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Product Name:Diacetato{(S)-(+)-5,5'-bis[di(3,5-di-t-butyl-4-Methoxyphenyl)phosphino]-4,4'-bi-1,3-benzodioxole}rutheniuM(II) Ru(OAc)2[(S)-dtbM-segphos?] CAS:1025476-84-9 Package:1g,250Mg,5g
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Product Name:Diacetato{(S)-(+)-5,5'-bis[di(3,5-di-t-butyl-4-methoxyphenyl)phosphino]-4,4'-bi-1,3-benzodioxole}ruthenium(II) CAS:1025476-84-9 Purity:97% Package:1g;5g;10g;15g;25g;100mg;250mg Remarks:NULL
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Aikon International Limited
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Product Name:Diacetato{(S)-(+)-5,5'-bis[di(3,5-di-t-butyl-4-methoxyphenyl)phosphino]-4,4'-bi-1,3-benzodioxole}ruthenium(II) CAS:1025476-84-9 Purity:95+% Package:1g;5g;10g
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| Diacetato{(S)-(+)-5,5'-bis[di(3,5-di-t-butyl-4-methoxyphenyl)phosphino]-4,4'-bi-1,3-benzodioxole}ruthenium(II) Ru(OAc)2[(S)-dtbm-segphos] Basic information |
Product Name: | Diacetato{(S)-(+)-5,5'-bis[di(3,5-di-t-butyl-4-methoxyphenyl)phosphino]-4,4'-bi-1,3-benzodioxole}ruthenium(II) Ru(OAc)2[(S)-dtbm-segphos] | Synonyms: | Diacetato{(S)-(+)-5,5'-bis[di(3,5-di-t-butyl-4-methoxyphenyl)phosphino]-4,4'-bi-1,3-benzodioxole}ruthenium(II) Ru(OAc)2[(S)-dtbm-segphos];Diacetato{(S)-(+)-5,5'-bis[di(3,5-di-t-butyl-4-methoxyphenyl)phosphino]-4,4'-bi-1,3-benzodioxole}ruthenium(II) Ru(OAc)2[(S)-dtbm-segphos(R)];Diacetato{(S)-(+)-5,5'-bis[di(3,5-di-t-butyL;e}ruthenium(II) Ru(OAc)2[(S)-dtbm-seg;Diacetato{(S)-(+)-5,5'-bis[di(3,5-di-t-butyl-4-methoxyphenyl)phosphino]-4,4'-bi-1,3-benzodioxole}ruthenium(II);RU(OAC)2[(S)-DTBM-SEGPHOS;Diacetato{(S)-(+)-5,5'-bis[di(3,5-di-t-butyl-4-methoxyphenyl)phosphino]-4,4'-bi-1,3-benzodioxole}ruthenium(II) Ru(OAc)2[(S)-dtbm-segphos;Diacetato{(S)-(+)-5,5''-bis[di(3,5-di-t-butyl-4-methoxyphenyl)phosphino]-4,4''-bi-1,3-benzodioxole}ruthenium(II) Ru(OAc)2[(S)-dtbm-segphos] | CAS: | 1025476-84-9 | MF: | C78H106O12P2Ru | MW: | 1398.686562 | EINECS: | | Product Categories: | | Mol File: | 1025476-84-9.mol | |
| Diacetato{(S)-(+)-5,5'-bis[di(3,5-di-t-butyl-4-methoxyphenyl)phosphino]-4,4'-bi-1,3-benzodioxole}ruthenium(II) Ru(OAc)2[(S)-dtbm-segphos] Chemical Properties |
form | solid | color | yellow to brownish-red to dark green | Sensitive | air sensitive | CAS DataBase Reference | 1025476-84-9 |
| Diacetato{(S)-(+)-5,5'-bis[di(3,5-di-t-butyl-4-methoxyphenyl)phosphino]-4,4'-bi-1,3-benzodioxole}ruthenium(II) Ru(OAc)2[(S)-dtbm-segphos] Usage And Synthesis |
Reactions |
- Biaryl bisphosphine ligand with narrow dihedral angle. The DM-SEGPHOS ligand, as the ruthenium complex, gives superior enantioselectivity and diastereoselectivity in the asymmetric hydrogenation of α-substituted-β-ketoesters.
- Ruthenium catalyzed enantioselective synthesis of β amino acids by hydrogenation.
- Ruthenium catalyzed asymmetric hydrogenation of 3-quinuclidinone.
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| Diacetato{(S)-(+)-5,5'-bis[di(3,5-di-t-butyl-4-methoxyphenyl)phosphino]-4,4'-bi-1,3-benzodioxole}ruthenium(II) Ru(OAc)2[(S)-dtbm-segphos] Preparation Products And Raw materials |
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