| Company Name: |
INTATRADE GmbH |
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+49 3493/605464 |
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sales@intatrade.de |
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| | Iron dodecacarbonyl Basic information |
| Product Name: | Iron dodecacarbonyl | | Synonyms: | Dodecacarbonyltriiron, 95+% (Assay on dry basis), stab. with 5-10% methanol;Triiron dodecacarbonyl, stabilized, 99%;Iron dodecacarbonyl(Stabilized with 5-10% methanol);di-mu-carbonyldecacarbonyl-triangulo-triiron;TRIIRON DODECACARBONYL, PROTECTED WITH 5 -10% METHYL ALCOHOL;TRI-IRONDODECACARBONYL MOISTENED WITH ME THANOL(CH3OH 5-10%;stabilisedwith5-10%methanol;IRON DODECARBONYL | | CAS: | 17685-52-8 | | MF: | C12H24FeO12 | | MW: | 416.15676 | | EINECS: | 241-668-5 | | Product Categories: | metal carbonyl complexes | | Mol File: | 17685-52-8.mol |  |
| | Iron dodecacarbonyl Chemical Properties |
| Melting point | 165 °C (dec.) (lit.) | | density | 1.99 | | Fp | 9℃ | | storage temp. | 2-8°C | | form | crystal | | Specific Gravity | 2 | | color | black | | Water Solubility | Insoluble in water. Soluble in non polar organic solvents. | | Sensitive | Air Sensitive | | Exposure limits | ACGIH: TWA 1 mg/m3
NIOSH: TWA 1 mg/m3 | | InChI | 1S/12CO.3Fe/c12*1-2;;; | | InChIKey | HLYRMDDXFDINCB-UHFFFAOYSA-N | | SMILES | [C-]#[O+].[C-]#[O+].[C-]#[O+].[C-]#[O+].[C-]#[O+].[C-]#[O+].[C-]#[O+].[C-]#[O+].[C-]#[O+].[C-]#[O+].O=C1[Fe]23[Fe][Fe]12C3=O | | NIST Chemistry Reference | Triiron dodecacarbonyl(17685-52-8) |
| | Iron dodecacarbonyl Usage And Synthesis |
| Chemical Properties | black powder or crystals | | Uses | Eliminates sulfur from substituted thiophene complexes, leading to ferroles. Access to new areas of organometallic chemistry is promising using the reaction of Fe3(CO)12 with tellurium-nitrogen heterocycles such as benzoisotellurazole. | | Uses | It eliminates sulfur from substituted thiophene complexes, which leads to ferroles. Access to new areas of organometallic chemistry is promising using the reaction of Fe3(CO)12 with tellurium-nitrogen heterocycles such as benzoisotellurazole. | | General Description | This product has been enhanced for catalytic efficiency. | | reaction suitability | core: iron
reagent type: catalyst | | Purification Methods | It usually contains 10% by weight of MeOH as stabiliser. This can be removed by keeping it in a vacuum at 0.5mm for at least 5hours. It can be sublimed slowly at high vacuum and is soluble in organic solvents. [Landesberg et al. J Org Chem 37 930 1972, Case & Whiting J Chem Soc 4632 1960, King & Stone Inorg Synth VII 193 1963.] TOXIC. |
| | Iron dodecacarbonyl Preparation Products And Raw materials |
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