- 4-Hydroxydiphenylamine
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- $0.00 / 25kg
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2025-07-25
- CAS:122-37-2
- Min. Order: 1kg
- Purity: 99%
- Supply Ability: 10000KGS
- 4-Hydroxydiphenylamine
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- $1.00 / 1kg
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2019-07-06
- CAS:122-37-2
- Min. Order: 1kg
- Purity: 99%
- Supply Ability: Customized
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| | 4-Hydroxydiphenylamine Basic information |
| | 4-Hydroxydiphenylamine Chemical Properties |
| Melting point | 67-73°C | | Boiling point | 190°C | | density | 1.0936 (rough estimate) | | refractive index | 1.5300 (estimate) | | Fp | 209°C | | storage temp. | Keep in dark place,Inert atmosphere,Room temperature | | solubility | Ethanol: Soluble: =10 mg/mlPBS (pH 7.2): Soluble: =10 mg/ml | | form | powder to lump | | pka | 10.46±0.13(Predicted) | | color | Gray, solid leaflets | | BRN | 511942 | | InChI | InChI=1S/C12H11NO/c14-12-8-6-11(7-9-12)13-10-4-2-1-3-5-10/h1-9,13-14H | | InChIKey | JTTMYKSFKOOQLP-UHFFFAOYSA-N | | SMILES | C1(O)=CC=C(NC2=CC=CC=C2)C=C1 | | CAS DataBase Reference | 122-37-2(CAS DataBase Reference) | | NIST Chemistry Reference | Phenol, 4-(phenylamino)-(122-37-2) | | EPA Substance Registry System | Phenol, 4-(phenylamino)- (122-37-2) |
| Hazard Codes | Xn | | Risk Statements | 37/38-41-22-21 | | Safety Statements | 26-36/37/39-36/39 | | RIDADR | UN2811 | | RTECS | SJ6950000 | | TSCA | Yes | | HazardClass | 6.1 | | PackingGroup | III | | HS Code | 29222990 | | Toxicity | LD50 oral in rat: 3300mg/kg |
| Provider | Language |
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ALFA
| English |
| | 4-Hydroxydiphenylamine Usage And Synthesis |
| Uses | 4-Hydroxydiphenylamine is used as a reactant in the preparation of iron methylisopropylglyoxime dimethylpyridine/dimethylaminopyridine/phenylaminophenol/imidazolidone complexes. | | Definition | Gray solid leaflets. Insoluble in water; soluble
in alcohol, ether, acetone, chloroform, alkali, and
benzene. | | Hazard | Irritant. | | Safety Profile | Poison by intravenous route.Moderately toxic by ingestion. A severe eye irritant. Seealso AROMATIC AMINES. When heated todecomposition it emits toxic fumes of NOx. | | Purification Methods | Crystallise the amine from chlorobenzene/pet ether, pentane (m 72o) or *C6H6/pet ether (m 70o). [Beilstein 13 III 1019, 13 IV 1052.] | | References | [1] HAOQI NINA ZHAO, EDWARD P. KOLODZIEJ* Transformation Products of Tire Rubber Antioxidant 6PPD in Heterogeneous Gas-Phase Ozonation: Identification and Environmental Occurrence[J]. 环境科学与技术, 2023, 57 14: 5621-5632. DOI: 10.1021/acs.est.2c08690
[2] NICO GRASSE, THORSTEN REEMTSMA* Uptake and Biotransformation of the Tire Rubber-derived Contaminants 6-PPD and 6-PPD Quinone in the Zebrafish Embryo (Danio rerio)[J]. 环境科学与技术, 2023, 57 41: 15598-15607. DOI: 10.1021/acs.est.3c02819
[3] W E ALEXANDER S E W A J Ryan. Metabolism of diphenylamine in the rat, rabbit and man.[J]. Food and cosmetics toxicology, 1965, 3 4: 571-579. DOI: 10.1016/s0015-6264(65)80203-6
[4] De Souza, F.I., Zumiotti, A.V., and Da Silva, C.F. Neuregulins 1-α and 1-β on the regeneration the peripheral nerves[J]. Acta Ortop Bras. |
| | 4-Hydroxydiphenylamine Preparation Products And Raw materials |
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