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Calcium hypophosphite

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CAS:7789-79-9
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Products Intro: Product Name:Calcium Hypophosphite
CAS:7789-79-9
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  • Calcium Hypophosphite
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  • $0.00 / 1kg
  • 2024-04-02
  • CAS:7789-79-9
  • Min. Order: 1kg
  • Purity: 99%
  • Supply Ability: 1000kg
  • Calcium hypophosphite
  • Calcium hypophosphite pictures
  • $0.00 / 25KG
  • 2023-09-08
  • CAS:7789-79-9
  • Min. Order: 1KG
  • Purity: 99%
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  • Calcium hypophosphite
  • Calcium hypophosphite pictures
  • $0.00 / 1kg
  • 2023-09-05
  • CAS:7789-79-9
  • Min. Order: 1kg
  • Purity: 99%
  • Supply Ability: 20tons
Calcium hypophosphite Basic information
Product Name:Calcium hypophosphite
Synonyms:CALCIUM HYPOPHOSPHITE;CALCIUM PHOSPHINATE;CALCIUM HYPOPHOSPHITE EXTRA PURE, DAC;Lime hypophosphite;CALCIUM HYPOPHOSPHITE TECHNICAL;Calcium hydrophosphite;CALCIUMHYPOPHOSPHITE,PURIFIED;Calcium bisphosphinate
CAS:7789-79-9
MF:Ca(H2PO2)2
MW:170.05
EINECS:232-190-8
Product Categories:Inorganics
Mol File:7789-79-9.mol
Calcium hypophosphite Structure
Calcium hypophosphite Chemical Properties
Melting point decomposes [ALF93]
Boiling point 480℃[at 101 325 Pa]
density 2.243[at 20℃]
solubility soluble in H2O; insoluble in ethanol
pka12.6[at 20 ℃]
form white monoclinic crystals
color white monoclinic crystals, crystalline
Water Solubility Soluble in water. Practically insoluble in alcohol. Slightly soluble in glycerol
Sensitive Hygroscopic
Merck 14,1675
InChIKeyXJPMAXXEWYLDCQ-UHFFFAOYSA-L
CAS DataBase Reference7789-79-9(CAS DataBase Reference)
EPA Substance Registry SystemCalcium hypophosphite (7789-79-9)
Safety Information
Hazard Codes F
Risk Statements 11
Safety Statements 7-15
RIDADR UN 3180 4.1/PG 2
WGK Germany 3
TSCA Yes
HazardClass 4.1
Hazardous Substances Data7789-79-9(Hazardous Substances Data)
MSDS Information
ProviderLanguage
Calcium hypophosphite English
SigmaAldrich English
ALFA English
Calcium hypophosphite Usage And Synthesis
DescriptionCalcium hypophosphite has the molecular formula of Ca(H2PO2)2 and the molecular weight of 170.0631 g/mol. This salt can be prepared by the aqueous reaction of the carbonate or oxide with H3PO2:
CaO + 2H3PO2 ? Ca(H2PO2)2
The salt is soluble in water (20 g/100 ml at 20°C) so that the solution must be evaporated to obtain crystals. Ca(H2PO2)2 has the CAS number of 7789-79-9 and the density of 1.59 g/cm3. It is composed of white square monoclinic crystalswhich are water soluble. It is insoluble in alcohol or ether.When heated to about 305°C, it disproportionates, forming calcium phosphate and phosphine:
Ca(H2PO2)2 + heat ? CaHPO3 + PH3
Chemical Propertieswhite monoclinic, prismatic crystal(s) or granular powder(s); used as a corrosion inhibitor and in medicine [MER06] [HAW93]
Physical propertiesCalcium hypophosphite is relatively soluble in water, and when added to a solution of sodium hypophosphite, forms a double salt. Crystals were obtained by slow evaporation of the solution to form dodecahedra with well-developed {110} faces. The crystal structure of CaNa(H2PO2)3 belongs to the cubic system with space group, P213, Z = 4 and a = 9.721?. The structure consists of two kinds of octahedral groups, one with a calcium atom and the other with a sodium atom. Each atom of the hypophosphite ions is coordinated to each one of the calcium and sodium atoms to form the octahedral. This structure is, in general, typical of the salts of hypophosphorous acid.
Calcium hypophosphite is readily available commercially since its main usage, both industrially and in Research, has proven to be as a source of hypophosphite anions to form other hypophosphites.
UsesAs corrosion inhibitor; in nickel plating. Pharmaceutic aid (retards oxidation of ferrous salts).
UsesIt is employed as dietary supplement. The product is used as a flame retardant and applied to chemical plating. Moreover, the product is used as a food additive and an animal nutrition agent, applied to the manufacture of pharmaceutical products, as well as antioxidant and analytical reagent.
Flammability and ExplosibilityHighly flammable
Calcium hypophosphite Preparation Products And Raw materials
Raw materialsCalcium hydroxide-->Phosphorus-->White phosphorus-->Water-->Phosphine
Preparation ProductsSodium hypophosphite-->SODIUM HYPOPHOSPHITE MONOHYDRATE-->MANGANESE HYPOPHOSPHITE HYDRATE
Tag:Calcium hypophosphite(7789-79-9) Related Product Information
Calcium carbonate Calcium Propionate Calcium carbide Calcium chloride Calcium phosphate Calcium dobesilate Calcium gluconate Hypophosphorous acid Calcium nitrate Silicic acid, calcium salt CALCIUM Phosphoric acid, calcium salt (1:?) Calcium phosphate monobasic Calcium Calcium hypophosphite