ChemicalBook > Product Catalog >Inorganic chemistry >industrial gases >HELIUM

HELIUM

HELIUM Suppliers list
Company Name: Mainchem Co., Ltd.
Tel: +86-0592-6210733
Email: sales@mainchem.com
Products Intro: Product Name:HELIUM
CAS:7440-59-7
Company Name: Shanghai Hanhong Scientific Co.,Ltd.  
Tel: 021-54306202,021-54308259
Email: info@hanhonggroup.com
Products Intro: Product Name:HELIUM
CAS:7440-59-7
Remarks:RA01000008
Company Name: Sigma-Aldrich  
Tel: 021-61415566 800-819-3336(Tel) 400-620-3333(Mobile)
Email: orderCN@sial.com
Products Intro: Product Name:Helium Messer(R) CANGas, 99.999%
CAS:7440-59-7
Purity:Messer(R) CANGas, 99.999% Package:1027.26RMB/1L Remarks:ALDRICH
Company Name: Shanghai wechem chemical co., ltd  
Tel: 021-5198 7501
Email: info@wechem.cn
Products Intro: Product Name:Helium
CAS:7440-59-7
Purity:99.9+ Package:50L
Company Name: AoboRui (Tianjin) Co., Ltd.  
Tel: 86 022 65675308 18310521067
Email: 23034325@qq.com
Products Intro: CAS:7440-59-7
Purity:99 Package:100G/1;500G/1;1KG/1;5KG/1;10KG/1
HELIUM Basic information
Product Name:HELIUM
Synonyms:HELIUM;HYDROGEN AND HELIUM;HYDROGEN-HELIUM;LEAK DETECTION STANDARD LD-3;atomichelium;He;helium,compressed;Primarily commercial liquefaction plants
CAS:7440-59-7
MF:He
MW:4
EINECS:231-168-5
Product Categories:refrigerants;Inorganics;Chemical Synthesis;Compressed and Liquefied Gases;Synthetic Reagents;Chemical Synthesis;Specialty Gases;Synthetic Reagents
Mol File:7440-59-7.mol
HELIUM Structure
HELIUM Chemical Properties
Melting point -272.2 °C(lit.)
Boiling point -268.934 °C(lit.)
density 0.1785(0℃)
vapor density 0.14 (vs air)
form gas
Water Solubility 8.61mL/1000g H2O (101.32kPa, 0°C) [KIR78]; Henry’s law constants, k×10?4: 9.856 (104°C), 6.739 (149.4°C), 2.524 (250.6°C), 1.796 (275.1°C) [POT78]
Merck 13,4645
Stability:Stable; extremely unreactive.
CAS DataBase Reference7440-59-7(CAS DataBase Reference)
Safety Information
Safety Statements 9
RIDADR UN 1046 2.2
WGK Germany 3
RTECS MH6520000
4.5-31
HazardClass 2.2
MSDS Information
ProviderLanguage
SigmaAldrich English
HELIUM Usage And Synthesis
Chemical Propertiescolourless gas
Chemical PropertiesHelium is a colorless, odorless, and tasteless gas. It is nonflammable.
Historyvalence usually 0. Evidence of the existence of helium was first obtained by Janssen during the solar eclipse of 1868 when he detected a new line in the solar spectrum; Lockyer and Frankland suggested the name helium for the new element; in 1895, Ramsay discovered helium in the uranium mineral cleveite, and it was independently discovered in cleveite by the Swedish chemists Cleve and Langlet about the same time. Rutherford and Royds in 1907 demonstrated that α particles are helium nuclei. Except for hydrogen, helium is the most abundant element found throughout the universe. Helium is extracted from natural gas; all natural gas contains at least trace quantities of helium. It has been detected spectroscopically in great abundance, especially in the hotter stars, and it is an important component in both the proton–proton reaction and the carbon cycle, which account for the energy of the sun and stars. The fusion of hydrogen into helium provides the energy of the hydrogen bomb. The helium content of the atmosphere is about 1 part in 200,000. It is present in various radioactive minerals as a decay product. Much of the world’s supply of helium is obtained from wells in Texas, Colorado, and Kansas. The only other known helium extraction plants, outside the United States, in 1999 were in Poland, Russia, China, Algeria, and India. The cost of helium has fallen from $2500/ft3 in 1915 to about 2.5¢/cu.ft. (.028 cu meters) in 1999. Helium has the lowest melting point of any element and has found wide use in cryogenic research, as its boiling point is close to absolute zero. Its use in the study of superconductivity is vital. Using liquid helium, Kurti and co-workers, and others, have succeeded in obtaining temperatures of a few microkelvins by the adiabatic demagnetization of copper nuclei, starting from about 0.01 K. Liquid helium (He4) exists in two forms: He4I and He4II, with a sharp transition point at 2.174 K (3.83 cm Hg). He4I (above this temperature) is a normal liquid, but He4II (below it) is unlike any other known substance. It expands on cooling; its conductivity for heat is enormous; and neither its heat conduction nor viscosity obeys normal rules. It has other peculiar properties. Helium is the only liquid that cannot be solidified by lowering the temperature. It remains liquid down to absolute zero at ordinary pressures, but it can readily be solidified by increasingthe pressure. Solid 3He and 4He are unusual in that both can readily be changed in volume by more than 30% by application of pressure. The specific heat of helium gas is unusually high. The density of helium vapor at the normal boiling point is also very high, with the vapor expanding greatly when heated to room temperature. Containers filled with helium gas at 5 to 10 K should be treated as though they contained liquid helium due to the large increase in pressure resulting from warming the gas to room temperature. While helium normally has a 0 valence, it seems to have a weak tendency to combine with certain other elements. Means of preparing helium diflouride have been studied, and species such as HeNe and the molecular ions He+ and He++ have been investigated. Helium is widely used as an inert gas shield for arc welding; as