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N-(TERT-BUTOXYCARBONYL)-P-TOLUENESULFONAMIDE

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CAS:18303-04-3
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CAS:18303-04-3
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Products Intro: Product Name:N-(TERT-BUTOXYCARBONYL)-P-TOLUENESULFONAMIDE
CAS:18303-04-3
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N-(TERT-BUTOXYCARBONYL)-P-TOLUENESULFONAMIDE manufacturers

N-(TERT-BUTOXYCARBONYL)-P-TOLUENESULFONAMIDE Basic information
Product Name:N-(TERT-BUTOXYCARBONYL)-P-TOLUENESULFONAMIDE
Synonyms:LABOTEST-BB LT00453242;N-(TERT-BUTOXYCARBONYL)-P-TOLUENESULFONAMIDE;N-BOC-P-TOLUENESULFONAMIDE;N-(tert-Butoxycarbonyl-p-tolunesulfonamide;(tert-Butoxycarbonyl)tosylamine;N-(p-Tolylsulfonyl)carbamic acid tert-butyl ester;N-Tosylcarbamic acid tert-butyl ester;Tosylcarbamic acid tert-butyl ester
CAS:18303-04-3
MF:C12H17NO4S
MW:271.33
EINECS:
Product Categories:Amination;Synthetic Organic Chemistry;Nitrogen Compounds;Organic Building Blocks;Protected Amines
Mol File:18303-04-3.mol
N-(TERT-BUTOXYCARBONYL)-P-TOLUENESULFONAMIDE Structure
N-(TERT-BUTOXYCARBONYL)-P-TOLUENESULFONAMIDE Chemical Properties
Melting point 121-123 °C(lit.)
density 1.201±0.06 g/cm3(Predicted)
storage temp. Sealed in dry,Room Temperature
solubility chloroform: soluble25mg/mL, clear, colorless
pka4.84±0.10(Predicted)
form powder to crystal
color White to Almost white
InChIKeyDUTLOVSBVBGNDM-UHFFFAOYSA-N
CAS DataBase Reference18303-04-3
Safety Information
Safety Statements 24/25
WGK Germany 3
HS Code 29350090
MSDS Information
ProviderLanguage
SigmaAldrich English
N-(TERT-BUTOXYCARBONYL)-P-TOLUENESULFONAMIDE Usage And Synthesis
UsesN-(tert-Butoxycarbonyl)-p-toluenesulfonamide may be used in the preparation of enyne amide, precursor for Pauson-Khand reaction.
Synthesis Reference(s)Tetrahedron Letters, 35, p. 379, 1994 DOI: 10.1016/0040-4039(94)85058-5
General DescriptionN-(tert-Butoxycarbonyl)-p-toluenesulfonamide is a N-substituted sulphonamide and its reaction with N-trityl L-serine esters under Mitsunobu reaction conditions is reported. It can be directly coupled with primary, secondary and allylic alcohols under Mitsunobu conditions to afford various sulfonyl-protected amines.
N-(TERT-BUTOXYCARBONYL)-P-TOLUENESULFONAMIDE Preparation Products And Raw materials
Tag:N-(TERT-BUTOXYCARBONYL)-P-TOLUENESULFONAMIDE(18303-04-3) Related Product Information
2-Azido-1,3-diMethyliMidazoliniuM Hexafluorophosphate Toluenesulfonamide N-(4-BROMO-2-BUTYNYL)-N-(TERT-BUTYLOXYCARBONYL)(4-METHYLPHENYL)SULFONAMIDE N-(PHENYLSULFONYL)-CARBAMIC ACID METHYL ESTER methyl tosylcarbamate Ethyl N-(4-methylphenyl)sulfonylcarbamate N-(TERT-BUTOXYCARBONYL)-P-TOLUENESULFONAMIDE