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ETHYLMERCURIC CHLORIDE

ETHYLMERCURIC CHLORIDE Chemical Properties
Melting point 195°C
density 3.482
solubility Chloroform (Slightly)
form solid
Water Solubility Insoluble in water. Slightly soluble in ether. Soluble in hot alcohol. Sublimes readilyInsoluble in water. Slightly soluble in ether. Soluble in hot alcohol.
Merck 14,3826
Exposure limitsNIOSH: IDLH 10 mg/m3; TWA 0.05 mg/m3; Ceiling 0.1 mg/m3
Stability:Stable. Incompatible with strong oxidizing agents. May be light sensitive.
CAS DataBase Reference107-27-7(CAS DataBase Reference)
EPA Substance Registry SystemMercury, chloroethyl- (107-27-7)
Safety Information
Hazard Codes T+,N
Risk Statements 26/27/28-33-50/53
Safety Statements 13-28-36-45-61-60
RIDADR 2025
RTECS OV9800000
HazardClass 6.1
PackingGroup II
HS Code 28521000
Toxicitymammal (species unspecified),LD50,unreported,18mg/kg (18mg/kg),"Chemistry of Pesticides," Melnikov, N.N., New York, Springer-Verlag New York, Inc., 1971Vol. -, Pg. 287, 1971.
MSDS Information
ProviderLanguage
ALFA English
ETHYLMERCURIC CHLORIDE Usage And Synthesis
Chemical PropertiesEthyl mercuric chloride, an alkyl-organo mercury compound, is silvery white, forming leaf-like crystals
Chemical PropertiesEthyl methacrylate is a colorless liquid.
Chemical Propertiessilver crystals or white solid
UsesEthyl mercuric chloride is used as the polymerization catalyst; seed or bulb fungicide.
UsesApplied at 2% strength (soln or mixed with solids) as a fungicide for treating seeds.
DefinitionChEBI: Ethylmercuric chloride is a highly toxic organomercury compound which is used as a fungicide for treating seeds. It has a role as a fungicide. It is a chlorine molecular entity and an organomercury compound.
General DescriptionSilver iridescent crystals or white fluffy solid . Sublimes easily. Sensitive to light. Highly toxic. Causes skin burns and is absorbed through the skin.
Air & Water ReactionsInsoluble in water.
Reactivity ProfileETHYLMERCURIC CHLORIDE is sensitive to prolonged exposure to light. Incompatible with strong oxidizers such as chlorine .
HazardStrong irritant.
Fire HazardFlash point data for ETHYLMERCURIC CHLORIDE are not available; however, ETHYLMERCURIC CHLORIDE is probably combustible.
Safety ProfilePoison by ingestion, inhalation, skin contact, and intraperitoneal routes. An experimental teratogen. Other experimental reproductive effects. Human mutation data reported. See also MERCURY COMPOUNDS, ORGANIC. When heated to decomposition it emits very toxic fumes of Cland Hg.
Potential ExposureThis chemical is used in manufacture of coatings, resins, and lacquers. Widely known as “Plexiglass” (in the polymer form), ethyl methacrylate is used to make polymers, which in turn are used for building, automotive, aerospace, and furniture industries. It is also used by dentists as dental plates, artificial teeth, and orthopedic cement.
ShippingUN2277 Ethyl methacrylate, stabilized, Hazard Class: 3; Labels: 3-Flammable liquid
Purification MethodsMercuric chloride can be removed by suspending ethylmercuric chloride in hot distilled water, filtering with suction onto a sintered-glass crucible and drying it. Then crystallise it from ethanol and sublime it under reduced pressure. It can also be crystallised from water. [Marvel et al. J Am Chem Soc 47 3009 1925.]
IncompatibilitiesMay form explosive mixture with air. Incompatible with oxidizers (chlorates, nitrates, peroxides, permanganates, perchlorates, chlorine, bromine, fluorine,etc.); contact may cause fires or explosions. Keep away from alkaline materials, strong bases, strong acids, oxoacids, and epoxides. Corrodes some metals. Unless inhibited, violent polymerization can occur from heat, sunlight, and contact with strong oxidizers
Waste DisposalIn accordance with 40CFR 165 recommendations for the disposal of pesticides and pesticide containers. Must be disposed properly by following package label directions or by contacting your local or federal environmental control agency, or by contacting your regional EPA office.
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