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| | Tris(triphenylphosphine)ruthenium(II) chloride Basic information |
| | Tris(triphenylphosphine)ruthenium(II) chloride Chemical Properties |
| Melting point | 159 °C | | storage temp. | Inert atmosphere,Room Temperature | | solubility | Very slightly soluble (with dissociation) in acetone, alcohol, chloroform, ethyl acetate, and toluene | | form | Solution | | color | Clear | | Water Solubility | insoluble | | Sensitive | Air & Moisture Sensitive | | Hydrolytic Sensitivity | 8: reacts rapidly with moisture, water, protic solvents | | BRN | 4935939 | | InChI | InChI=1S/3C18H15P.2ClH.Ru/c3*1-4-10-16(11-5-1)19(17-12-6-2-7-13-17)18-14-8-3-9-15-18;;;/h3*1-15H;2*1H;/q;;;;;+2/p-2 | | InChIKey | QUVLSIIMVTXAPD-UHFFFAOYSA-M | | SMILES | P(C1=CC=CC=C1)(C1=CC=CC=C1)C1=CC=CC=C1.P(C1=CC=CC=C1)(C1=CC=CC=C1)C1C=CC=CC=1.P(C1=CC=CC=C1)(C1=CC=CC=C1)C1=CC=CC=C1.[Ru](Cl)Cl | | CAS DataBase Reference | 15529-49-4(CAS DataBase Reference) |
| | Tris(triphenylphosphine)ruthenium(II) chloride Usage And Synthesis |
| Chemical Properties | black crystals | | Uses | Dichlorotris(triphenylphosphine)ruthenium(II) serves as a precatalyst for the hydrogenation of alkenes, nitro compounds, ketones, carboxylic acids, synthesis of furans from allenyl sulfides and C-H Activation Catalyst in a Ruthenium/Lewis Acid System | | Uses | suzuki reaction | | Preparation | Tris(triphenylphosphine)ruthenium(II) chloride can be prepared by refluxing hydrated Ruthenium(III) Chloride and Triphenylphosphine in ethanol according to the procedure of Wilkinson. | | General Description | Tris(triphenylphosphine)ruthenium(II) chloride can be used in the hydrogenation of nitro groups, imines, and ketones, and the selective oxidation of alcohols. | | reaction suitability | core: ruthenium
reagent type: catalyst
reaction type: C-H Activation |
| | Tris(triphenylphosphine)ruthenium(II) chloride Preparation Products And Raw materials |
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