|
|
| | DIETHYLENE GLYCOL BIS(P-TOLUENESULFONATE) Basic information |
| Product Name: | DIETHYLENE GLYCOL BIS(P-TOLUENESULFONATE) | | Synonyms: | PEG2-Tos 2,2'-oxybis-,1,1'-bis(4-methylbenzenesulfonate);2-[2-(p-tolylsulfonyloxy)ethoxy]ethyl 4-methylbenzenesulfonate;Diethylene glycol bis(p-toluenesulfonate)≥ 99%(HPLC);BIS(2-TOSYLOXYETHYL) ETHER;BIS[2-(P-TOLUENESULFONYLOXY)ETHYL] ETHER;DI(ETHYLENE GLYCOL) DI-P-TOSYLATE;DIETHYLENE GLYCOL DITOSYLATE;DIETHYLENE GLYCOL BIS(P-TOLUENESULFONATE) | | CAS: | 7460-82-4 | | MF: | C18H22O7S2 | | MW: | 414.49 | | EINECS: | 628-596-3 | | Product Categories: | CMLLYL | | Mol File: | 7460-82-4.mol |  |
| | DIETHYLENE GLYCOL BIS(P-TOLUENESULFONATE) Chemical Properties |
| Hazard Codes | Xi | | Risk Statements | 36/37/38 | | Safety Statements | 26-36 | | WGK Germany | 3 |
| | DIETHYLENE GLYCOL BIS(P-TOLUENESULFONATE) Usage And Synthesis |
| Description | Tos-PEG3-Tos is a PEG linker containing two tosyl groups. The hydrophilic PEG spacer increases solubility in aqueous media. The tosyl group is a very good leaving group for nucleophilic substitution reactions. | | Chemical Properties | White to off-white powder | | Uses | Diethylene glycol di(p-toluenesulfonate) was used in the synthesis of bis(dibenzosulfoxo)-27,30,35,38-tetramethyl-24-crown-6, bis(dibenzosulfoxo)-21,24,29,32-tetramethyl-18-crown-4, dibenzosulfoxo-15,18-dimethyl-12-crown-3 and dibenzosulfoxo-12,15-dimethyl-9-crown-2 macrocycles. | | Purification Methods | Purify the ester by recrystallisation from Me2CO and dry it in a vacuum. [Beilstein 11 III 225.] |
| | DIETHYLENE GLYCOL BIS(P-TOLUENESULFONATE) Preparation Products And Raw materials |
|