|
|
| | TRIETHYL 2-PHOSPHONOPROPIONATE Basic information |
| | TRIETHYL 2-PHOSPHONOPROPIONATE Chemical Properties |
| Melting point | 161-164° | | Boiling point | 143-144 °C12 mm Hg(lit.) | | density | 1.111 g/mL at 25 °C(lit.) | | refractive index | n20/D 1.431(lit.) | | Fp | 192 °F | | storage temp. | Inert atmosphere,Room Temperature | | solubility | Miscible with chloroform and methanol. | | form | Liquid | | Specific Gravity | 1.111 | | color | Clear colorless | | BRN | 1786994 | | InChIKey | BVSRWCMAJISCTD-UHFFFAOYSA-N | | CAS DataBase Reference | 3699-66-9(CAS DataBase Reference) |
| | TRIETHYL 2-PHOSPHONOPROPIONATE Usage And Synthesis |
| Chemical Properties | CLEAR COLOURLESS LIQUID | | Uses | Triethyl 2-Phosphonopropionate is used in studies involving insecticides and their efficacy on various bacterium. Also act as inhibitors of Epstein-Bar virus transmission and infections. | | Uses | Triethyl 2-phosphonopropionate is used as a reactant in intramolecular conjugate addition for the synthesis of floresolide B, enantioselective synthesis of spiroindane di-methyl acetic acid and in stereo selective intramolecular Diels-Alder reactions. It plays an important role in Horner-Wadsworth-Emmons reactions and chemoenzymatic one-pot synthesis of gamma-butyrolactones. It is also used in the preparation of 3-[2]furyl-2-methyl-acrylic acid ethyl ester by reacting with furfural. | | Purification Methods | Purify it by fractional distillation with high reflux ratio, preferably using a spinning band column. [Kosolapoff & Powell J Am Chem Soc 72 4198 1950, Kresze et al. Justus Liebigs Ann Chem 756 112 1972, Beilstein 4 IV 3617.] |
| | TRIETHYL 2-PHOSPHONOPROPIONATE Preparation Products And Raw materials |
|