a protective gas in growing silicon and germanium crystals, and in titanium and zirconium production; as a cooling medium for nuclear reactors, and as a gas for supersonic wind tunnels. A mixture of helium and oxygen is used as an artificial atmosphere for divers and others working under pressure. Different ratios of He/O2 are used for different depths at which the diver is operating. Helium is extensively used for filling balloons as it is a much safer gas than hydrogen. One of the recent largest uses for helium has been for pressurizing liquid fuel rockets. A Saturn booster such as used on the Apollo lunar missions required about 13 million ft3 of helium for a firing, plus more for checkouts. Liquid helium’s use in magnetic resonance imaging (MRI) continues to increase as the medical profession accepts and develops new uses for the equipment. This equipment is providing accurate diagnoses of problems where exploratory surgery has previously been required to determine problems. Another medical application that is being developed uses MRI to determine by blood analysis whether a patient has any form of cancer. Lifting gas applications are increasing. Various companies in addition to Goodyear, are now using “blimps” for advertising. The Navy and the Air Force are investigating the use of airships to provide early warning systems to detect low-flying cruise missiles. The Drug Enforcement Agency has used radar-equipped blimps to detect drug smugglers along the southern border of the U.S. In addition, NASA is currently using helium-filled balloons to sample the atmosphere in Antarctica to determine what is depleting the ozone layer that protects Earth from harmful U.V. radiation. Research on and development of materials which become superconductive at temperatures well above the boiling point of helium could have a major impact on the demand for helium. Less costly refrigerants having boiling points considerably higher could replace the present need to cool such superconductive materials to the boiling point of helium. Natural helium contains two stable isotopes 3He and 4He. 3He is present in very small quantities. Six other isotopes of helium are now recognized.
UsesGases, diluent.
DefinitionNoble element of atomic number 2, first element in the noble gas group of the periodic table, aw 4.00260, valence of 0. Helium nuclei are alpha particles. Most important isotope is helium-3.
General DescriptionA colorless, odorless, noncombustible gas. Can asphyxiate. Inhalation causes the voice to become squeaky (Mickey Mouse voice). Exposure of the container to prolonged heat or fire can cause HELIUM to rupture violently and rocket. If liquefied, contact of the very cold liquid with water causes violent boiling. Pressures may build to dangerous levels if the liquid contacts water in a closed container. Used in arc welding, to trace leaks in refrigeration and other closed systems and as a lifting gas for lighter-than-air aircraft.
Reactivity ProfileChemically inert. These substances undergo no chemical reactions under any known circumstances. They are nonflammable, noncombustible and nontoxic. They can asphyxiate.
Health HazardVapors may cause dizziness or asphyxiation without warning. Vapors from liquefied gas are initially heavier than air and spread along ground.
Fire HazardNon-flammable gases. Containers may explode when heated. Ruptured cylinders may rocket.
Potential ExposureIt is used in weather balloons and in welding gases. Liquid helium is used as a closed system cooling agent.
First aidIf frostbite has occurred, seek medical attention immediately; do not rub the affected areas or flush them with water. In order to prevent further tissue damage, do not attempt to remove frozen clothing from frostbitten areas. If frostbite has NOT occurred, immediately and thor oughly wash contaminated skin with soap and water. Seek medical attention promptly. Breathing: Remove the person from exposure. Begin (using universal precautions, includ ing resuscitation mask) if breathing has stopped and CPR if heart action has stopped. Transfer promptly to a medical facility.
ShippingUN1046 Helium, compressed, Hazard Class: 2.2; Labels: 2.2-Nonflammable compressed gas; UN1963 Helium, refrigerated liquid (cryogenic liquid), Hazard Class: 2.2; Labels: 2.2-Nonflammable compressed gas.
Purification MethodsDry the gas by passing it through a column of Linde 5A molecular sieves and CaSO4, then through an activated-charcoal trap cooled in liquid N2, to adsorb N2, argon, xenon and krypton. Also pass it over CuO pellets at 300o to remove hydrogen and hydrocarbons, over Ca chips at 600o to remove oxygen, and then over titanium chips at 700o to remove N2 [Arnold & Smith J Chem Soc, Faraday Trans 2 77 861 1981]. Its solubility in 100mL of H2O is 0.94mL at 25o, 1.05mL at 50o and 1.21 at 75o.
Waste DisposalReturn refillable compressed gas cylinders to supplier.
HELIUM Preparation Products And Raw materials
Preparation ProductsNEON
Raw materialsAmmonia
Tag:HELIUM(7440-59-7) Related Product Information
Argon Nitrogen HELIUM ENRICHED NAT GAS REF STD 1X14L MULTI-COMPONENTS GAS IN HELIUM 14L HELIUM - NEON METHANE IN HELIUM 100PPM 1X48L PROPANE-HELIUM ETHYLENE IN HELIUM(100PPM) 14L Rare gases,mixtures Helium and neon mixtures Helium Neon Laser Photography Composition Film (LP-6328 II) CARBON DIOXIDE, NITROGEN, HELIUM (3He)helium Helium, crude BUTANE/HELIUM HYDROGEN CHLORIDE AND HYDROGEN HELIUM GAS MIXTURE G-8 HELIUM-3