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Methyl propiolate

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CAS:922-67-8
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Products Intro: Product Name:Propynoic acid methyl ester
CAS:922-67-8
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CAS:922-67-8
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Methyl propiolate manufacturers

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  • 2023-09-06
  • CAS:922-67-8
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Related articles

  • Applications of Methyl propiolate
  • Methyl propiolate(MP) is an organic compound with the formula HC2CO2CH3. It is the methyl ester of propiolic acid, the simples....
  • Nov 15,2019
Methyl propiolate Basic information
Product Name:Methyl propiolate
Synonyms:METHYL PROPIOLATE;METHYL PROPYNOATE;METHYL ACETYLENECARBOXYLATE;PROPARGYLIC ACID METHYL ESTER;PROPIOLIC ACID METHYL ESTER;Acetylenecarboxylic acid methyl ester;acetylenecarboxylicacidmethylester;HCequivCCOOCH3
CAS:922-67-8
MF:C4H4O2
MW:84.07
EINECS:213-083-5
Product Categories:Pyridines;pharmaceutical raw material;Miscellaneous;Aliphatics;Esters;Acetylenes;Acetylenic Carboxylic Acids & Their Derivatives;bc0001
Mol File:922-67-8.mol
Methyl propiolate Structure
Methyl propiolate Chemical Properties
Melting point 171-173 °C
Boiling point 103-105 °C (lit.)
density 0.945 g/mL at 25 °C (lit.)
refractive index n20/D 1.408(lit.)
Fp 50 °F
storage temp. Inert atmosphere,2-8°C
solubility Chloroform (Sparingly), Methanol (Sparingly)
form Liquid
Specific Gravity0.9450
color Clear colorless
Water Solubility Not miscible in water.
BRN 605462
Stability:Stable. Highly flammable. Incompatible with strong oxidizing agents, bases, acids.
InChIKeyIMAKHNTVDGLIRY-UHFFFAOYSA-N
CAS DataBase Reference922-67-8(CAS DataBase Reference)
NIST Chemistry Reference2-Propynoic acid, methyl ester(922-67-8)
Safety Information
Hazard Codes F,Xi
Risk Statements 11-36/37/38-36
Safety Statements 26-36-36/37/39-23-16-33-7/9
RIDADR UN 3272 3/PG 2
WGK Germany 3
RTECS UE0050000
19
Hazard Note Highly Flammable/Harmful
HazardClass 3
PackingGroup II
HS Code 29161980
MSDS Information
ProviderLanguage
2-Propynoic acid methyl ester English
SigmaAldrich English
ACROS English
ALFA English
Methyl propiolate Usage And Synthesis
Chemical Propertiescolourless to light yellow liquid
UsesMethyl propiolate was used in the synthesis of polysubstituted 3-arylaminoacrylate and tetrahydropyrimidin-2-one derivatives. It was also used as a thiol derivatizing agent for capillary electrophoresis.
Purification MethodsPurify the propiolate by fractional distillation and collecting the middle fraction, note that propiolic acid has a high b [144o(dec)/760mm]. [Beilstein 2 IV 1688.] LACHRYMATORY.
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