2',3',5',6'-tetramethyl-[1,1':4',1''-terphenyl]-3,3'',5,5''-tetracarboxylic acid
| 中文名称 | 2',3',5',6'-tetramethyl-[1,1':4',1''-terphenyl]-3,3'',5,5''-tetracarboxylic acid |
|---|---|
| 中文同义词 | 2',3',5',6'-四甲基-[1,1':4',1''-三联苯]-3,3'',5,5''-四羧酸;2',3',5',6'-四甲基-[1,1':4',1'-三苯基]-3,3'',5,5'-四羧酸;1,4-双(3',5'-二羧基苯基)-2,3,5,6-四甲基苯;1,4-双(3',5'-二羧基苯基)-2,3,5,6-四甲基苯;2',3',5',6'-四甲基-[1,1':4'-1'']-三联苯-3,3″,5,5″-四甲酸 |
| 英文名称 | 2',3',5',6'-tetramethyl-[1,1':4',1''-terphenyl]-3,3'',5,5''-tetracarboxylic acid |
| 英文同义词 | 2',3',5',6'-tetramethyl-[1,1':4',1''-terphenyl]-3,3'',5,5''-tetracarboxylic acid;[1,1':4',1''-Terphenyl]-3,3'',5,5''-tetracarboxylic acid,2',3',5',6'-tetramethyl-;1,4-Bis (3 ', 5' -dicarboxyphenyl) -2,3,5,6-tetramethylbenzen;1,4-di(3,5-dicarboxyphenyl)-2,3,5,6-tetramethylbenzene;1,4-Bis (3 ', 5' -dicarboxyphenyl) -2,3,5,6-tetramethylbenzen |
| CAS号 | 1119195-99-1 |
| 分子式 | C26H22O8 |
| 分子量 | 462.45 |
| EINECS号 | |
| 相关类别 | |
| Mol文件 | 1119195-99-1.mol |
| 结构式 | ![2',3',5',6'-tetramethyl-[1,1':4',1''-terphenyl]-3,3'',5,5''-tetracarboxylic acid 结构式](CAS/20180703/GIF/1119195-99-1.gif) |
2',3',5',6'-tetramethyl-[1,1':4',1''-terphenyl]-3,3'',5,5''-tetracarboxylic acid 性质
| 沸点 | 728.0±60.0 °C(Predicted) |
|---|---|
| 密度 | 1.379±0.06 g/cm3(Predicted) |
| 酸度系数(pKa) | 2.76±0.10(Predicted) |
可作为配体用于合成MOF材料：NOTT-107
[2] Gas Storage and Diffusion through Nanocages and Windows in Porous Metal–Organic Framework Cu2(2,3,5,6-tetramethylbenzene-1,4-diisophthalate)(H2O)2. https://doi.org/10.1021/cm403697m
[3] Stepwise Synthesis of Diverse Isomer MOFs via Metal-Ion Metathesis in a Controlled Single-Crystal-to-Single-Crystal Transformation. https://doi.org/10.1021/acs.cgd.7b00118
参考文献
[1] High Capacity Hydrogen Adsorption in Cu(II) Tetracarboxylate Framework Materials: The Role of Pore Size, Ligand Functionalization, and Exposed Metal Sites. https://doi.org/10.1021/ja806624j
[2] Gas Storage and Diffusion through Nanocages and Windows in Porous Metal–Organic Framework Cu2(2,3,5,6-tetramethylbenzene-1,4-diisophthalate)(H2O)2. https://doi.org/10.1021/cm403697m
[3] Stepwise Synthesis of Diverse Isomer MOFs via Metal-Ion Metathesis in a Controlled Single-Crystal-to-Single-Crystal Transformation. https://doi.org/10.1021/acs.cgd.7b00118