IRON(III) PERCHLORATE HYDRATE manufacturers
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| | IRON(III) PERCHLORATE HYDRATE Basic information |
| Product Name: | IRON(III) PERCHLORATE HYDRATE | | Synonyms: | Perchloricacid,iron(3+)salt;perchloricacid,iron(3++)salt;IRON(III) PERCHLORATE HYDRATE, LOW CHLORIDE;IRON(III) PERCHLORATE HYDRATE;IRON(III) PERCHLORATE N-HYDRATE;IRON (III) PERCHLORATE HYDRATE, YELLOW;IRON(+3)PERCHLORATE HYDRATE;FERRIC PERCHLORATE, HYDRATED | | CAS: | 13537-24-1 | | MF: | Cl3FeH2O13 | | MW: | 372.21 | | EINECS: | 236-908-0 | | Product Categories: | Inorganics | | Mol File: | 13537-24-1.mol |  |
| | IRON(III) PERCHLORATE HYDRATE Chemical Properties |
| Hazard Codes | O,Xi | | Risk Statements | 8-36/37/38 | | Safety Statements | 17-26-27 | | RIDADR | UN 1481 5.1/PG 2 | | WGK Germany | 3 | | HazardClass | 5.1 | | PackingGroup | II |
| | IRON(III) PERCHLORATE HYDRATE Usage And Synthesis |
| Chemical Properties | yellow crystal(s); hygroscopic [STR93] | | Preparation | This crystallizes as the pale pink decahydrate Fe(ClO4)3.10H2O
from solutions of iron(III) chloride or hydrous iron(III) oxide in perchloric acid. Upon
standing over phosphorus pentoxide the decahydrate becomes the hexahydrate ; a 9-hydrate
crystallizes from solution above 42°. This salt has been important in the study of the
hydrated Fe3+ ion since perchlorate ions have only very low coordinating ability. | | Purification Methods | Crystallise it twice from conc HClO4, the first time in the presence of a small amount of H2O2 to ensure that the iron is fully oxidised [Sullivan J Am Chem Soc 84 4256 1962]. Extreme care should be taken with this preparation because it is potentially EXPLOSIVE. |
| | IRON(III) PERCHLORATE HYDRATE Preparation Products And Raw materials |
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