D-fructose 6-(dihydrogen phosphate)

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CAS:643-13-0
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Products Intro: Product Name:Fructose 6-phosphate
CAS:643-13-0
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D-fructose 6-(dihydrogen phosphate) Basic information
Product Name:D-fructose 6-(dihydrogen phosphate)
Synonyms:lactacidogen;D-fructose 6-(dihydrogen phosphate);[(2R,3R,4S)-2,3,4,6-tetrahydroxy-5-oxo-hexoxy]phosphonic acid;D-Fructose 6-phosphoric acid;Fru6-P;Fructose 6-phosphoric acid;Fructose-6-phosphoric acid;A-D-fructose-6-P
CAS:643-13-0
MF:C6H13O9P
MW:260.14
EINECS:211-395-6
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Mol File:643-13-0.mol
D-fructose 6-(dihydrogen phosphate) Structure
D-fructose 6-(dihydrogen phosphate) Chemical Properties
alpha D21 +2.5° (c = 3), Meyerhof, Lohmann, Biochem. Z. 185, 117 (1927); D +1.2° (c = 0.9), Lohmann, ibid. 262, 145 (1933)
Boiling point 697.7±65.0 °C(Predicted)
density 1.840±0.06 g/cm3(Predicted)
pka1.83±0.10(Predicted)
EPA Substance Registry SystemD-Fructose, 6-(dihydrogen phosphate) (643-13-0)
Safety Information
RIDADR 1759
HazardClass 8
PackingGroup III
MSDS Information
D-fructose 6-(dihydrogen phosphate) Usage And Synthesis
DefinitionChEBI: Keto-D-fructose 6-phosphate is the open chain form of D-fructose 6-phosphate. It is functionally related to a D-fructose. It is a conjugate acid of a D-fructose 6-phosphate(2-).
Purification MethodsCrystallise fructose-6-phosphate as the barium salt from water by adding 4-volumes of EtOH. The barium can be removed by passage through the H+ form of a cation exchange resin, and the free acid is collected by freeze-drying. Alternatively the Ba salt is dissolved in H2O, and one equivalent of Na2SO4 is added in small portions with stirring, filter off BaSO4 and freeze dry to give the Na salt. The 6-phosphate hydrolyses more slowly than the 1-phosphate and considerably slower than pyrophosphoric acid (102 times) and triphosphoric acid (103 times). [Neuberg Biochem Zeitschrift 88 432 1918, pKa: Meyerhof & Lohmann Biochem Zeitschrift 185 113, 131 1927, Neuberg et al. Arch Biochem 3 33, 40 1944, Hydrolysis: Friess J Am Chem Soc 74 5521 1954, Beilstein 1 I 464, 1 IV 4423, H 31 537.]
D-fructose 6-(dihydrogen phosphate) Preparation Products And Raw materials
Tag:D-fructose 6-(dihydrogen phosphate)(643-13-0) Related Product Information
ETHANE Maltose Fructose sodium diphosphate Phosphoric acid URIDINE 5'-DIPHOSPHOGLUCOSE DISODIUM SALT Succinylcholine Chloride 3-PHOSPHOGLYCERIC PHOSPHOKINASE 6-PHOSPHOFRUCTOKINASE TYPE VII Repaglinide Calcium lactate D-Glucuronic acid Arabic gum