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1,2-Diaminopropane

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CAS:78-90-0
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1,2-Diaminopropane Basic information
Product Name:1,2-Diaminopropane
Synonyms:1,2-DIAMINOPROPANE;12AP;PROPYLENE-1,2-DIAMINE;1,2-Proplenediamine;1,2-Propanediamine-Propylenediamine;1,2-DIAMINOPROPANE, 99+%;Propylendiamin techn;1,2-Propylendiamin
CAS:78-90-0
MF:C3H10N2
MW:74.12
EINECS:201-155-9
Product Categories:Building Blocks;Chemical Synthesis;Nitrogen Compounds;Organic Building Blocks;Polyamines;Isotope Labelled Compounds;Aliphatics;Amines;Isotope Labeled Compounds;Intermediates of Dyes and Pigments;straight chain compounds;top;bc0001;K00001
Mol File:78-90-0.mol
1,2-Diaminopropane Structure
1,2-Diaminopropane Chemical Properties
Melting point -37 °C
Boiling point 120-122 °C(lit.)
density 0.87 g/mL at 25 °C(lit.)
vapor density 2.6 (vs air)
vapor pressure 14 mm Hg ( 20 °C)
refractive index n20/D 1.446
Fp 92 °F
storage temp. Flammables area
solubility H2O: very soluble
pka9.82(at 25℃)
form clear liquid
color Colorless to Almost colorless
PH12 (100g/l, H2O, 20℃)
explosive limit2.2-11.1%(V)
Water Solubility SOLUBLE
Sensitive Air Sensitive & Hygroscopic
Merck 14,7852
BRN 605274
Dielectric constant10.2(Ambient)
Stability:Stable. Flammable. Incompatible with strong oxidizing agents, acids, acid chlorides, acid anhydrides.
InChIKeyAOHJOMMDDJHIJH-UHFFFAOYSA-N
LogP-1.2 at 20℃
CAS DataBase Reference78-90-0(CAS DataBase Reference)
NIST Chemistry Reference1,2-Propanediamine(78-90-0)
EPA Substance Registry System1,2-Diaminopropane (78-90-0)
Safety Information
Hazard Codes C
Risk Statements 10-21/22-35-42/43
Safety Statements 26-37/39-45-36/37/39-23
RIDADR UN 2258 8/PG 2
WGK Germany 1
RTECS TX6650000
3-10-23
Autoignition Temperature680 °F
TSCA Yes
HazardClass 8
PackingGroup II
HS Code 29212900
MSDS Information
ProviderLanguage
1,2-Diaminopropane English
SigmaAldrich English
ACROS English
ALFA English
1,2-Diaminopropane Usage And Synthesis
Description1,2-Diaminopropane is a colorless liquid that is very hygroscopic and miscible with water and most organic solvents. It forms azeotropes with butanol, 2-methylpropanol, and toluene and has a strong ammoniacal odor.
Chemical Propertiesclear liquid
Uses1,2-Diaminopropane was used as model precursor in the electron induced deposition of amorphous carbon nitride films.
UsesIn conjunction with cupric sulfate it is a very sensitive reagent for mercury.
Production MethodsBecause 1,2-dichloropropane does not react smoothly with ammonia, 1,2-diaminopropane is usually prepared by aminating a mixture of 2-amino-1-propanol and 1-amino-2-propanol, which is obtained from propylene oxide and ammonia. The process differs from corresponding processes for the production of diaminoethane in that the temperature in the catalytic amination is higher (190 – 230 ℃).
Application1,2-Diaminopropane is used as an intermediate for crop-protection agents, e.g., Basfungin (BASF). Analogous to the ethylenediamine derivatives, the zinc dithiocarbamate propineb acts as a fungicide. Especially in the United States, derivatives of the amine are used as fuel and lubricant additives.
DefinitionChEBI: A diamine that is propane substituted by amino groups at positions 1 and 2. Propylenediamine is commonly used as a bidentate ligand in the formation of coordination complexes.
General DescriptionA colorless liquid with an ammonia-like odor. Flash point 160°F. Density 0.87 g / cm3. Boiling point 243°F. Strongly irritates skin and tissue.
Air & Water ReactionsVery hygroscopic. Very soluble in water.
Reactivity Profile1,2-Diaminopropane neutralizes acids in exothermic reactions to form salts plus water. May be incompatible with isocyanates, halogenated organics, peroxides, phenols (acidic), epoxides, anhydrides, and acid halides. May generate hydrogen, a flammable gas, in combination with strong reducing agents such as hydrides.
Health HazardMay cause toxic effects if inhaled or ingested/swallowed. Contact with substance may cause severe burns to skin and eyes. Fire will produce irritating, corrosive and/or toxic gases. Vapors may cause dizziness or suffocation. Runoff from fire control or dilution water may cause pollution.
Fire HazardFlammable/combustible material. May be ignited by heat, sparks or flames. Vapors may form explosive mixtures with air. Vapors may travel to source of ignition and flash back. Most vapors are heavier than air. They will spread along ground and collect in low or confined areas (sewers, basements, tanks). Vapor explosion hazard indoors, outdoors or in sewers. Runoff to sewer may create fire or explosion hazard. Containers may explode when heated. Many liquids are lighter than water.
Flammability and ExplosibilityFlammable
Safety ProfileModerately toxic by ingestion, sktn contact, and subcutaneous routes. A corrosive irritant to eyes, skin, and mucous membranes. Dangerous fire hazard when exposed to heat, flames, oxidizers. To fight fire, use alcohol foam. When heated to decomposition it emits toxic fumes of NOx. Used as an intermedate in production of petroleum and polymer additives, and surfactants. See also AMINES.
Purification MethodsPurify the diamine by azeotropic distillation with toluene. Then distil it. Store it in a CO2 free atmosphere. [Horton et al. Anal Chem 27 269 1955, Beilstein 4 IV 1255.]
Tag:1,2-Diaminopropane(78-90-0) Related Product Information
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