L-樟脑酸
| 中文名称 | L-樟脑酸 |
|---|---|
| 中文同义词 | (1S,3R)-(-)-樟脑酸;(1S,3R)-1,2,2-三甲基-1,3-环戊烷二羧酸;(1S,3R)-(-)-樟脑酸;(-)-樟脑酸;L-樟脑酸;(1S,3R)-(-)-CAMPHORIC ACID (1S,3R)-(-)-樟脑酸;L-樟脑酸(CAS号:560-09-8);(1S,3R)-1,2,2-三甲基环戊烷-1,3-二羧酸 |
| 英文名称 | (1S,3R)-1,2,2-Trimethyl-1,3-cyclopentanedicarboxylic acid |
| 英文同义词 | (-)-Camphoric acid, (1S,3R)-1,2,2-Trimethyl-1,3-cyclopentanedicarboxylic acid;(1S)-1,2,2-Trimethylcyclopentane-1α,3α-dicarboxylic acid;(1S,3R)-1,2,2-Trimethylcyclopentane-1,3-dicarboxylic acid;[1S,(-)]-1,2,2-Trimethyl-1α,3α-cyclopentanedicarboxylic acid;1,2,2-Trimethylcyclopentane-1α,3α-dicarboxylic acid;(-)-CAMPHORIC ACID, UNNATURAL FORM;Acid, L-caMphor;(1S,3R)-(-)-CaMphoric acid 99% |
| CAS号 | 560-09-8 |
| 分子式 | C10H16O4 |
| 分子量 | 200.23 |
| EINECS号 | 200-258-5 |
| 相关类别 | 手性砌块;羰基化合物;Chiral Reagents;Miscellaneous Reagents;Chiral Compound |
| Mol文件 | 560-09-8.mol |
| 结构式 |  |
L-樟脑酸 性质
| 熔点 | 188-190 °C(lit.) |
|---|---|
| 沸点 | 312.0±25.0 °C(Predicted) |
| 密度 | 1.177±0.06 g/cm3(Predicted) |
| 储存条件 | Sealed in dry,Room Temperature |
| 溶解度 | 可溶于DMSO、乙醇、甲醇 |
| 形态 | 固体 |
| 酸度系数(pKa) | 4.57±0.60(Predicted) |
| 颜色 | 白色至类白色 |
| 旋光度 (Optical Rotation) | [α]20/D 48°, c = 10 in ethanol |
| BRN | 1874674 |
| InChI | 1S/C10H16O4/c1-9(2)6(7(11)12)4-5-10(9,3)8(13)14/h6H,4-5H2,1-3H3,(H,11,12)(H,13,14)/t6-,10+/m0/s1 |
| InChIKey | LSPHULWDVZXLIL-QUBYGPBYSA-N |
| SMILES | CC1(C)[C@@H](CC[C@]1(C)C(O)=O)C(O)=O |
| CAS 数据库 | 560-09-8(CAS DataBase Reference) |
可作为配体用于合成MOF材料：[{Zn2((+)cam)2(dabco)}n]
[2] Enantiopure Metal–Organic Framework Thin Films: Oriented SURMOF Growth and Enantioselective Adsorption. https://doi.org/10.1002/anie.201104240
[3] A Tale of Three Carboxylates: Cooperative Asymmetric Crystallization of a Three‐Dimensional Microporous Framework from Achiral Precursors. https://doi.org/10.1002/anie.200906248
参考文献
[1] Integrated Molecular Chirality, Absolute Helicity, and Intrinsic Chiral Topology in Three-Dimensional Open-Framework Materials. https://doi.org/10.1021/ja8075692
[2] Enantiopure Metal–Organic Framework Thin Films: Oriented SURMOF Growth and Enantioselective Adsorption. https://doi.org/10.1002/anie.201104240
[3] A Tale of Three Carboxylates: Cooperative Asymmetric Crystallization of a Three‐Dimensional Microporous Framework from Achiral Precursors. https://doi.org/10.1002/anie.200906248
安全信息
| 安全说明 | 22-24/25 |
|---|---|
| WGK Germany | 3 |
| 海关编码 | 29172090 |
| 存储类别 | 11 - 可燃固体 |
| 提供商 | 语言 |
|---|---|
|
英文
|