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Yttrium oxide

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CAS:1314-36-9
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  • Yttrium oxide
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  • 2024-04-24
  • CAS:1314-36-9
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  • Yttrium oxide
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  • 2023-12-25
  • CAS:1314-36-9
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Yttrium oxide Basic information
Physical Properties Uses Preparation
Product Name:Yttrium oxide
Synonyms:YTTRIUMOXIDE,POWDER;Yttriumoxid;Yttrium(III) oxide, REacton(R), 99.9999% (REO);Yttrium(III) oxide, REacton(R), 99.999% (REO);Yttrium(III) oxide sputtering target, 50.8mm (2.0in) dia x 3.18mm (0.125in) thick, 99.99% (metals basis);Y2O3 A YTTRIUMOXIDE GRADE A - A PRODUCT OF H.C. STARCK;YTTRIUM OXIDE: 99.9995%;Y2O3 B YTTRIUMOXIDE GRADE B - A PRODUCT OF H.C. STARCK
CAS:1314-36-9
MF:O3Y2
MW:225.81
EINECS:215-233-5
Product Categories:Alternative Energy;ElectrolytesMetal and Ceramic Science;Materials Science;Oxides;Yttrium;39: Y;YttriumNanomaterials;Nanomaterials;Nanoparticles: Oxides, Nitrides, and Other CeramicsMetal and Ceramic Science;Nanopowders and Nanoparticle Dispersions;metal oxide;Inorganics;Inorganic Chemicals
Mol File:1314-36-9.mol
Yttrium oxide Structure
Yttrium oxide Chemical Properties
Melting point 2410 °C
Boiling point 81-83 °C
density 5.01 g/mL at 25 °C(lit.)
Fp 12 °C
storage temp. no restrictions.
solubility soluble in dilute acid solutions
form nanopowder
Specific Gravity5.01
color White
PH10±1
Water Solubility Insoluble
Sensitive Air Sensitive
Crystal StructureTrigonal
Merck 14,10107
Exposure limitsACGIH: TWA 1 mg/m3
NIOSH: IDLH 500 mg/m3; TWA 1 mg/m3
InChIKeySIWVEOZUMHYXCS-UHFFFAOYSA-N
CAS DataBase Reference1314-36-9(CAS DataBase Reference)
EPA Substance Registry SystemYttrium oxide (Y2O3) (1314-36-9)
Safety Information
Hazard Codes Xi,F
Risk Statements 36/37/38-67-36/37-36-11
Safety Statements 26-36-37/39-16
RIDADR UN1950
WGK Germany 1
RTECS ZG3850000
3-9
TSCA Yes
HazardClass 2.1
HS Code 28469011
Toxicitymouse,LD50,intraperitoneal,430mg/kg (430mg/kg),"Toxicometric Parameters of Industrial Toxic Chemicals Under Single Exposure," Izmerov, N.F., et al., Moscow, Centre of International Projects, GKNT, 1982Vol. -, Pg. 121, 1982.
MSDS Information
ProviderLanguage
ACROS English
SigmaAldrich English
ALFA English
Yttrium oxide Usage And Synthesis
Physical PropertiesWhite powder; body-centered cubic structure; density 5.03 g/cm3; melts at 2,436°C; insoluble in water; soluble in dilute acids.
Yttrium oxide.jpg
UsesYttrium Oxide, also called Yttria, high purity Yttrium Oxides are the most important materials for tri-bands Rare Earth phosphors which give the red colour in colour television & computer tubes. In optical industry, the Yttrium Oxide is used to produce Yttrium-Iron-Garnets, which are very effective microwave filters. Low purity of Yttrium Oxide are widely applied in electronic ceramics. It is widely used to make Eu:YVO4 and Eu:Y2O3 phosphors that give the red color in color TV picture tubes.
Also, it is used in gas mantles and acetylene lights. Other uses are in yttriumiron garnets for microwave filters in lasers, and as a stabilizer for high temperature in refractories.
PreparationYttrium oxide is produced as an intermediate in recovery of yttrium from xenotime and monazite (See Yttrium, Recovery). The oxide is produced after separation of rare earth sulfates obtained from digesting the mineral with sulfuric acid on a cation exchange bed, precipitating yttrium fraction as oxalate, and igniting the oxalate at 750°C.
