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Di-tert-butylchlorophosphane

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Products Intro: Product Name:Di-t-butylchlorophosphine
CAS:13716-10-4
Purity:98% Package:1kg;USD|10kg;USD|25kg;USD
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Products Intro: Product Name:Di-tert-butylchlorophosphane
CAS:13716-10-4
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Products Intro: Product Name:Di-tert-butylchlorophosphane
CAS:13716-10-4
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Products Intro: Product Name:Di-tert-butylchlorophosphane
CAS:13716-10-4
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Products Intro: Product Name:Di-tert-butylchlorophosphane
CAS:13716-10-4
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Di-tert-butylchlorophosphane manufacturers

Di-tert-butylchlorophosphane Basic information
Product Name:Di-tert-butylchlorophosphane
Synonyms:AURORA KA-1319;Bis(1,1-dimethylethyl)-phosphinous chloride;DI-T-BUTYLCHLOROPHOSPHINE;DI-T-BUTYLPHOSPHINOUS CHLORIDE;DI-TERT-BUTYLPHOSPHORUS CHLORIDE;DI-TERT-BUTYLCHLOROPHOSPHANE;(tert-C4H9)2PCl;Di-tert-Butylphosphinous chloride
CAS:13716-10-4
MF:C8H18ClP
MW:180.66
EINECS:237-266-4
Product Categories:organophosphine halide;Catalysis and Inorganic Chemistry;Phosphorus Compounds;Phosphorus Precursors;Phosphines;Ligand;Chlorophosphines;Achiral Phosphine;Alkyl Phosphine;P-Cl
Mol File:13716-10-4.mol
Di-tert-butylchlorophosphane Structure
Di-tert-butylchlorophosphane Chemical Properties
Melting point 2-3°C
Boiling point 48 °C/3 mmHg (lit.)
density 0.951 g/mL at 25 °C (lit.)
refractive index n20/D 1.482(lit.)
Fp 142 °F
solubility Miscible with terahydrofuran.
form Liquid
Specific Gravity0.951
color Clear colorless
Sensitive Air & Moisture Sensitive
InChIKeyMCRSZLVSRGTMIH-UHFFFAOYSA-N
CAS DataBase Reference13716-10-4(CAS DataBase Reference)
NIST Chemistry ReferencePhosphinous chloride, bis(1,1-dimethylethyl)-(13716-10-4)
Safety Information
Hazard Codes C
Risk Statements 34
Safety Statements 26-36/37/39-45-25
RIDADR UN 3265 8/PG 2
WGK Germany 3
TSCA No
HazardClass 8
PackingGroup II
HS Code 29310099
MSDS Information
ProviderLanguage
ACROS English
SigmaAldrich English
Di-tert-butylchlorophosphane Usage And Synthesis
Chemical PropertiesColorless to light yellow liqui
UsesBulky ligand used with Pd(OAc)2 in efficient Suzuki-Miyaura cross-couplings of arylboronic acids with aryl bromides and chlorides.
UsesDi-tert-butylchlorophosphine is associated with palladium(II) acetate and used in Suzuki-Miyaura cross-couplings of arylboronic acids with aryl bromides and chlorides. It serves as a ligand and used in the preparation of mono- and bidentate phosphine ligands in metal complexes for catalytic chiral asymmetric hydrogenations. Further, it is used in asymmetric and transition metal coupling reactions. In addition to this, it plays an important role in the preparation of other phosphines in catalytic polymerization reactions.
UsesDi-tert-butylchlorophosphine is used as a catalyst in organic synthesis.
ApplicationBulky ligand used with Pd(OAc)2 in efficient Suzuki-Miyaura cross-couplings of arylboronic acids with aryl bromides and chlorides.
PrecautionsAir and moisture sensitive. Keep the container tightly closed in a dry and well-ventilated place. Incompatible with strong oxidizing agents and strong reducing agents.
Tag:Di-tert-butylchlorophosphane(13716-10-4) Related Product Information
DI-T-BUTYLPHOSPHINE OXIDE 2-Di-t-butylphosphino-4-Methoxy-3,5,6-triMethyl-2',4',6'-tri-i-propylbiphenyl, Min. 98% [~1:1 Mixture with regioisoMer, 2-Di-t-butylphosphino-5-Methoxy-3,4,6-triMethyl-2',4',6'-tri-i-propylbiphenyl] Lithium Aluminum Hydride Tetrakis(hydroxymethyl)phosphonium sulfate T-BUTYLPHOSPHINE DIBROMO(CHLORODI-TERT-BUTYLPHOSPHINE)PALLADIUM (II) DIMER DICHLOROBIS(CHLORODI-TERT-BUTYLPHOSPHINE) PALLADIUM (II) DI-1-ADAMANTYLPHOSPHINIC CHLORIDE DI-TERT-BUTYLCHLOROPHOSPHINE BORANE COMPLEX Di-tert-butylchlorophosphane DIBROMO(CHLORODI-T-BUTYLPHOSPHINE)PALLADIUM(II) DIMER AURORA KA-1706 DICHLORO(CHLORODI-TERT-BUTYLPHOSPHINE) PALLADIUM (II) DIMER AURORA KA-1182