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ChemicalBook > Product Catalog >Organic Chemistry >Organometallic compounds >Organic rhodium >(-)-1,2-BIS((2S,5S)-2,5-DIMETHYLPHOSPHOLANO)ETHANE(CYCLOOCTADIENE)RHODIUM (I) TETRAFLUOROBORATE

(-)-1,2-BIS((2S,5S)-2,5-DIMETHYLPHOSPHOLANO)ETHANE(CYCLOOCTADIENE)RHODIUM (I) TETRAFLUOROBORATE

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(-)-1,2-BIS((2S,5S)-2,5-DIMETHYLPHOSPHOLANO)ETHANE(CYCLOOCTADIENE)RHODIUM (I) TETRAFLUOROBORATE Suppliers list
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Products Intro: Product Name:(?à)-Methyl 2-benzyloxycarbonylamino-2-(dimethoxyphosphinyl)acetat
CAS:213343-65-8
Purity:97%min HPLC Package:100g;1kg;5kg,10kg,25kg,50kg
Company Name: Hubei xin bonus chemical co. LTD
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Products Intro: Product Name:(-)-1,2-BIS((2S,5S)-2,5-DIMETHYLPHOSPHOLANO)ETHANE(CYCLOOCTADIENE)RHODIUM (I) TETRAFLUOROBORATE
CAS:213343-65-8
Purity:0.99 Package:5KG;1KG
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Products Intro: CAS:213343-65-8
Purity:97%+ Package:5g;25g;100g;500g;1kg;25kg
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Products Intro: Product Name:(+)-1,2-Bis[(2S,5S)-2,5-diMethylphospholano]ethane(1,5-cyclooctadiene)rhodiuM(I)tetrafluoroborate,97%
CAS:213343-65-8
Purity:99.00% Package:25kgs/Drum;200kgs/Drum Remarks:ISO 9001：2015 REACH Approved Manufacturer
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Products Intro: Product Name:(-)-1,2-Bis((2S,5S)-2,5-dimethylphospholano)ethane(1,5-cyclooctadiene)rhodium(I) tetrafluoroborate, 98+% (S,S)-Me-BPE-Rh
CAS:213343-65-8
Remarks:https://www.alfachemic.com/catalysts/product/1-2-bis-2s-5s-2-5-dimethylphospholano-ethane-cas-213343-65-8-100946.html
(-)-1,2-BIS((2S,5S)-2,5-DIMETHYLPHOSPHOLANO)ETHANE(CYCLOOCTADIENE)RHODIUM (I) TETRAFLUOROBORATE Basic information
Reaction
Product Name:(-)-1,2-BIS((2S,5S)-2,5-DIMETHYLPHOSPHOLANO)ETHANE(CYCLOOCTADIENE)RHODIUM (I) TETRAFLUOROBORATE
Synonyms:(+)-1,2-Bis[(2S,5S)-2,5-diMethylphospholano]ethane(1,5-cyclooctadiene)rhodiuM(I) tetrafluoroborate, 97%;(-)-1,2-Bis((2S,5S)-2,5-diMethylphospholano)ethane(1,5-cyclooctadiene)rhodiuM(I) tetrafluoroborate (S,S)-Me-BPE-Rh;(à)-Methyl 2-benzyloxycarbonylamino-2-(dimethoxyphosphinyl)acetat;(-)-1,2-BIS((2S,5S)-2,5-DIMETHYLPHOSPHOLANO)ETHANE(CYCLOOCTADIENE)RHODIUM (I) TETRAFLUOROBORATE;(-)-1,2-Bis((2S,5S)-2,5-dimethylphospholano)ethane(cyclooctadiene)rhodium(I)tetrafluoroborate,98+%(S,S)-Me-BPE-Rh;(S,S)-ME-BPE-RH;(-)-1,2-Bis((2S,5S)-2,5-dimethylphospholano)ethane(1,5-cyclooctadiene)rhodium(I) tetrafluoroborate, 98+% (S,S)-Me-BPE-Rh;(-)-1,2-BIS((2S,5S)-2,5-DIMETHYLPHOSPHOLANO)ETHANE(1,5-CYCLOOCTADIENE)RHODIUM(I)TETRAFLUOROBORATE,98+%(S,S)-ME-BPE-RH
CAS:213343-65-8
MF:C22H40BF4P2Rh-
MW:556.21
EINECS:
Product Categories:Privileged Ligands and Complexes;organometallic complex;Chiral Catalysts, Ligands, and Reagents;DuPhos/BPE
Mol File:213343-65-8.mol
(-)-1,2-BIS((2S,5S)-2,5-DIMETHYLPHOSPHOLANO)ETHANE(CYCLOOCTADIENE)RHODIUM (I) TETRAFLUOROBORATE Structure
(-)-1,2-BIS((2S,5S)-2,5-DIMETHYLPHOSPHOLANO)ETHANE(CYCLOOCTADIENE)RHODIUM (I) TETRAFLUOROBORATE Chemical Properties
Melting point 152.2-156.3 °C
form Crystalline Powder
color Orange to red to brown
Sensitive air sensitive
Safety Information
Hazard Codes Xi
Risk Statements 36/37/38
Safety Statements 22-24/25-26
WGK Germany 3
MSDS Information
(-)-1,2-BIS((2S,5S)-2,5-DIMETHYLPHOSPHOLANO)ETHANE(CYCLOOCTADIENE)RHODIUM (I) TETRAFLUOROBORATE Usage And Synthesis
ReactionThe DUPHOS family of catalysts is highly efficient for the asymmetric hydrogenation of various substituted acetamidoacrylates and enol acetates yielding products of high enantiomeric excesses. Efficient ligand for the asymmetric hydrogenation of tetrasubstituted enamides. Reactions of 213343-65-8
UsesDuPhos and BPE Ligands: Highly Efficient Privileged Ligands

Catalyst for:
  • Asymmetric hydrogenation
(-)-1,2-BIS((2S,5S)-2,5-DIMETHYLPHOSPHOLANO)ETHANE(CYCLOOCTADIENE)RHODIUM (I) TETRAFLUOROBORATE Preparation Products And Raw materials
Tag:(-)-1,2-BIS((2S,5S)-2,5-DIMETHYLPHOSPHOLANO)ETHANE(CYCLOOCTADIENE)RHODIUM (I) TETRAFLUOROBORATE(213343-65-8) Related Product Information
1,3-CYCLOOCTADIENE (+)-1,2-BIS((2R,5R)-2,5-DIMETHYLPHOSPHOLANO)ETHANE(CYCLOOCTADIENE)RHODIUM (I) TETRAFLUOROBORATE (-)-1,2-BIS((2R,5R)-2,5-DIPHENYLPHOSPHOLANO)ETHANE(1,5-CYCLOOCTADIENE)RHODIUM (I) TETRAFLUOROBORATE (-)-1,2-BIS((2S,5S)-2,5-DIMETHYLPHOSPHOLANO)ETHANE(CYCLOOCTADIENE)RHODIUM (I) TETRAFLUOROBORATE (-)-1,2-BIS((2S,5S)-2,5-DIMETHYLPHOSPHOLANO)ETHANE 1,2-BIS(DIETHYLPHOSPHINO)ETHANE