitive
InChIInChI=1S/2C26H24P2.Pd/c2*1-5-13-23(14-6-1)27(24-15-7-2-8-16-24)21-22-28(25-17-9-3-10-18-25)26-19-11-4-12-20-26;/h2*1-20H,21-22H2;
InChIKeyUTBLWXFSGOYWOH-UHFFFAOYSA-R
SMILESP(CCP(C1=CC=CC=C1)C1=CC=CC=C1)(C1C=CC=CC=1)C1=CC=CC=C1.P(CCP(C1=CC=CC=C1)C1=CC=CC=C1)(C1=CC=CC=C1)C1=CC=CC=C1.[Pd]
CAS DataBase Reference31277-98-2
Safety Information
Hazard Codes Xn,Xi
Risk Statements 20/21/22-36/37/38
Safety Statements 36-37/39-26
RIDADR 1479
WGK Germany 3
HazardClass 5.1
PackingGroup III
HS Code 28439000
Storage Class11 - Combustible Solids
Hazard ClassificationsAcute Tox. 4 Dermal
Acute Tox. 4 Inhalation
Acute Tox. 4 Oral
MSDS Information
ProviderLanguage
ACROS English
SigmaAldrich English
ALFA English
Bis[1,2-bis(diphenylphosphino)ethane]palladium(0) Usage And Synthesis
Chemical Propertiesyellow to orange crystalline powder
UsesBis[1,2-bis(diphenylphosphino)ethane]palladium(0) is a homogeneous catalyst most widely used in allylic substitution reactions; good catalyst for bulky substrates; slowly dissociating ligand that gives good stereoselectivity.
reaction suitabilitycore: palladium
reaction type: Buchwald-Hartwig Cross Coupling Reaction
reaction type: Cross Couplings
reaction type: Heck Reaction
reaction type: Hiyama Coupling
reaction type: Negishi Coupling
reaction type: Sonogashira Coupling
reaction type: Stille Coupling
reaction type: Suzuki-Miyaura Coupling
reagent type: catalyst
storageair and light sensitive. If stored under nitrogen or argon it is stable for  about one month. Avoid inhalation. Use in a fume hood.
Purification MethodsBis[1,2-bis(diphenylphosphino)ethane]palladium(0) can be recrystallized from benzene-ethanol or ethanol.
Bis[1,2-bis(diphenylphosphino)ethane]palladium(0) Preparation Products And Raw materials
Tag:Bis[1,2-bis(diphenylphosphino)ethane]palladium(0)(31277-98-2) Related Product Information
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