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| | [1,1'-Bis(diphenylphosphino)ferrocene]dichloropalladium(II) Basic information | | Uses |
| Product Name: | [1,1'-Bis(diphenylphosphino)ferrocene]dichloropalladium(II) | | Synonyms: | 1,1'-BIS(DIPHENYLPHOSPHINO)FERROCENEDICHLOROPALLADIUM(II);1,1'-BIS(DIPHENYLPHOSPHINO)FERROCENE PALLADIUM DICHLORIDE;1,1'-BIS(DIPHENYLPHOSPHINO)FERROCENEPALLADIUM(II) DICHLORIDE;Dichloro(1,1'-bis(diphenylphosphino)ferrocene)palladium (II) dichloromethane add;1,1'-Bis(diphenylphosphino)ferroceneüpalladium(II) chloride, 1:1 complex with dichloromethane;[bis(diphenylphosphino)ferrocene]PdCl2/ dichloromethane;1,1'-Bis(diphenylphosphino)ferrocene palladium dichloride ,99%;[1,1'-Bis(diphenylphosphino)ferrocene]dichloropall | | CAS: | 72287-26-4 | | MF: | C34H28Cl2FeP2Pd | | MW: | 731.7 | | EINECS: | 460-040-3 | | Product Categories: | Pd;Catalysts-Ligands;API intermediates;pharmacetical;Catalysts for Organic Synthesis;Metal Compounds;Catalysis and Inorganic Chemistry;Homogeneous Pd Catalysts;Palladium;Classes of Metal Compounds;Fe (Iron) Compounds;Ferrocenes;Homogeneous Catalysts;Metal Complexes;Metallocenes;Pd (Palladium) Compounds;Synthetic Organic Chemistry;Transition Metal Compounds;72287-26-4 | | Mol File: | 72287-26-4.mol | ![[1,1'-Bis(diphenylphosphino)ferrocene]dichloropalladium(II) Structure](CAS/GIF/72287-26-4.gif) |
| | [1,1'-Bis(diphenylphosphino)ferrocene]dichloropalladium(II) Chemical Properties |
| Melting point | 275-280 °C(lit.) | | storage temp. | Keep in dark place,Inert atmosphere,Room temperature | | solubility | Soluble in dichloromethane. | | form | powder | | color | red to very dark red | | Stability: | Hygroscopic |
| | [1,1'-Bis(diphenylphosphino)ferrocene]dichloropalladium(II) Usage And Synthesis |
| Uses | [1,1′-Bis(diphenylphosphino)ferrocene]dichloropalladium(II), is a palladium catalyst used in chemical synthesis of various compounds. Is used in preparation of Nucleosides as Ectonucleotidase inhibitors. | | Chemical Properties | [1,1'-Bis(diphenylphosphino)ferrocene]dichloropalladium(II) is Red solid | | Uses | [1,1'-Bis(diphenylphosphino)ferrocene]dichloropalladium(II) is used as a catalyst for Suzuki and Stile couplings. | | Uses | suzuki reaction | | Uses | Catalyst for C-C and C-N coupling reaction. | | Application | [1,1'-Bis(diphenylphosphino)ferrocene]dichloropalladium(II) may be used as an effective palladium catalyst in the following reactions:
Cross-coupling of sec-alkyl and n-alkyl Grignard reagents with high yield and selectivity.
Suzuki coupling of aryl boronic esters with [11C]methyl iodide to form functionalized [11C]toluene derivatives.
Kumada cross-coupling of 1,3,5-tribromobenzene with Grignard reagents to form star-shaped oligothiophenes. | | Mechanism of action | [1,1'-Bis(diphenylphosphino)ferrocene]dichloropalladium(II) (pd(dppf)cl2) catalysis has gained widespread use in industrial and academic synthetic chemistry laboratories as a powerful methodology for the formation of C-C and C-Heteroatom bonds.
![[1,1'-Bis(diphenylphosphino)ferrocene]dichloropalladium(II) uses](/NewsImg/2022-12-13/6380652963927745778883369.jpg "[1,1'-Bis(diphenylphosphino)ferrocene]dichloropalladium(II) uses")
R = usually sp2
hybridised carbon
X = usually I, Br, Cl or OTf
The nature of R' and M are dependant upon
the specic coupling being performed
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| | [1,1'-Bis(diphenylphosphino)ferrocene]dichloropalladium(II) Preparation Products And Raw materials |
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