dinitrobenzene

dinitrobenzene Basic information
Product Name:dinitrobenzene
Synonyms:dinitrobenzene;dinitro-benzen;dinitrobenzol;Dinitrobenzol (All Isomers);Dinitrobenzol solid;Dintrobenzen solid
CAS:25154-54-5
MF:C6H4N2O4
MW:168.10696
EINECS:246-673-6
Product Categories:
Mol File:25154-54-5.mol
dinitrobenzene Structure
dinitrobenzene Chemical Properties
Melting point 89-174 °C
Boiling point 297.01°C (rough estimate)
density 1.6328 (rough estimate)
refractive index 1.4738 (estimate)
form Colorless or yellowish needles or plates
EPA Substance Registry SystemDinitrobenzene (25154-54-5)
Safety Information
RIDADR 1597
HazardClass 6.1(a)
PackingGroup II
Hazardous Substances Data25154-54-5(Hazardous Substances Data)
MSDS Information
dinitrobenzene Usage And Synthesis
UsesSynthesis of dyestuffs, explosives, celluloid production
DefinitionChEBI: 1,2-dinitrobenzene is a dinitrobenzene.
General DescriptionOne or more of the three isomeric (1,2- 1,3- and 1,4-) dinitrobenzenes, which are solids at room conditions, presumably in a non-aqueous solvent or carrier. Toxic by skin absorption. Exposure of the confined material to heat or shock may result in explosive decomposition. Produces toxic oxides of nitrogen during combustion.
Reactivity Profiledinitrobenzene may react vigorously with oxidizing materials. Reaction with nitric acid (nitration) leads to a mixture of trinitrobenzenes possessing high-explosive properties [Urbanski, 1967, vol. 3, p. 290]. If heat and reaction conditions of the nitration are not controlled, detonation comparable to that of TNT may occur [Anon., J. R. Inst. Chem., 1960, 84, p. 451]. A mixture of 1,3-dinitrobenzene with tetranitromethane can be highly explosive [Urbanski, 1964, vol. 1, 592]. 1,2-dinitrobenzene is a severe explosion hazard when shocked or exposed to heat or flame.
Health HazardHighly toxic, may be fatal if inhaled, swallowed or absorbed through skin. Contact with molten substance may cause severe burns to skin and eyes. Avoid any skin contact. Effects of contact or inhalation may be delayed. Fire may produce irritating, corrosive and/or toxic gases. Runoff from fire control or dilution water may be corrosive and/or toxic and cause pollution.
Fire HazardCombustible material: may burn but does not ignite readily. Containers may explode when heated. Runoff may pollute waterways. Substance may be transported in a molten form.
Safety ProfileSuspected carcinogen. A poison. When heated to decomposition it emits toxic fumes of NOx. See also oDINITROBENZENE.
CarcinogenicityIn vitro studies show that m-DNB is mutagenic in Salmonella typhimurium.
The 2003 ACGIH threshold limit valuetime- weighted average (TLV-TWA) for all isomers of dinitrobenzene is 0.15 ppm (1.0mg/ m3) with a notation for skin absorption.
dinitrobenzene Preparation Products And Raw materials
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