|
|
| | (PHENYLTHIOMETHYL)TRIMETHYLSILANE Basic information |
| | (PHENYLTHIOMETHYL)TRIMETHYLSILANE Chemical Properties |
| Boiling point | 158-159 °C52 mm Hg(lit.) | | density | 0.967 g/mL at 25 °C(lit.) | | refractive index | n20/D 1.539(lit.) | | Fp | 103 °F | | solubility | sol most common organic solvents. | | form | clear liquid | | color | Colorless to Almost colorless | | Specific Gravity | 0.97 | | Hydrolytic Sensitivity | 4: no reaction with water under neutral conditions | | BRN | 1932375 | | NIST Chemistry Reference | Silane, trimethyl[(phenylthio)methyl]-(17873-08-4) |
| Hazard Codes | Xn | | Risk Statements | 20-38 | | Safety Statements | 23-28 | | RIDADR | UN 1993 3/PG 3 | | WGK Germany | 3 | | HS Code | 2931.90.6000 | | HazardClass | 3.2 | | PackingGroup | III |
| | (PHENYLTHIOMETHYL)TRIMETHYLSILANE Usage And Synthesis |
| Physical properties | bp 158–159 °C/52 mmHg; d20 0.967 g cm?3; n20
D
1.5390. | | Uses | lithio derivative is a one-carbon homologating agent leading to
aldehydes via sila-Pummerer rearrangement, vinyl sulfides via
Peterson alkenation, and vinylsilanes from silyl epoxides. | | Purification Methods | If the sample is suspect, then add H2O, wash it with 10% aqueous NaOH, H2O again, dry (anhydrous CaCl2) and fractionally distil it through a 2ft column packed with glass helices. [Cooper J Am Chem Soc 76 3713 1954.] |
| | (PHENYLTHIOMETHYL)TRIMETHYLSILANE Preparation Products And Raw materials |
|