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Titanium tetraisopropanolate

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Company Name: Dalian Richfortune Chemicals Co., Ltd
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Products Intro: Product Name:Titanium tetraisopropanolate
CAS:546-68-9
Company Name: Shanghai Time Chemicals CO., Ltd.
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Products Intro: Product Name:Titanium tetraisopropanolate
CAS:546-68-9
Company Name: Hangzhou FandaChem Co.,Ltd.
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Products Intro: Product Name:TA-10;A-1(TPT);TPT;TYZOR TP
CAS:546-68-9
Purity:as in COA Package:as customers' requirements
Company Name: Anhui Royal Chemical Co., Ltd.
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Products Intro: Product Name:Titanium(IV) Isopropoxide
CAS:546-68-9
Purity:99.00% Package:25kg/drum;200kg/drum Remarks:pharmaceutical intermediates; blocking agent;
Company Name: Hefei TNJ Chemical Industry Co.,Ltd.
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Products Intro: Product Name:Titanium tetraisopropanolate
CAS:546-68-9
Purity:96% Package:200kg;USD

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Titanium tetraisopropanolate Basic information
Reactions
Product Name:Titanium tetraisopropanolate
Synonyms:ISOPROPYL TITANATE;ISOPROPYL TITANATE(IV);TITANIUM ISOPROPOXIDE;TITANIUM ISO-PROPYLATE;TITANIUM (IV) I-PROPOXIDE;TITANIUM(IV) ISOPROPOXIDE;TITANIUM (IV) TETRA-I-PROPOXIDE;TITANIUM(IV) TETRAISOPROPOXIDE
CAS:546-68-9
MF:C12H28O4Ti
MW:284.22
EINECS:208-909-6
Product Categories:TITANIUM;Catalysts for Organic Synthesis;Classes of Metal Compounds;Homogeneous Catalysts;Synthetic Organic Chemistry;Ti (Titanium) Compounds;Organic-metal salt;Titanium Alkoxides, etc. (Homogeneous Catalysts);Transition Metal Compounds;metal alkoxide
Mol File:546-68-9.mol
Titanium tetraisopropanolate Structure
Titanium tetraisopropanolate Chemical Properties
Melting point 14-17 °C(lit.)
Boiling point 232 °C(lit.)
density 0.96 g/mL at 20 °C(lit.)
refractive index n20/D 1.464(lit.)
Fp 72 °F
storage temp. Flammables area
solubility Soluble in anhydrous ethanol, ether, benzene and chloroform.
form Liquid
color Colorless to pale yellow
Specific Gravity0.955
Water Solubility HYDROLYSIS
FreezingPoint 14.8℃
Sensitive Moisture Sensitive
Hydrolytic Sensitivity7: reacts slowly with moisture/water
Merck 14,9480
BRN 3679474
Stability:Stable, but decomposes in the presence of moisture. Incompatible with aqueous solutions, strong acids, strong oxidizing agents. Flammable.
InChIKeyVXUYXOFXAQZZMF-UHFFFAOYSA-N
CAS DataBase Reference546-68-9(CAS DataBase Reference)
EPA Substance Registry System2-Propanol, titanium(4+) salt (546-68-9)
Safety Information
Hazard Codes Xi,F
Risk Statements 10-36-36/37/38-11-67
Safety Statements 16-26-36/37/39-7/9
RIDADR UN 2413 3/PG 3
WGK Germany 2
RTECS NT8060000
21
TSCA Yes
HazardClass 3
PackingGroup III
HS Code 29051900
Hazardous Substances Data546-68-9(Hazardous Substances Data)
MSDS Information
ProviderLanguage
Titanium(IV) isopropoxide English
SigmaAldrich English
ACROS English
ALFA English
Titanium tetraisopropanolate Usage And Synthesis
Reactions
  • Catalyst for the synthesis of acyclic epoxy alcohols and allylic epoxy alcohols.
  • Useful for diastereoselective reduction of alpha-fluoroketones.
  • Catalyzes the asymmetric allylation of ketones.
  • Reagent for the synthesis of cyclopropylamines from aryl and alkenyl nitriles.
  • Useful for racemic and/or enantioselective addition of nucleophiles to aldehydes, ketones and imines.
  • Catalytic intramolecular formal [3+2] cycloaddition.
  • Catalyst for the synthesis of cyclopropanols from esters and organomagnesium reagents
Chemical Propertiescolourless to light yellow liquid
UsesCatalyst especially for asymmetric induction in organic syntheses; in preparation of nanosized TiO2. Complexing agent in sol-gel process.
General DescriptionA water-white to pale-yellow liquid with an odor like isopropyl alcohol. About the same density as water and . Flash point 66°F. Vapors heavier than air.
Air & Water ReactionsHighly flammable. Fumes in air. Soluble in water. Decomposes rapidly in water to form flammable isopropyl alcohol.
Reactivity ProfileMetal alkyls, such as TETRAISOPROPYL TITANATE, are reducing agents and react rapidly and dangerously with oxygen and with other oxidizing agents, even weak ones. Thus, they are likely to ignite on contact with alcohols.
Health HazardInhalation or contact with material may irritate or burn skin and eyes. Fire may produce irritating, corrosive and/or toxic gases. Vapors may cause dizziness or suffocation. Runoff from fire control or dilution water may cause pollution.
Purification MethodsDissolve it in dry *C6H6 , filter if a solid separates, evaporate and fractionate. It is hydrolysed by H2O to give solid Ti2O(iso-OPr)2 m ca 48o. [Bradley et al. J Chem Soc 2027, 1952, Bradley et al. J Chem Soc 469 1957, Beilstein 1 II 328, 1 IV 1469S.]
Tag:Titanium tetraisopropanolate(546-68-9) Related Product Information
Ethyl methyl carbonate (R)-Glycidyl butyrate Titanium ethoxide Diethyl carbonate Propylene carbonate DMC Tetrabutyl titanate Rutile LEAD TITANIUM ETHYLHEXANO-ISOPROPOXIDE TITANIUM ALLYLACETOACETATETRAISOPROPOXIDE SEC-BUTYL TITANATE Tetraoctyliniglycol titanate STRONTIUM TITANIUM ISOPROPOXIDE N,N,N',N'-TETRAKIS(2-PROPOXY)ETHYLEDIAMINE TITANIUM(IV) LEAD TITANIUM ISOPROPOXIDE TITANIUM(IV) TERT-BUTOXIDE Isopropyl isocyanate Diisopropyl azodicarboxylate