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Titanocene dichloride

Titanocene dichloride Suppliers list
Company Name: Capot Chemical Co.,Ltd.
Tel: +86-571-85586718
Email: sales@capotchem.com
Products Intro: Product Name:Titanocene dichloride
CAS:1271-19-8
Purity:98%Min. Package:100g;1kg;5kg,10kg,25kg,50kg
Company Name: Fluoropharm Co., Ltd.
Tel:
Email: sales@fluoropharm.com
Products Intro: Product Name:Titanocene dichloride
CAS:1271-19-8
Purity:98% Package:100g;1kg;5kg;25kg;100kg Remarks:Mature product
Company Name: Tianjin Zhongxin Chemtech Co., Ltd.
Tel: 022-66880623
Email: sales@tjzxchem.com
Products Intro: Product Name:Titanocene dichloride
CAS:1271-19-8
Purity:97%Min Package:25kgs druM Remarks:Catalyst for polyMer
Company Name: Hubei Jusheng Technology Co.,Ltd.
Tel: 86-18871470254
Email: linda@hubeijusheng.com
Products Intro: Product Name:Bis(cyclopentadienyl)titanium Dichloride
CAS:1271-19-8
Purity:99% Package:5KG;1KG
Company Name: Accela ChemBio Inc.
Tel: (+1)-858-699-3322
Email: info@accelachem.com
Products Intro: Product Name:Bis(cyclopentadienyl)titanium(IV) Dichloride
CAS:1271-19-8
Purity:98% Package:5g;10g;25g;100g Remarks:SY010218

Lastest Price from Titanocene dichloride manufacturers

  • Titanocene dichloride
  • US $1.00 / KG
  • 2019-12-31
  • CAS:1271-19-8
  • Min. Order: 1KG
  • Purity: 99%
  • Supply Ability: 100KG
Titanocene dichloride Basic information
Reaction
Product Name:Titanocene dichloride
Synonyms:Bis(cyclopentadienyl)titaniuM dichloride,98% Cp2TiCl2;DICYCLOPENTADIENYLTITANIUM DICHLORIDE FO;di(cyclopenta-1,3-dien-1-yl)titaniuM(IV) chloride;Dichlorobis(1,3-cyclopentadiene)titaniumDichlorodicyclopentadienyltitanium;Bis(cyclopentadienyl)titanium dichloride for synthesis;TITANOCENE DICHLORIDE;Bis(cyclopentadienyl)titaniuM dichloride, 97% 10GR;Bis(cyclopentadienyl)titaniuM dichloride, 97% 50GR
CAS:1271-19-8
MF:C10H10Cl2Ti
MW:248.96
EINECS:215-035-9
Product Categories:Miscellaneous;Classes of Metal Compounds;Metallocenes;Ti (Titanium) Compounds;Titanocene, etc.;Transition Metal Compounds;Industrial/Fine Chemicals;metallocene;Red to red-orange crystals.;chemical intermediate;PETRO CATALYST
Mol File:1271-19-8.mol
Titanocene dichloride Structure
Titanocene dichloride Chemical Properties
Melting point 260-280 °C (dec.)(lit.)
Boiling point 355.52°C (estimate)
density 1.6 g/mL at 25 °C(lit.)
storage temp. Inert atmosphere,Room Temperature
form crystal
color red
Specific Gravity1.6
Water Solubility slow decomposition
Sensitive Air & Moisture Sensitive
Hydrolytic Sensitivity4: no reaction with water under neutral conditions
Merck 14,9482
Stability:Stable. Incompatible with strong oxidizing agents. Decomposes in water. Moisture sensitive.
CAS DataBase Reference1271-19-8(CAS DataBase Reference)
NIST Chemistry ReferenceTitanocene dichloride(1271-19-8)
EPA Substance Registry SystemTitanocene dichloride (1271-19-8)
Safety Information
Hazard Codes Xi,T
Risk Statements 37/38-61-40-34-33-36/37/38
Safety Statements 36-7/8-6A-45-36/37/39-26
RIDADR UN3261
WGK Germany 3
RTECS XR2050000
8-10-21
TSCA Yes
HazardClass 8
PackingGroup II
HS Code 29310095
Hazardous Substances Data1271-19-8(Hazardous Substances Data)
MSDS Information
ProviderLanguage
Titanocene dichloride English
SigmaAldrich English
ACROS English
ALFA English
Titanocene dichloride Usage And Synthesis
Reaction
  1. Precatalyst for reduction of esters and α,β-unsaturated ketones.
  2. Catalyzes reductive deoxygenation of alcohols and hydroxylamines.
  3. Catalyst for the radical cyclization of epoxides.
  4. Reagent for the conversion of enynes to bicyclic cyclopentenones.
  5. Catalyzes silylation of alkenes and alkynes.

Chemical PropertiesTitanocene dichloride is irritating to the skin and mucous membranes.
Chemical PropertiesRed crystals. Moderately soluble in toluene, chloroform; sparingly soluble in ether and water. Stable in dry air, slowly hydrolyzed in moist air.
UsesCatalyst; with aluminum alkyls as Ziegler-Natta polymerization catalyst.
UsesTitanocene dichloride is used as an experimental cancer chemotherapeutic agent.
Production MethodsTitanocene dichloride is produced by the reaction of titanium tetrachloride with cyclopentadienyl sodium.
General DescriptionRed to red-orange crystals.
Air & Water ReactionsStable in dry air. Decomposes in moist air and in water to form HCl .
Reactivity ProfileTitanocene dichloride is incompatible with strong oxidizers. Titanocene dichloride may decompose on exposure to water. .
HazardToxic by inhalation, irritant to skin and mucous membranes.
Fire HazardFlash point data for Titanocene dichloride are not available; however, Titanocene dichloride is probably combustible.
Safety ProfilePoison by intravenous and intraperitoneal routes. Questionable carcinogen with experimental neoplastigenic, tumorigenic, and teratogenic data. Mutation data reported. See also TITANIUM COMPOUNDS. When heated to decomposition it emits toxic fumes of Cl-
CarcinogenicityBased on the results of 2 year gavage studies, the National Toxicology Program determined that there was equivocal evidence of the carcinogenic activity of titanocene dichloride in male and female rats based on a marginal increase in the incidence of forestomach squamous cell effects.
CarcinogenicityTitanocene administered by intramuscular injection produced tumors both at the injection site and at sites distant from the injection site. Titanocene dichloride showed equivocal evidence of carcinogenicity in male and female Fischer 244 rats in a 2-year oral gavage study.
Purification MethodsIt forms bright red crystals from toluene or xylene/CHCl3 (1:1) and sublimes at 190o/2mm. It is moderately soluble in EtOH and insoluble in Et2O, *C6H6, CS2, CCl4, pet ether and H2O. The crystalline dipicrate explodes on melting at 139-140o. [Wilkinson et al. J Am Chem Soc 75 1011 1953, IR: Wilkinson & Birmingham J Am Chem Soc 76 4281 1954, NMR and X-ray: Glivicky & McCowan Can J Chem 51 2609 1973, Clearfield et al. J Am Chem Soc 53 1622 1975, Beilstein 16 IV 1769.]
Tag:Titanocene dichloride(1271-19-8) Related Product Information
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