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| | TRIPHENYL TRITHIOORTHOFORMATE Basic information |
| | TRIPHENYL TRITHIOORTHOFORMATE Chemical Properties |
| Melting point | 39-41 °C (lit.) | | Boiling point | 488.1±25.0 °C(Predicted) | | density | 1.26±0.1 g/cm3(Predicted) | | Fp | >230 °F | | form | powder to crystal | | pka | 23(at 25℃) | | color | White to Almost white | | BRN | 1914230 | | InChI | InChI=1S/C19H16S3/c1-4-10-16(11-5-1)20-19(21-17-12-6-2-7-13-17)22-18-14-8-3-9-15-18/h1-15,19H | | InChIKey | YOQHDHPBEXTHCP-UHFFFAOYSA-N | | SMILES | C(SC1=CC=CC=C1)(SC1=CC=CC=C1)SC1=CC=CC=C1 |
| Hazard Codes | Xi | | Risk Statements | 36/37/38 | | Safety Statements | 26-37/39 | | RIDADR | UN 3335 | | WGK Germany | 3 | | F | 13 | | HS Code | 29309090 |
| | TRIPHENYL TRITHIOORTHOFORMATE Usage And Synthesis |
| Uses | Tris(phenylthio)methane has been used in the preparation of:
- 1-phenylthio-tetrahydroisoquinolines via activated Pictet-Spengler cyclization
- homoallylchalcogenoacetals via reaction with allylsilanes in the presence of a Lewis acid
| | Uses | A precursor to tris(phenylthio)methyllithium, used for nucleophilic carboxylation; electrophilic formylating agent for aromatic compounds and diazo esters. | | storage | Tris(phenylthio)Methane ?is stable indefinitely if stored at ambient temperatures in tightly sealed containers to exclude moisture, which promotes hydrolysis to thiophenol and formic acid. |
| | TRIPHENYL TRITHIOORTHOFORMATE Preparation Products And Raw materials |
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