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[Ir{dFCF3ppy}2(bpy)]PF6

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Company Name: Career Henan Chemica Co
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Products Intro: Product Name:[Ir{dFCF3ppy}2(bpy)]PF6
CAS:1092775-62-6
Purity:Min98% HPLC/GC Package:1KG;8USD
Company Name: Hunan russell chemicals technology co ltd
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Products Intro: Product Name:(2,2'-Bipyridine)bis[3,5-difluoro-2-[5-(trifluoromethyl)-2-pyridinyl-kN][phenyl-kC]iridium(III) hexafluorophosphate
CAS:1092775-62-6
Purity:98+% Package:As buyer requirement
Company Name: Alfa Chemistry
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Products Intro: Product Name:(Ir[dFCF3ppy]2(bpy))PF6
CAS:1092775-62-6
Purity:95% Remarks:https://photochem.alfa-chemistry.com/product/ir-dfcf3ppy-2-bpy-pf6-cas-1092775-62-6-355685.html
Company Name: LEAP CHEM CO., LTD.
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Products Intro: Product Name:"[Ir{dFCF3ppy}2(bpy)]PF6
CAS:1092775-62-6
Package:1g; 5g; 25g; 1kg; 5kg; 25kg
Company Name: Suzhou Origin Specialty Chemicals Co., Ltd.
Tel: +86-512-68662322 +86-17312436797
Email: hanqun@origsc.com
Products Intro: Product Name:(2,2'-Bipyridine)bis[3,5-difluoro-2-[5-(trifluoromethyl)-2-pyridinyl-κN][phenyl-κC]iridium(III) Hexafluorophosphate
CAS:1092775-62-6
Purity:98% Package:100g;1KG;5KG

[Ir{dFCF3ppy}2(bpy)]PF6 manufacturers
[Ir{dFCF3ppy}2(bpy)]PF6 Basic information
Reaction
Product Name:[Ir{dFCF3ppy}2(bpy)]PF6
Synonyms:[Ir{dFCF3ppy}2(bpy)]PF6;Bis [2- (2,4-difluorophenyl) -5-trifluoromethylpyridine] [2-2'-bipyridyl] iridium hexafluorophosphate;(2,2'-BIPYRIDINE)BIS[3,5-DIFLUORO-2-[5-(TRIFLUOROMETHYL)-2-PYRIDINYL-KN][PHENYL-KC]IRIDIUM(III)HEXAFLUOROPHOSPHATE;Ir{dFCF3ppy}2(bpy)]PF6,(2,2'-Bipyridine)bis[3,5-difluoro-2-[5-trifluoromethyl-2-pyridinyl-kN)phenyl-kC]iridium(III) hexafluorophosphate,;2-(2,4-difluorobenzene-6-id-1-yl)-5-(trifluoromethyl)pyridine;2,2'-bipyridine, bis({3,5-difluoro-2-[5-(trifluoromethyl)pyridin-2-yl]phenyl})iridiumylium, hexafluoro-lambda5-phosphanuide;(2,2'-Bipyridine)bis[3,5-difluoro-2-[5-(trifluoromethyl)-2-pyridinyl]phenyl]iridium(III) Hexafluorophosphate;(2,2'-Bipyridine)bis[3,5-difluoro-2-[5-(trifluoromethyl)-2-pyridinyl-kappaN][phenyl-kappaC]iridium(III) Hexafluorophosphate
CAS:1092775-62-6
MF:C34H18F16IrN4P
MW:1009.6987322
EINECS:
Product Categories:
Mol File:1092775-62-6.mol
[Ir{dFCF3ppy}2(bpy)]PF6 Structure
[Ir{dFCF3ppy}2(bpy)]PF6 Chemical Properties
storage temp. Keep in dark place,Inert atmosphere,Room temperature
form Powder
color yellow
Sensitive air sensitive
Safety Information
MSDS Information
[Ir{dFCF3ppy}2(bpy)]PF6 Usage And Synthesis
Reaction
  1. Catalyst used for the chemo-, regio, and stereoselective trifluoromethylation of styrene.
  2. Photoredox catalyst used in cross-coupling: Ir/Ni dual catalysts for the synthesis of benzylic ethers.
  3. Iridium complex used for catalytic olefin hydroamidation enabled by proton-coupled electron transfer.
  4. Catalyst used for visible light photoredox cross-coupling of acyl chlorides with potassium alkoxymethyltrifluoroborates.
  5. Iridium catalyst used in the photoredox/nickel dual catalytic cross-coupling of secondary alkyl β-trifluoroboratoketones and –esters with aryl bromides.
  6. Photocatalyst used in the cross-coupling of trifluoroalkylboranes.
Reactions of 1092775-62-6_1
Reactions of 1092775-62-6_2
UsesWhen used in tandem with a nickel catalyst, the above photoredox catalyst effects the cross-coupling of C-sp3 hybridized trifluoroborates with aryl bromides under exceptionally mild conditions.
[Ir{dFCF3ppy}2(bpy)]PF6 Preparation Products And Raw materials
Tag:[Ir{dFCF3ppy}2(bpy)]PF6(1092775-62-6) Related Product Information
Tris[2-(2-pyridinyl-κN)-5-(trifluoromethyl)phenyl-κC]iridium(III) Tris[2-(4,6-difluorophenyl)pyridinato-C2,N]iridium(III) Ir[dF(t-Bu)-ppy]3 (2,2'-Bipyridine)bis[2-(2,4-difluorophenyl)pyridine]iridium(III) Hexafluorophosphate Iridium [2,2'-bis (4-tert-butylpyridine)] bis [2- (4-fluorophenyl) pyridine] iridium (III) hexafluorophosphate (2,2'-bipyridyl) bis [2- (4-fluorophenyl) pyridine] iridium (III) hexafluorophosphate Tris (2- (4-tert-butylphenyl) pyridine) iridium Ir[dF(Me)ppy]2(dtbbpy)PF6 Ir(dFppy)3 (2,2'-Bipyridine)bis(2-phenylpyridinato)iridium(III) Hexafluorophosphate Ir[p-F(t-Bu)-ppy]3 [Ir(dtbbpy)(ppy)2][PF6] Bis [2- (2,4-difluorophenyl) -5-trifluoromethylpyridine] [1,10-phenanthroline] iridium hexafluorophosphate Ir[dFppy]2(dtbbpy)PF6 hexafluorophosphate Iridium(1+),[4,4'-bis(1,1-dimethylethyl)-2,2'-bipyridine-κN1,κN1']bis[5-(1,1-dimethylethyl)-2-[4-(1,1-dimethylethyl)-2-pyridinyl-κN]phenyl-κC]-,(OC-6-33)-,hexafluorophosphate(1-) Ir[p-F(Me)ppy]2(dtbbpy)PF6