- Methyl nitroacetate
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- $0.00 / 1kg
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2022-09-23
- CAS:2483-57-0
- Min. Order: 1kg
- Purity: 98%
- Supply Ability: 1Ton
- Methyl nitroacetate
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- $1.00 / 1kg
-
2019-07-06
- CAS:2483-57-0
- Min. Order: 1kg
- Purity: 95%-99%
- Supply Ability: as request
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| Methyl nitroacetate Basic information |
| Methyl nitroacetate Chemical Properties |
Boiling point | 195-198 °C (lit.) | density | 1.294 g/mL at 25 °C (lit.) | refractive index | n20/D 1.425(lit.) | Fp | 221 °F | storage temp. | Keep in dark place,Sealed in dry,Room Temperature | solubility | Miscible with ethanol, ether and most organic solvents. | pka | 5.73±0.29(Predicted) | form | clear liquid | color | Colorless to Light yellow | Sensitive | Light Sensitive | BRN | 1758670 | InChI | InChI=1S/C3H5NO4/c1-8-3(5)2-4(6)7/h2H2,1H3 | InChIKey | ALBSWLMUHHZLLR-UHFFFAOYSA-N | SMILES | C(OC)(=O)C[N+]([O-])=O | CAS DataBase Reference | 2483-57-0(CAS DataBase Reference) | NIST Chemistry Reference | Acetic acid, nitro-, methyl ester(2483-57-0) |
Hazard Codes | Xi | Risk Statements | 36/37/38 | Safety Statements | 26-36-37/39 | WGK Germany | 2 | RTECS | AJ1093000 | F | 8 | HS Code | 29161995 |
| Methyl nitroacetate Usage And Synthesis |
Chemical Properties | clear yellow liquid | Uses | Methyl nitroacetate is used in the synthesis of aromatic and heteroaromatic linear (E)-alfa-nitro-arylpentenoates. It is also used to prepare phenyliodonium ylide. Further, it is utilized in the highly enantioselective and diastereoselective copper(I)-catalyzed cyclopropanation of alkenes. In addition to this, it is employed in the production of methyl (Z)-2-nitro-3-(4-nitrophenyl)-2-propenoate through reaction with 4-nitrobenzylideneaniline. | Synthesis Reference(s) | The Journal of Organic Chemistry, 25, p. 266, 1960 DOI: 10.1021/jo01072a606 |
| Methyl nitroacetate Preparation Products And Raw materials |
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