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(3S,3'S,4S,4'S,11BS,11'BS)-(+)-4,4'-DI-T-BUTYL-4,4',5,5'-TETRAHYDRO-3,3'-BI-3H-DINAPHTHO[2,1-C:1',2'-E]PHOSPHEPIN

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(3S,3'S,4S,4'S,11BS,11'BS)-(+)-4,4'-DI-T-BUTYL-4,4',5,5'-TETRAHYDRO-3,3'-BI-3H-DINAPHTHO[2,1-C:1',2'-E]PHOSPHEPIN Suppliers list
Company Name: career henan chemical co
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Products Intro: Product Name:(3S,3'S,4S,4'S,11BS,11'BS)-(+)-4,4'-DI-T-BUTYL-4,4',5,5'-TETRAHYDRO-3,3'-BI-3H-DINAPHTHO[2,1-C:1',2'-E]PHOSPHEPIN
CAS:610304-81-9
Purity:97%-99.9% Package:1KG;1USD
Company Name: Zibo Hangyu Biotechnology Development Co., Ltd
Tel: +86-0533-2185556 +8617865335152
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Products Intro: CAS:610304-81-9
Purity:0.99 Package:5KG;1KG
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Company Name: J & K SCIENTIFIC LTD.  
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Products Intro: Product Name:(3S,3'S,4S,4'S,11bS,11'bS)-(+)-4,4'-Di-t-butyl-4,4',5,5'-tetrahydro-3,3'-bi-3H-dinaphtho[2,1-c:1',2'-e]phosphepin, 97% (S)-BINAPINE
CAS:610304-81-9
Purity:97% Package:250mg;50mg
Company Name: Meryer (Shanghai) Chemical Technology Co., Ltd.  
Tel: 4006608290; 18621169109
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Products Intro: Product Name:(3S,3'S,4S,4'S,11bS,11'bS)-(+)-4,4'-Di-t-butyl-4,4',5,5'-tetrahydro-3,3'-bi-3H-dinaphtho[2,1-c:1',2'-e]phosphepin
CAS:610304-81-9
Purity:97% Remarks:AAM156767

(3S,3'S,4S,4'S,11BS,11'BS)-(+)-4,4'-DI-T-BUTYL-4,4',5,5'-TETRAHYDRO-3,3'-BI-3H-DINAPHTHO[2,1-C:1',2'-E]PHOSPHEPIN manufacturers
(3S,3'S,4S,4'S,11BS,11'BS)-(+)-4,4'-DI-T-BUTYL-4,4',5,5'-TETRAHYDRO-3,3'-BI-3H-DINAPHTHO[2,1-C:1',2'-E]PHOSPHEPIN Basic information
Reaction
Product Name:(3S,3'S,4S,4'S,11BS,11'BS)-(+)-4,4'-DI-T-BUTYL-4,4',5,5'-TETRAHYDRO-3,3'-BI-3H-DINAPHTHO[2,1-C:1',2'-E]PHOSPHEPIN
Synonyms:(3S,3'S,4S,4'S,11bS,11'bS)-(+)-4,4'-Di-t-butyl-4,4',5,5'-tetrahydro-3,3'-bi-3H-dinaphtho[2,1-c:1',2'-e]phosphepin (S)-BINAPINE;(3S,3'S,4S,4'S,11BS,11'BS)-(+)-4,4'-DI-T-BUTYL-4,4',5,5'-TETRAHYDRO-3,3'-BI-3H-DINAPHTHO[2,1-C:1',2'-E]PHOSPHEPIN;(S)-BINAPINE;(3S,3'S,4S,4'S,11bS,11'bS)-(+)-4,4'-Di-t-butyl-4,4',5,5'-tetrahydro-3,3'-bi-3H-dinaphtho[2,1-c:1',2'-e]phosphepin,97%(S)-BINAPINE;BINAPINE (Mixture);(3S,3'S)-4,4'-di-tert-butyl-4,4',5,5'-tetrahydro-3H,3'H-3,3'-bidinaphtho[2,1-c:1',2'-e]phosphepine
CAS:610304-81-9
MF:C52H48P2
MW:734.89
EINECS:
Product Categories:
Mol File:610304-81-9.mol
(3S,3'S,4S,4'S,11BS,11'BS)-(+)-4,4'-DI-T-BUTYL-4,4',5,5'-TETRAHYDRO-3,3'-BI-3H-DINAPHTHO[2,1-C:1',2'-E]PHOSPHEPIN Structure
(3S,3'S,4S,4'S,11BS,11'BS)-(+)-4,4'-DI-T-BUTYL-4,4',5,5'-TETRAHYDRO-3,3'-BI-3H-DINAPHTHO[2,1-C:1',2'-E]PHOSPHEPIN Chemical Properties
Melting point >300 °C (dec.)(lit.)
form Powder
color white to light yellow
Sensitive air sensitive
CAS DataBase Reference610304-81-9
Safety Information
Risk Statements 36/37/38
Safety Statements 26-36/37/39
WGK Germany 3
MSDS Information
ProviderLanguage
SigmaAldrich English
(3S,3'S,4S,4'S,11BS,11'BS)-(+)-4,4'-DI-T-BUTYL-4,4',5,5'-TETRAHYDRO-3,3'-BI-3H-DINAPHTHO[2,1-C:1',2'-E]PHOSPHEPIN Usage And Synthesis
Reaction
  1. Rhodium complex used in asymmetric hydroformylation reactions.
  2. Ligand-palladium complex used in enantioselective carbonyl-ene reactions.
  3. Nickel-catalyzed asymmetric transfer hydrogenation of olefins for the synthesis of αand βamino acids.
  4. Nickel-catalyzed asymmetric transfer hydrogenation of hydrazones and other ketimines.
  5. Nickel/ligand catalyst used in the enantioselective reductive amination of ketones with both arylamines and benzhydrazide,
  6. Rh-Binapine and Pd-Binapine complexes form excellent catalysts for asymmetric (transfer) hydrogenation of aryl substituted olefins to form β-amino acids.
Reactions of 610304-81-9_1
Reactions of 610304-81-9_2
Reactions of 610304-81-9_3
(3S,3'S,4S,4'S,11BS,11'BS)-(+)-4,4'-DI-T-BUTYL-4,4',5,5'-TETRAHYDRO-3,3'-BI-3H-DINAPHTHO[2,1-C:1',2'-E]PHOSPHEPIN Preparation Products And Raw materials
Tag:(3S,3'S,4S,4'S,11BS,11'BS)-(+)-4,4'-DI-T-BUTYL-4,4',5,5'-TETRAHYDRO-3,3'-BI-3H-DINAPHTHO[2,1-C:1',2'-E]PHOSPHEPIN(610304-81-9) Related Product Information
(3S,3'S,4S,4'S,11BS,11'BS)-(+)-4,4'-DI-T-BUTYL-4,4',5,5'-TETRAHYDRO-3,3'-BI-3H-DINAPHTHO[2,1-C:1',2'-E]PHOSPHEPIN(1,5-CYCLOOCTADIENE)RHODIUM (I) TETRAFLUOROBORATE DIBENZYLPHOSPHINE 2-Methyl-1,1'-binaphthalene (3S,3'S,4S,4'S,11BS,11'BS)-(+)-4,4'-DI-T-BUTYL-4,4',5,5'-TETRAHYDRO-3,3'-BI-3H-DINAPHTHO[2,1-C:1',2'-E]PHOSPHEPIN 1,2-BIS(DIETHYLPHOSPHINO)ETHANE (S,S)-1,2-BIS(TERT-BUTYLMETHYLPHOSPHINO)ETHANE