ChemicalBook > Product Catalog >Chemical Reagents >Organic reagents >Borane >(S)-3,3-Diphenyl-1-methylpyrrolidino[1,2-c]-1,3,2-oxazaborole

(S)-3,3-Diphenyl-1-methylpyrrolidino[1,2-c]-1,3,2-oxazaborol

(S)-3,3-Diphenyl-1-methylpyrrolidino[1,2-c]-1,3,2-oxazaborole Suppliers list
Company Name: Capot Chemical Co.,Ltd.
Tel: +86 (0)571-855 867 18
Email: sales@capotchem.com
Products Intro: Product Name:(S)-2-Methyl-CBS-oxazaborolidine
CAS:112022-81-8
Purity:98%(Min,HPLC) Package:100g;1kg;5kg,10kg,25kg,50kg
Company Name: Henan DaKen Chemical CO.,LTD.
Tel: +86-371-55531817
Email: inquiry@dakenchem.com
Products Intro: Product Name:(S)-3,3-Diphenyl-1-methylpyrrolidino[1,2-c]-1,3,2-oxazaborole
CAS:112022-81-8
Purity:99% Package:100g,500g,1kg,5kg,10kg
Company Name: Henan Tianfu Chemical Co.,Ltd.
Tel: 0371-55170693
Email: info@tianfuchem.com
Products Intro: CAS:112022-81-8
Purity:99% Package:500G;1KG;5KG;25KG
Company Name: Mainchem Co., Ltd.
Tel: +86-0592-6210733
Email: sales@mainchem.com
Products Intro: Product Name:(S)-3,3-Diphenyl-1-methylpyrrolidino[1,2-c]-1,3,2-oxazaborole
CAS:112022-81-8
Company Name: Nanjing ChemLin Chemical Industry Co., Ltd.
Tel: 025-83697070;product@chemlin.com.cn
Email: product@chemlin.com.cn
Products Intro: CAS:112022-81-8
Purity:1M THF Package:g-Kg Remarks:Colorless to pale yellow liquid

Lastest Price from (S)-3,3-Diphenyl-1-methylpyrrolidino[1,2-c]-1,3,2-oxazaborole manufacturers

(S)-3,3-Diphenyl-1-methylpyrrolidino[1,2-c]-1,3,2-oxazaborole Basic information
Reaction
Product Name:(S)-3,3-Diphenyl-1-methylpyrrolidino[1,2-c]-1,3,2-oxazaborole
Synonyms:(S)-1-METHYL-3,3-DIPHENYL-TETRAHYDRO-PYRROLO[1,2C][1,3,2]OXAZABOROLE;(S)-5,5-DIPHENYL-2-METHYL-3,4-PROPANO-1,3,2-OXAZABOROLIDINE;(S)-(-)-2-METHYL-CBS-OXAZABOROLIDINE;(S)-2-METHYL-CBS-OXAZABOROLIDINE;(S)-2-METHYL-CBS-OXAZABOROLIDINE MONOHYDRATE;(S)-3,3-Diphenyl-1-methylpyrrolidino[1,2-c]-1,3,2-oxazaborole;(S)-3,3-DIPHENYL-1-METHYLTETRAHYDRO-1H,3H-PYRROLO[1,2-C][1,3,2]OXAZABOROLE;(S)-3,3-DIPHENYL-1-METHYLTETRAHYDRO-3H-PYRROLO-[1,2-C][1,3,2]OXAZABOROLE
CAS:112022-81-8
MF:C18H20BNO
MW:277.17
EINECS:-0
Product Categories:API intermediates;Asymmetric Synthesis;B (Classes of Boron Compounds);B-Bromocatecholborane, etc.;Synthetic Organic Chemistry;Asymmetric Synthesis;Chiral Catalysts, Ligands, and Reagents;Reduction;organic or inorganic borate
Mol File:112022-81-8.mol
(S)-3,3-Diphenyl-1-methylpyrrolidino[1,2-c]-1,3,2-oxazaborole Structure
(S)-3,3-Diphenyl-1-methylpyrrolidino[1,2-c]-1,3,2-oxazaborole Chemical Properties
Melting point 115-117°C
Boiling point 111 °C
density 0.93 g/mL at 20 °C(lit.)
refractive index -68 ° (C=1, MeOH)
Fp 40 °F
storage temp. Refrigerator
form Liquid
color Colorless to amber
Water Solubility Hydrolyzes in water.
Sensitive Air & Moisture Sensitive
BRN 8492123
InChIKeyVMKAFJQFKBASMU-KRWDZBQOSA-N
CAS DataBase Reference112022-81-8(CAS DataBase Reference)
Safety Information
Hazard Codes Xi,Xn,F
Risk Statements 36/37/38-67-65-63-48/20-11-19-40
Safety Statements 26-62-36/37-33-29-16
RIDADR UN 1294 3/PG 2
WGK Germany 3
10-21
HazardClass 3
PackingGroup II
MSDS Information
(S)-3,3-Diphenyl-1-methylpyrrolidino[1,2-c]-1,3,2-oxazaborole Usage And Synthesis
Reaction
  1. Convenient catalyst for the enantioselective borane reduction of ketones at ambient temperatures.
  2. Asymmetric synthesis of α-chiral hydroxyalkylphosphines via a catalytic, enantioselective reduction of acylphosphines.
  3. Nickel-catalyzed cross-couplings of benzylic pivalates with arylboroxines: Stereospecific formation of diarylalkanes and triarylmethanes.
  4. Enantioselective reduction of prochiral ketones with NaBH4/Me2SO4/(S)-Me-CBS.
Chemical PropertiesColorless to yellow liquid
Usessuzuki reaction
(S)-3,3-Diphenyl-1-methylpyrrolidino[1,2-c]-1,3,2-oxazaborole Preparation Products And Raw materials
Raw materialsTetrahydrofuran-->Dichloromethane-->Thionyl chloride-->2-Pyrrolidinecarboxylic acid-->PHENYLMAGNESIUM BROMIDE-->Trimethylboroxine
Tag:(S)-3,3-Diphenyl-1-methylpyrrolidino[1,2-c]-1,3,2-oxazaborole(112022-81-8) Related Product Information
(S)-(−)-α,α-Diphenyl-2-pyrrolidinemethanol L-(+)-Prolinol Methylboronic acid (R)-3,3-Diphenyl-1-methylpyrrolidino[1,2-c]-1,3,2-oxazaborole (R)-Tetrahydro-1,3,3-triphenyl-1H,3H-pyrrolo[1,2-c][1,3,2]oxaborole, 99% (R)-Phenyl oxazaborolidine (S)-O-TOLYL-CBS-OXAZABOROLIDINE, 0.5M I& (S)-Tetrahydro-1,3,3-triphenyl-1H,3H-pyrrolo[1,2-c][1,3,2]oxaborole, 99% (S)-Phenyl oxazaborolidine (S)-CBS-BORANE COMPLEX (S)-3,3-Diphenyl-1-methylpyrrolidino[1,2-c]-1,3,2-oxazaborole (R)-O-TOLYL-CBS-OXAZABOROLIDINE, 0.5M I&