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ETHYLALUMINUM DICHLORIDE

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Products Intro: Product Name:ETHYLALUMINUM DICHLORIDE
CAS:563-43-9
Purity:0.99 Package:5KG;1KG
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CAS:563-43-9
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Products Intro: Product Name:ETHYLALUMINUM DICHLORIDE
CAS:563-43-9
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Products Intro: Product Name:Ethylaluminum Dichloride, 25% in Toluene
CAS:563-43-9
Purity:0.98 Package:1KG;5KG;25KG

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ETHYLALUMINUM DICHLORIDE Basic information
Product Name:ETHYLALUMINUM DICHLORIDE
Synonyms:Aluminiumethyldichloride;Aluminum,dichloroethyl-;Dichloro(ethyl)aluminium;dichloroethyl-aluminu;Dichloromonoethylaluminum;ethylaluminumdichloridesolution;ETHYLALUMINUM DICHLORIDE;Ethylaluminum dichloride solution 1.0 in hexanes
CAS:563-43-9
MF:C2H5AlCl2
MW:126.95
EINECS:209-248-6
Product Categories:Chemical Synthesis;Organoaluminum;Organometallics;Al (Alminum) Compounds;Catalysts for Organic Synthesis;Organometallic Reagents;Classes of Metal Compounds;Homogeneous Catalysts;Synthetic Organic Chemistry;Titanium Alkoxides, etc. (Homogeneous Catalysts);Typical Metal Compounds
Mol File:563-43-9.mol
ETHYLALUMINUM DICHLORIDE Structure
ETHYLALUMINUM DICHLORIDE Chemical Properties
Melting point 32 °C(lit.)
Boiling point 68-70°C
density 0.927 g/mL at 25 °C
vapor pressure 5 mm Hg ( 60 °C)
Fp 40 °F
storage temp. 0-6°C
form Liquid
Specific Gravity0.927
Specific Gravity0.73
color Colorless to pale yellow
Water Solubility Soluble in acetone. Miscible with alcohol, chloroform, ether. Reacts with water.
FreezingPoint 32℃
Sensitive Air & Moisture Sensitive
Hydrolytic Sensitivity8: reacts rapidly with moisture, water, protic solvents
Hydrolytic Sensitivity9: reacts extremely rapidly with atmospheric moisture - may be pyrophoric - glove box or sealed system required
Merck 326
BRN 4123357
InChIKeyUAIZDWNSWGTKFZ-UHFFFAOYSA-L
CAS DataBase Reference563-43-9(CAS DataBase Reference)
EPA Substance Registry SystemAluminum, dichloroethyl- (563-43-9)
Safety Information
Hazard Codes F,T,N,C
Risk Statements 11-15-23/24/25-34-14-67-65-62-51/53-48/20-14/15-17-63
Safety Statements 16-26-36/37/39-45-62-61-43-27
RIDADR UN 3399 4.3/PG 1
WGK Germany 1
RTECS BD0705000
10-21
TSCA Yes
HazardClass 4.3
PackingGroup I
HS Code 29319090
Hazardous Substances Data563-43-9(Hazardous Substances Data)
MSDS Information
ProviderLanguage
ACROS English
SigmaAldrich English
ALFA English
ETHYLALUMINUM DICHLORIDE Usage And Synthesis
Chemical PropertiesClear colorless to yellow solution
Chemical PropertiesThe aluminum alkyl halides are flammable, reactive, and may be spontaneously combustible in air. They are colorless to yellow liquids. Ethylaluminum dichloride:(563-43-9):
UsesCatalyst for olefin polymerization, aromatic hydrogenation; intermediate.
General DescriptionA colorless to light-yellow heated liquid. Freezing point 90°F.
Air & Water ReactionsHighly flammable. Ignites when exposed to air. Reacts violently with water or moisture in air forming hydrogen chloride fumes and flammable ethane gas (Rose 1961).
Reactivity ProfileOrganometallics, such as ETHYLALUMINUM DICHLORIDE, are reactive with many other groups. Incompatible with acids and bases. Organometallics are good reducing agents and therefore incompatible with oxidizing agents. Often reactive with water to generate toxic or flammable gases. Organometallics containing halogens (fluorine, chlorine, bromine, iodine) bonded to the metal typically with generate gaseous hydrohalic acids (HF, HCl, HBr, HI) with water.
HazardIgnites on contact with air, dangerous fire risk, reacts violently with water. Skin irritant.
Health HazardInhalation of smoke from fire causes metal-fume fever (flu-like symptoms); acid fumes irritate nose and throat. Contact with liquid (which is spontaneously flammable) causes severe burns of eyes and skin.
Potential ExposureThese materials are used as components of olefin polymerization catalysts. The reader is referred to the entry on “Aluminum alkyls” for additional information on this entry. The aluminum alkyl halides parallel very closely the aluminum alkyls
ShippingUN3052 Spontaneously combustible. Water reactive releasing large quantities of toxic and deadly hydrogen gas. (Note: this number does not appear in the 49/CFR HazMat tables)
IncompatibilitiesThe aluminum alkyl halides are strong reducing agents; they react—possibly violently—with oxidizers (chlorates, nitrates, peroxides, permanganates, perchlorates, chlorine, bromine, fluorine, etc.); contact may cause fires or explosions. Keep away from alkaline materials, strong bases, strong acids, oxoacids, epoxides. These chemicals react violently with nitromethaneEthylaluminum sesquichloride reacts explosively with carbon tetrachloride at room temperature. This chemical reacts violently with water, forming corrosive hydrogen chloride and flammable ethane gas. Diethylaluminum chloride may form an explosive product with chlorine azide.
Tag:ETHYLALUMINUM DICHLORIDE(563-43-9) Related Product Information
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