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Cesium bromide

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CAS:7787-69-1
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Products Intro: Product Name:Cesium bromide
CAS:7787-69-1
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  • Cesium bromide
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  • Cesium bromide
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  • Cesium bromide
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  • 2025-12-01
  • CAS:7787-69-1
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Cesium bromide Chemical Properties
Melting point 636 °C (lit.)
Boiling point 1300 °C
density 4.44 g/mL at 25 °C (lit.)
refractive index 1.6984
Fp 1300°C
storage temp. Store at room temperature, keep dry and cool
solubility H2O: 3 M at 20 °C, clear, colorless
form beads
color White
Specific Gravity4.44
Water Solubility 55 g/100 mL (20 ºC)
Sensitive Hygroscopic
Merck 14,2009
Stability:Stable.
InChI1S/BrH.Cs/h1H;/q;+1/p-1
InChIKeyLYQFWZFBNBDLEO-UHFFFAOYSA-M
SMILES[Br-].[Cs+]
CAS DataBase Reference7787-69-1(CAS DataBase Reference)
NIST Chemistry ReferenceCesium bromide(7787-69-1)
EPA Substance Registry SystemCesium bromide (CsBr) (7787-69-1)
Safety Information
Hazard Codes Xi
Risk Statements 36/37/38
Safety Statements 26-36
WGK Germany 3
RTECS FK9275000
TSCA TSCA listed
HS Code 28275900
Storage Class11 - Combustible Solids
Hazard ClassificationsAcute Tox. 4 Oral
Aquatic Acute 1
Repr. 2
ToxicityLD50 i.p. in rats: 1.4 g/kg (Cochran)
MSDS Information
ProviderLanguage
Cesium bromide English
SigmaAldrich English
ACROS English
ALFA English
Cesium bromide Usage And Synthesis
StructureCesium bromide (CsBr) is Tetraauricupride structured and crystallizes in the cubic Pm̅3m space group. Cs¹⁺ is bonded in a body-centred cubic geometry to eight equivalent Br¹⁻ atoms. All Cs-Br bond lengths are 3.75 Å. Br¹⁻ is bonded in a body-centered cubic geometry to eight equivalent Cs¹⁺ atoms.Cesium bromide
Description Cesium bromide is a colorless crystal with the formula CsBr. It is a moderately water soluble crystalline Cesium source that decomposes to Cesium oxide on heating. Most metal bromine compounds are water-soluble and are used in water treatment, chemical analysis, and ultra-high purity for certain crystal growth applications.
Cesium bromide
Chemical PropertiesCesium bromide is a colourless crystals. It has been used in protein crystallization for anamolous scattering.
Cesium bromide
UsesIn x-ray fluorescent screens, spectrometer prisms, absorption-cell windows.
UsesCesium bromide is used as reagent, intermediate in pharmaceuticals.
UsesCesium bromide (CsBr) crystals are used in scintillation counters to detect radiation. The compound is also used to coat the inside of fluorescent screens.
PreparationCaesium bromide can be prepared via following reactions:
Neutralization:
CsOH (aq) + HBr (aq) → CsBr (aq) + H2O (l)
Cs2(CO3) (aq) + 2 HBr (aq) → 2 CsBr (aq) + H2O (l) + CO2 (g)
Direct synthesis:
2 Cs (s) + Br2 (g) → 2 CsBr (s)
The direct synthesis is a vigorous reaction of caesium with other halogens. Due to its high cost, it is not used for preparation.
Production MethodsSingle crystals Cesium bromide can be synthesized by the Kyropoulus method or the Stockbarger method. One can polish the crystal using pure alcohol.
Safety ProfileModerately toxic by intraperitoneal route. See also CESIUM and BROMIDES. When heated to decomposition it emits toxic fumes of Br-.
Purification MethodsIt is very soluble in H2O, soluble in EtOH but insoluble in Me2CO. Dissolve it in the minimum volume of H2O, filter and precipitate it by adding Me2CO. Filter off the solid and dry it at 100o. Also recrystallise it from water (0.8mL/g) by partial evaporation in a desiccator.
Structure and conformationThe space lattice of CsBr(Cesium bromide) belongs to the cubic system, and its cesium chloride structure has a lattice constant of a=0.429 nm.
Cesium bromide Preparation Products And Raw materials
Raw materialsCesium carbonate-->Cesium hydroxide-->Cesium iodide-->Cesium sulfate
Tag:Cesium bromide(7787-69-1) Related Product Information
Clidinium bromide Ethidium bromide Sodium bromate Sodium bromide Cesium nitrate 2,2,6,6-TETRAMETHYL-3,5-HEPTANEDIONATO CESIUM [CS(TMHD)] Cesium chloride Caesium fluoride CESIUM DODECAHYDRODODECABORATE Cesium carbonate CESIUM HYDROXIDE, HYDRATE (99.9%-CS) Cesium sulfate NEODYMIUM(III) BROMIDE HYDRATE TITANIUM(IV) BROMIDE Magnesium bromide hexahydrate Cerium(III) bromide hydrate TIN (II) BROMIDE Manganese(II) bromide tetrahydrate Caesium Bromide

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