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Tris(dibenzylideneacetone)dipalladium-chloroform adduct

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CAS:52522-40-4
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CAS:52522-40-4
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CAS:52522-40-4
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Products Intro: Product Name:Tris(dibenzylideneacetone)dipalladium-chloroform adduct
CAS:52522-40-4
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Tris(dibenzylideneacetone)dipalladium-chloroform adduct Basic information
Reaction
Product Name:Tris(dibenzylideneacetone)dipalladium-chloroform adduct
Synonyms:TRIS(DIBENZYLIDENEACETONE)(CHLOROFORM)-DI-PALLADIUM(0);TRIS(DIBENZYLIDENEACETONE)DIPALLADIUM(0) CHLOROFORM ADDUCT;TRIS(DIBENZYLIDENEACETONE)DIPALLADIUM-CHLOROFORM ADDUCT;TRIS(DIBENZYLIDENEACETONE)DIPALLADIUM CHLOROFORM COMPLEX;DIPALLADIUM(0)TRIS(DIBENZYLIDENEACETONE)-CHLOROFORM ADDUCT;DI-PALLADIUM-TRIS(DIBENZYLIDENEACETONE)CHLOROFORM COMPLEX;Dipalladiumtris(dibenzylideneacetone) chloroform adduct;TRIS(DIBENZYLIDENEACETONE)DIPALLADIUM(0) CHLOROFORM ADDUCT 98+%
CAS:52522-40-4
MF:C52H31Cl3O3Pd2
MW:1023.01
EINECS:610-856-2
Product Categories:organometallic complexes;Metal Compounds
Mol File:52522-40-4.mol
Tris(dibenzylideneacetone)dipalladium-chloroform adduct Structure
Tris(dibenzylideneacetone)dipalladium-chloroform adduct Chemical Properties
Melting point 131-135 °C(lit.)
storage temp. Keep in dark place,Sealed in dry,Room Temperature
form Crystalline Powder
color Purple to black
Water Solubility Soluble in organic solvents. Insoluble in water.
Sensitive Air & Moisture Sensitive
InChIKeyNLYJPAJWGANOKG-CXKPDERJSA-N
Safety Information
Hazard Codes Xn,Xi
Risk Statements 22-38-40-48/20/22-36/37/38
Safety Statements 36/37-37/39-26
WGK Germany 3
TSCA No
HS Code 28439000
MSDS Information
ProviderLanguage
ACROS English
SigmaAldrich English
ALFA English
Tris(dibenzylideneacetone)dipalladium-chloroform adduct Usage And Synthesis
Reaction
  1. Used for Pd-catalyzed asymmetric arylation, vinylation, and Allenylation of tert-cyclobutanols via enantioselective C−C Bond cleavage.
  2. Used for synthesis of chiral chromans through the Pd-catalyzed asymmetric allylic alkylation (AAA).
  3. Catalyst for double N-arylation of primary amines to synthesize multisubstituted carbazoles from 2,2‘biphenylylene ditriflates.
  4. Paladium catalyst for regioand enantioselective allylic alkylation of ketones through allyl enol carbonates.
  5. Used for Pd-catalyzed enantioselective C-3 allylation of 3-substituted-1H-indoles using trialkylboranes.
  6. Used for enantioselective construction of spirocyclic oxindolic cyclopentanes by Pd-catalyzed trimethylenemethane-[3+2]-cycloaddition.
  7. Used for Pd-catalyzed insertion of α-diazoesters into vinyl halides to generate α,β-unsaturated γ-amino Esters.
  8. Pd catalyst for decarboxylative asymmetric allylic alkylation of enol carbonates.
  9. Palladium catalyst for asymmetric addition of oxindoles and allenes.
  10. Catalyst for diastereoand enantioselective formal [3+2]-cycloaddition between substituted vinylcyclopropanes and electron-deficient olefins.
  11. Used for Pd-catalyzed asymmetric decarboxylative cycloaddition of vinylethylene carbonates with Michael sacceptors.
  12. Catalyst for enantioselective [6+4] cycloaddition of vinyl oxetanes with azadienes to access ten-membered heterocycles.




Chemical Propertiespurple to black crystalline powder
Usessuzuki reaction
Biological ActivityN -myristoyltransferase-1 (NMT-1) inhibitor that prevents activation of MAPK, PI 3-K and STAT3 signaling pathways. Exhibits antiproliferative activity against melanoma cells in vitro and in vivo . Also used as a cyclization catalyst.
Tris(dibenzylideneacetone)dipalladium-chloroform adduct Preparation Products And Raw materials
Raw materialsEthanol-->Sodium hydroxide-->Methanol-->Diethyl ether-->Dichloromethane-->Toluene-->Chloroform-->Acetone-->Ammonium chloride-->Acetonitrile-->Sodium acetate-->Benzaldehyde-->Palladium chloride-->tert-Butyl methyl ether
Tag:Tris(dibenzylideneacetone)dipalladium-chloroform adduct(52522-40-4) Related Product Information
Tris(dibenzylideneacetone)dipalladium Tris(dibenzylideneacetone)dipalladium TRIS(DIMETHYLAMINO)ANTIMONY TRIS(DIMETHYLAMINO)SILANE Palladium Benzylacetone Benzalacetone Chloroform Benzyl chloride Tris Base Tricine Bis(dibenzylideneacetone)palladium DIBENZYLIDENE ACETONE Tris(dibenzylideneacetone)dipalladium-chloroform adduct DIBENZYLIDENEACETONE Benzyltrimethylammonium chloride BUFFER SOLUTION PH = 6,00 (20 °C) (POTASSIUM DIHYDROGEN PHOSPHATE/SODIUM HYDROXIDE) Benzyltriethylammonium chloride