Yttrium oxide also may be obtained by thermal decomposition of yttrium nitrate.
Chemical Propertieswhite powder(s) or sintered tablets and pieces of 99.9% purity; bcc; readily absorbs atmospheric CO2; enthalpy of fusion 105.00 kJ/mol; used in crucible form for experimental, proprietary melting, also sintered pieces used as evaporation material for hard film dielectric coating and thin film capacitors, and as 99.999%, 99.99%, 99.9% pure sputtering target for preparing hard films, dielectric coatings, and thin film capacitor [CER91] [MER06] [CRC10]
Physical propertiesYttrium oxide is a medium-refractiveindex, low-absorption material used for optical coating in the near-UV (300 nm) to IR (12 μm) regions and hence used to protect Al and Ag mirrors. Used for crucibles containing molten lithium.
UsesYttrium oxide is an excellent mineralizing agent for spinel formation. Yttrium oxide is used as a common starting material for both materials science as well as inorganic compounds. Provides easy application of uniform, thin, protective high temperature Yttrium Oxide coatings. Yttrium Oxide is used to produce Yttrium-Iron-Garnets, which are very effective microwave filters. Low purity of Yttrium Oxide are widely applied in electronic ceramics. Yttrium Oxide is also used to make Yttrium-Iron-Garnets, which are very effective microwave filters.
UsesYttrium oxide was used in the preparation of pervoskite type structure, YAlO3, containing chrome ions.1 The effect of yttrium oxide dopant on the phase formation and sintering characteristics was studied. It may be used in the manufacturing of neodymium Nd:YAG lasers and in components of MOS and LED transistors.
Uses
IndustryApplicationRole/benefit
Gas lightingManufacture of gas mantlesEffective component/has extremely high temperature stability
Inorganic synthesisManufacture of Yttrium compoundsRaw material/source of Yttrium
ceramicManufacture of pure ceramicRaw material or additive/has extremely high temperature stability and outstanding resistance to alkaline melts
Manufacture of other ceramicmaterial (Si3N4,AIN,ZrO2, etc.)
Multilayer ceramic capacitors
Display materialsColor TV picture tubesAdditive material/used as raw material to make Eu:YVo4 and Eu:Y2O3 phosphors that give the red color
Field-emission displays
Plasma display panels
Flat-panel displays
cathode ray tube screens
lnsulatorlnsulator coatingEffective component/extremely thermodynamically stable and resistant to many reactive molten metals
Laminated insulator
Nuclear technologyCoating material for graphite in nuclear technologyMain component/extremely thermodynamically stable
Diluting uranium oxide for nuclear fuel rodsDiluting agent/ Yttrium oxide can form a solid solution with uranium oxide
RefractoryCoating material for high-temperature applicationsMain component/extremely thermodynamically stable
OthersManufacture of steel, non-ferrous alloys and ironAdditive/extremely thermodynamically stable
Manufacture of IR and UV translucent glass
Manufacture of high-temperature superconductors
Preparation of permanent magnetsAdditive
Prospective solid-state laser materialDopant / lasers with ytterbium allow the efficient operation both in continuous operation and in pulsed regimes
Making Yttrium iron garnets for powerful microwave filtersRaw material/source of Yttrium
Ultrafast sensors used in g-ray and x-raysAdditive
Paints and plasticsAdditive/decreases UV degradation
General DescriptionYttrium oxide is an excellent mineralizing agent for spinel formation. It has a high melting point(2450oC), chemical stability, low coefficient of thermal expansion, high transparency for both visible (70%) and infrared (60%) light, low cut off energy of photons.
Flammability and ExplosibilityNon flammable
Safety ProfileA poison by intraperitoneal route. See also YTTRIUM and RARE EARTHS.
Yttrium oxide Preparation Products And Raw materials
Raw materialsMISCH METAL-->Rare earth micronutrients-->fergusonite
Preparation ProductsALUMINUM ZIRCONATE-->YTTRIUM FLUORIDE
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